Facile modifications of polyimide via chloromethylation: II. Synthesis and characterization of thermocurable transparent polyimide having methylene acrylate side groups

From chloromethylated polyimide, a useful starting material for modification of aromatic polyimides, a thermocurable transparent polyimide having acrylate side groups was prepared. In the presence of 1,8‐diazabicyclo[5,4,0]undec‐7‐ene, chloromethylated polyimide was esterified with acrylic acid to synthesize poly(imide methylene acrylate). The polymer was soluble in organic solvent, which makes it possible to prepare a planar film by spin coating. The polymer film became insoluble after thermal treatment at 230 °C for 30 min. Optical transparency of the film at 400 nm (for 1 µm thickness) was higher than 98 % and not affected by further heating at 230 °C for 250 min. Adhesion properties measured by the ASTM D3359‐B method ranged from 4B to 5B. Preliminary results of planarization testing showed a high degree of planarization (DOP) value (>0.53). These properties demonstrate that poly(imide methylene acrylate) could be utilized as a thermocurable transparent material in fabricating display devices such as TFT‐LCD. Copyright © 2004 Society of Chemical Industry     

天津通信企业IT信息网络支撑平台

从系统建设背景、关键技术、创新点及应用情况等方面介绍了天津市通信公司企业IT信息网络支撑平台是一个统一、高效、简洁的综合业务网络平台。     

数据通信网综合网管的设计分析

结合TMN电信管理网的体系结构．对数据通信网综合网管的结构和功能进行了分析。     

面向嵌入式系统组态工具的研究

本文在对当前流行的组态软件进行了分析的基础上，根据专用嵌入式系统的特点，设计了一个面向嵌入式系统组态工具的软件原型，并给出了相应的数据结构。     

电力负荷削峰减载系统在珠钢电炉的应用

借助现场采集装置,在计算机上获取每一分钟的冶炼工艺电能需求量,显示当前15分钟时段已发生的电耗量,调整用户设定,实现需量自动刷新、报警和专家分析推荐后续用量;实现平稳用电并减少对电网冲击,同时降低电能最大需用量以减少成本。