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121.
122.
    
This work examines how different factors such as temperature, amount of injected Fe2+, lipid concentration, pH, concentration of NaCl and concentration of dissolved oxygen influenced the lipid oxidation rate of liposomes made from cod phospholipids. The rate of lipid oxidation was measured by consumption of dissolved oxygen by liposomes in a closed vessel. The rate of oxygen consumption in liposomes was proportional to the concentration of iron and the lipid concentration in the assay mixture. The oxygen consumption rate was dependent on pH, with a maximum observed between pH 4 and 5. The addition of salt (final concentration 0.04–0.8 M) decreased the rate of oxygen consumption. The rate of oxidation was independent of the concentration of dissolved oxygen (in the range of 230–5 μM). The oxygen consumption rate followed Arrhenius kinetics, and the variation in activation energy found (60–87 kJ/moles×K) might be due to variations in the composition of raw materials used in the experiments and different susceptibility to oxidation.  相似文献   
123.
    
The design of novel chiral ligands is at the core of asymmetric catalysis. The catalytic characteristics of a transition metal catalyst such as activity, selectivity and stability can be fine-tuned by optimization of the steric and electronic properties of the coordinating ligands. In asymmetric transformations, catalyst optimization still relies to a large extent on trial-and-error and educated guesses. New strategies based on combinatorial screening and high-throughput experimentation have been introduced for the design and optimization of new ligands and catalytic systems. Supramolecular bidentate ligands that form by self-assembly of building blocks are particularly suited for this combinatorial approach as the potential number of catalysts grows exponentially with the number of building blocks synthesized. Catalytic systems based on supramolecular interactions have proven to be highly advantageous in creating large ligand libraries for high-throughput screening, which allows optimization of activity and selectivity for a variety of reactions. In this review we describe the progress in this field.  相似文献   
124.
    
Phosphine complexes of cobalt halide salts activated by diethylaluminum chloride are shown to yield highly active catalysts in the hydrovinylation of styrene, with unprecedented high selectivity to the desired product 3‐phenyl‐1‐butene (3P1B). Double‐bond isomerization, a common problem in codimerization reactions, only occurs after full conversion with these catalyst systems, even at elevated temperature. The most active catalysts are based on cobalt halide species combined with either C1‐ or C2‐bridged diphosphines, heterodonor P,N or P,O ligands, flexible bidentate phosphine ligands or monodentate phosphine ligands. Kinetic investigations show an order >1 in catalyst, which indicates either the involvement of dinuclear species in the catalytic cycle or partial catalyst decomposition via a bimolecular pathway.  相似文献   
125.
    
A theoretical analysis of the dynamic behaviour of floating bridges is presented. The main emphasis is placed on the wave-induced response. The waves on the sea surface are idealized as a three-dimensional zero mean covariance stationary Gaussian process and the wave loading processes are derived using the linearized probabilistic potential theory. The structural idealization is based on the finite element technique. Alternative solution techniques of the equations of motion are discussed, including a sample treatment based on Monte Carlo simulation of time-space realizations of the wave loading processes combined with step-by-step integration.

Results from numerical analysis of a continuous curved floating bridge are presented. This includes a demonstration of the influences of the shortcrestedness of waves on the structural response.  相似文献   

126.
In Reference 1 a class of first-order factorization methods for the solution of large, sparse systems of equations, of which the coefficient matrix is a symmetric M-matrix, was introduced. Asymptotic results for the computational complexity was proved in the case of systems arising from finite difference approximation of second-order self-adjoint elliptic partial differential equation problems in two dimensions with Dirichlet boundary conditions. In this paper the result is extended to cover even mixed boundary conditions and problems with discontinuous material coefficients. Results from numerical experiments with various finite difference and finite element approximations are presented and comparisons with direct and other interative methods are made.  相似文献   
127.
The aim was to examine how well different beef muscles from Norwegian Red bulls respond to the consumer needs. Ten carcasses were slaughtered at a commercial abbatoir, chilled at 4 °C for 48 h, and 10 muscles excised. After ageing for 9 days at 4 °C, the muscles were subjected to sensory and chemical analyses and classified according to these analyses in 4 quality groups. The results regarding the comparative quality of the muscles were similar to results from other studies on predominantly steers. M. infraspinatus showed superior tenderness, juiciness and colour properties and was the only muscle to be consistent in tenderness with 80% of the samples in the highest sensory quality class. Also M. triceps brachii and M. semimembranosus adductor were reasonably tender and consistent in tenderness. As compared with the studies on steers, the M. biceps femoris and M. vastus lateralis seemed to be less tender in bulls. Results regarding sensory colour intensity, juiciness and taste showed similar findings. The pattern of association between the muscles in this study was highly irregular as the relative muscle quality varied widely, which means that using M. longissimus dorsi as a quality indicator of all muscles in the carcass is questionable.  相似文献   
128.
Global food security is one of the most pressing issues for humanity, and agricultural production is critical for achieving this. The existing analyses of specific threats to agricultural food production seldom bring out the contrasts associated with different levels of economic development and different climatic zones. We therefore investigated the same biophysical threats in three modelled types of countries with different economic and climatic conditions. The threats analysed were environmental degradation, climate change and diseases and pests of animals and plants. These threats were analysed with a methodology enabling the associated risks to be compared. The timeframe was 2012–2050 and the analysis was based on three underlying assumptions for 2050: the world population will have increased to 9 billion people, there will be a larger middle class in the world and climate change will be causing more extreme weather events, higher temperatures and altered precipitation. It is suggested that the risks, presented by the biophysical threats analysed, differ among the three modelled types of countries and that climate zone, public stewardship and economic strength are major determinants of these differences. These determinants are far from evenly spread among the world’s major food producers, which implies that diversification of risk monitoring and international assessment of agricultural production is critical for assuring global food security in 2050.  相似文献   
129.
This study evaluates whether marine lipids can oxidise in acidic stomach environment and whether authentic gastric juice has the potential to act as a pro- or anti-oxidative medium. Oxidation of herring lipids in emulsions and liposomes was followed in in vitro digestion models containing authentic human gastric juice, and compared to models containing hydrochloric acid solution. Peroxide value, concentration of thiobarbituric acid reactive substances and oxygen uptake rate increased in all the models during 2.5 h incubation at pH 4 and 37 °C in darkness. The markers showed no difference between oxidation in gastric juice and hydrochloric acid solution. Gastric juice reduced the prooxidant activity of iron ions measured as oxygen uptake rate, but did not reduce the activity of methemoglobin. Berry juice, green tea, red wine, and caffeic acid reduced oxygen uptake in the acidic environments while coffee, ascorbic acid and orange juice increased oxidation. Beverages accompanying foods containing marine lipids will therefore affect the course of post-prandial lipid oxidation.  相似文献   
130.
The authors present the results of a 2-year longitudinal study of 228 Norwegian children beginning some 12 months before formal reading instruction began. The relationships between a range of cognitive and linguistic skills (letter knowledge, phoneme manipulation, visual–verbal paired-associate learning, rapid automatized naming (RAN), short-term memory, and verbal and nonverbal ability) were investigated and related to later measures of word recognition in reading. Letter knowledge, phoneme manipulation, and RAN were independent longitudinal predictors of early reading (word recognition) skills in the regular Norwegian orthography. Early reading skills initially appeared well described as a unitary construct that then showed rapid differentiation into correlated subskills (word decoding, orthographic choice, text reading, and nonword reading) that showed very high levels of longitudinal stability. The results are related to current ideas about the cognitive foundations of early reading skills. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
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