Copper substituted nickel ferrite nanoparticles anchored onto the graphene sheets as electrode materials for supercapacitors fabrication

Nickel ferrites with high theoretical capacitance value as compared to the other metal oxides have been applied as electrode material for energy storage devices i.e. batteries and supercapacitors. High tendency towards aggregation and less specific surface area make the metal oxides poor candidate for electrochemical applications. Therefore, the improvements in the electrochemical properties of nickel ferrites (NiFe₂O₄) are required. Here, we report the synthesis of graphene nano-sheets decorated with spherical copper substituted nickel ferrite nanoparticles for supercapacitors electrode fabrication. The copper substituted and unsubstituted NiFe₂O₄ nanoparticles were prepared via wet chemical co-precipitation route. Reduced graphene oxide (rGO) was prepared via well-known Hummer's method. After structural characterization of both ferrite (Ni_1-xCu_xFe₂O₄) nanoparticles and rGO, the ferrite particles were decorated onto the graphene sheets to obtain Ni_1-xCu_xFe₂O₄@rGO nanocomposites. The confirmation of preparation of these nanocomposites was confirmed by scanning electron microscopy (SEM). The electrochemical measurements of nanoparticles and their nanocomposites (Ni_0.9Cu_0.1Fe₂O₄@rGO) confirmed that the nanocomposites due to highly conductive nature and relatively high surface area showed better capacitive behavior as compared to bare nanoparticles. This enhanced electrochemical energy storage properties of nanocomposites were attributed to the graphene and also supported by electrical (I-V) measurements. The cyclic stability experiments results showed ~65% capacitance retention after 1000 cycles. However this retention was enhanced from 65% to 75% for the copper substituted nanoparticles (Ni_0.9Cu_0.1Fe₂O₄) and 65–85% for graphene based composites. All this data suggest that these nanoparticles and their composites can be utilized for supercapacitors electrodes fabrication.     

Numerical investigations on dynamic performance of stiffened box steel bridge piers

The aim of this paper is to carry out extensive numerical investigations about the effect of various structural parameters on the dynamic performance of stiffened box steel bridge pier under a strong earthquake ground motion. The considered structural parameters are the local slenderness ratios of stiffener and stiffened wall as well as the global slenderness ratio of the pier. In the present study, all investigated piers are made of high tensile steel with high yield ratio. The non-linear time history analyses are carried out using in-house Finite Element Program DYNAPSS, recently developed by the first author. This program is verified by comparing its results with the results obtained by the general FE program. In this program, the geometrical nonlinearity is considered on the bases of Total Lagrangian formulation, while the non-linearity of structural steel material is considered through implementation of modified multisurface cyclic plasticity model by which real characteristics of high tensile steel material such as, Plateau, Massing type of Bauschinger??s effect, disappearing of Plateau and cyclic strain hardening, are accurately modeled. The results are closely examined in respect with the damage index criterion. From this study, it is found that the increase in slenderness ratios of stiffener does not only increase the damage index, but also may lead to the full collapse. Furthermore, the damage index increases with the increase of local slenderness ratio of stiffened wall and the global slenderness ratio. Also, it is found that when the loacal buckling is not the dominant eigen mode and the pier behave as a single degree of freedom, the natural period has destructive effects when it is close to predominant period of the earthquake. Finally, contour plots of damage index values are presented. These contour plots may be greatly useful for the design of stiffened box steel bridge piers, where, critical values of structural parameters corresponding to certain value of damage index could be determined.     

Hypoglycemic effects of cocoa (Theobroma cacao L.) autolysates

Fat, alkaloid and polyphenol contents of two clones of cocoa (UIT1 and PBC 140) were removed and the remaining powder was autolyzed at pH 3.5 and 5.2. Based on the results, autolysates of UIT produced at pH 3.5 exhibited the highest ability to inhibit α-amylase activity. However, no α-glucosidase inhibition activity was observed under the conditions specified. Autolysates produced under pH 3.5 caused the highest amount of insulin secretion. In streptozotocin-diabetic rats, all cocoa autolysates significantly decreased blood glucose at 4 h. To assure that the results from the assays were not due to the polyphenols of cocoa autolysates qualitative and quantitative tests were applied. According to their results cocoa autolysates were found to be free from polyphenols. Analysis of amino acid composition revealed that cocoa autolysates were abundant in hydrophobic amino acids. It can be suggested that besides other compounds of cocoa, its peptides and amino acids could contribute to its health benefits.     

