Synthesis and Characterizations of Triphenylamine End-Functionalized Polymers via Reversible Addition-Fragmentation Chain Transfer Polymerization

A novel reversible addition-fragmentation chain transfer (RAFT) reagent bearing triphenylamine (TPA) group, 4-diphenylamino-dithiobenzoic acid benzyl ester (DDABE), was designed and synthesized. It was used in the RAFT polymerizations of styrene (St) and methyl acrylate (MA) to prepare end-functionalized polymers. The results of the polymerization showed that the RAFT polymerizations could be well controlled using DDABE as the RAFT agent. Number-average molecular weight (M_n,GPC) increased linearly with monomer conversion, and molecular weight distributions were relatively narrow (PDI< 1.50). The results of chain-extension reaction, ¹H NMR spectra and UV/Vis spectra confirmed that most of the polymers chains were end-capped by the functional triphenylamine (TPA) groups. The effect of feed molar ratios of St/DDABE/AIBN on polymerization was investigated.     

裂齿矩形翅片板翅式换热器优化设计的分析

对裂齿矩形翅片板翅式换热器中的裂齿矩形翅片的传热效率作了分析,并以单位质量材耗的换热能力最大为目标函数,分析研究了在不同雷诺数(Re)的操作条件下裂齿矩形翅片间角度、翅片厚、长度、宽度及极厚之间的关系。结果表明:在气体换热的场合下,当Re在某一范围时翅片可有效地起到强化传热的作用。当板厚为5mm,翅片厚为3mm,翅片间夹角为45°～70°,Re为2×10~3～8×10~3,最佳翅片纵向间距与翅片长度和翅片厚度乘积的平方根的比为1.5～2.5,最佳翅片尺寸系数为3～5时,传热强化效果较好。     

基于MoCA标准的家庭网络研究

本文描述了一种基于MOCA标准的家庭网络,并对该网络及设备进行了基本性能的测试.本文首先介绍了家庭网络的发展现状,对目前的各种家庭网络标准进行了比较.在此基础上详细描述了基于MOCA标准的家庭网络,并对该网络的设计,实现、网络性能进行了详述.然后对该网络进行了测试并得出了相关的测试结论.最后指出该网络的不足及改进之处.     

爆轰试验用新型射频连接器的结构设计

针对目前爆轰试验中使用的机械密封射频连接器存在的问题.设计了基于玻璃封接技术的新型密封射频连接器结构,并进行了射频反射补偿计算和强度分析.本项研究为爆轰条件下新型密封射频连接器的研制提供了设计依据.     

基于嵌入式Linux的远程数据采集系统

以嵌入式微控制器为核心,将传感器网络收集来的数据通过无线电发射机发送到远程接收机,从而实现远程数据采集.系统的优势是充分利用了短波无线链路资源,适合于工作在无人区等场合.以ARM7为控制器,功耗小,性能稳定,维护方便;通信方式采用串口通信,连接线少,实现相对简单.系统设计主要应用嵌入式μCLinux系统设计、无线电发射、调制解调器等方面的知识,文中给出了调制解调器拨号协议、系统原理和软件流程等.     

非编码MPSK-OFDM系统判决指导的相位估计研究

本文论及非编码MPSK-OFDM系统载波跟踪中的重要部件?判决指导的相位估计器(PED)的研究.多载波系统的相位估计可以表示为各子载波相位估计的加权和.文中在分析单载波的基础上考察了符号判决错误对多载波相位估计的影响,并提出了两种改进方案,一是给出一组新的加权系数,改善了PED在较低信噪比的性能;二是由导频子载波相位估计指导其它数据子载波相位估计,获得了(-(/)M (/)M)区间上的线性无偏估计器.文中对两种改进算法进行了分析比较和仿真验证.     

Mapping rule-based systems onto multicomputers using simulated annealing

In this paper, we present a static load balancing method for mapping production rules in an expert system onto processors of a message-passing multicomputer. The method uses simulated annealing to achieve a nearly optimal allocation of production rules onto processor nodes. The approach balances the initial rule distribution to avoid higher communication demand among processor nodes at run time. A formal mapping model is developed and a new cost function is defined for the annealing process. New heuristic swap functions and cooling policies are provided to ensure the quality of the annealing process. A software load balancing package, SIMAL, was implemented on a SUN workstation to carry out the benchmark experiments. The overhead associated with this mapping method is O(m In m), where m is the number of rules in the production system. Two benchmark production systems, Toru-waltz and Tourney, are mapped onto a hypercube computer with 32 nodes. Experimental benchmark results verify the effectiveness of the rule mapping method. The method can be applied for distributed artificial intelligence processing or for the parallel execution of cooperating expert systems on a message-passing multicomputer.     

掺Nd纳米ZnO薄膜特性研究

研究了用真空蒸发法在玻璃衬底上制备稀土掺杂纳米ZnO薄膜结构、导电性及光透射性能。结果显示 ,在 5 0 0℃氧化、热处理稀土元素Nd掺杂后能够明显改善纳米ZnO薄膜的结构特性 ,薄膜的晶粒尺寸随掺杂含量的增加而减小。掺Nd使ZnO薄膜的电性能有所改善但使纳米ZnO薄膜的光透射性有所降低。