Phase Transformations of α-Alumina Made from Waste Aluminum via a Precipitation Technique

We report on a recycling project in which α-Al₂O₃ was produced from aluminum cans because no such work has been reported in literature. Heated aluminum cans were mixed with 8.0 M of H₂SO₄ solution to form an Al₂(SO₄)₃ solution. The Al₂(SO₄)₃ salt was contained in a white semi-liquid solution with excess H₂SO₄; some unreacted aluminum pieces were also present. The solution was filtered and mixed with ethanol in a ratio of 2:3, to form a white solid of Al₂(SO₄)₃·18H₂O. The Al₂(SO₄)₃·18H₂O was calcined in an electrical furnace for 3 h at temperatures of 400–1400 °C. The heating and cooling rates were 10 °C/min. XRD was used to investigate the phase changes at different temperatures and XRF was used to determine the elemental composition in the alumina produced. A series of different alumina compositions, made by repeated dehydration and desulfonation of the Al₂(SO₄)₃·18H₂O, is reported. All transitional alumina phases produced at low temperatures were converted to α-Al₂O₃ at high temperatures. The X-ray diffraction results indicated that the α-Al₂O₃ phase was realized when the calcination temperature was at 1200 °C or higher.     

Application of MIKE SHE modelling system to set up a detailed water balance computation

Estimation of total water balance is a substantial issue for watershed modelling in order to simulate the major components of the hydrological cycle to determine the stress of different anthropogenic activities on the available water resources within a catchment. In this context, the fully distributed physically based MIKE SHE modelling system was used to simulate the individual hydrological components of the total water balance for the Paya Indah Wetlands (PIW) watershed in the west of Peninsular Malaysia. Results reveal that the overall water balance is predominantly controlled by climate variables. Application of the model to the PIW watershed provides detailed estimation of the total water balance for a first‐order catchment in which actual evapotranspiration (ET) represents approximately 65 and 58%, while overland flow (OL) to the PIW lake system represents 12.38 and 12.3% of the total rainfall during the calibration and validation periods, respectively. The difference of the inflow and outflow was taken as storage in depth. Overall, the model gives a reasonable output of total error of less than 1% of the total rainfall, which in turn indicates that the interaction among components is satisfactorily sustained.     

Parallel query execution over encrypted data in database-as-a-service (DaaS)

The Journal of Supercomputing - The main challenge in database-as-a-service is the security and privacy of data because service providers are not usually considered as trustworthy. So, the data...     

Exploration of connectivity with SEM: An fMRI study of resting state

In this era, the neuroscientists get attention to find a network of brain which is activated in resting state of mind. It is challenging for any analytical technique to find out the connectivity among Brodmann areas of brain in resting state. To find network, a study was conducted in which brains are scan by functional magnetic resonance imaging of four healthy right handed individuals. Exploratory factor analysis was used to explore that which Brodmann areas are related to each other and then structural equation model has applied on explored factors (lobes) to find a network of activated brain in resting state. © 2016 Wiley Periodicals, Inc. Int J Imaging Syst Technol, 26, 264–269, 2016     

Characterization of Ceramic Foam Filters Used for Liquid Metal Filtration

In the current study, the morphology including tortuosity, and the permeability of 50-mm thick commercially available 30, 40, 50, and 80 pores per inch (PPI) alumina ceramic foam filters (CFFs) have been investigated. Measurements have been taken of cell (pore), window, and strut sizes, porosity, tortuosity, and liquid permeability. Water velocities from ~0.015 to 0.77 m/s have been used to derive both first-order (Darcy) and second-order (Non-Darcy) terms for being used with the Forchheimer equation. Measurements were made using 49-mm “straight through” and 101-mm diameter “expanding flow field” designs. Results from the two designs are compared with calculations made using COMSOL 4.2a^® 2D axial symmetric finite element modeling (FEM), as a function of velocity and filter PPI. Permeability results are correlated using directly measurable parameters and compared with the previously published results. Development of improved wall sealing (49 mm) and elimination of wall effects (101 mm) have led to a high level of agreement between experimental, analytic, and FEM methods (±0 to 7 pct on predicted pressure drop) for both types of experiments. Tortuosity has been determined by two inductive methods, one using cold-solidified samples at 60 kHz and the other using liquid metal at 50 Hz, giving comparable results.