金属阳极四元涂层开发现状浅析

通过分析金属阳极涂层结构，在现有金属阳极三元涂层的基础上，确定了钌、钛、铱、锡四元涂层。对该涂层的电化性能指标及实际运行数据进行了分析，并与三元涂层电化性能指标进行对比，说明了四元涂层在析氯电位、极化率、析氧电位、寿命等方面均明显优于三元涂层，而且更适合在高电流密度下运行。     

Electrochemical micromachining of nitinol by confined-etchant-layer technique

The confined etchant layer technique has been applied to fabricate complex three-dimensional microstructures on nitinol for the first time. HF and HNO₃ were locally and simultaneously electrogenerated at the mold surface to etch a nitinol workpiece. NaOH was used as an efficient scavenger to confine the etchant close to the mold. Cyclic voltammetry was employed to study the electrochemical behavior of a Pt electrode in the etching solution in order to choose an appropriate potential for etchant generation on the mold. The thickness of the confined etchant layer was estimated to be several micrometers by inspecting the deviation of the sizes of the etched spots from the sizes of those on the microelectrode. Thus, the composition of the electrolyte could be optimized for better etching precision. By optimizing the composition of the electrolyte, complex microstructures on a Pt-Ir mold bearing the logo “XMU” of Xiamen University were successfully fabricated on nitinol. The etched patterns were approximately negative copies of the mold, and the precision of duplication could easily reach the micrometer scale.     

A comparative analysis of evolutionary and memetic algorithms for community detection from signed social networks

To detect communities in signed networks consisting of both positive and negative links, two new evolutionary algorithms (EAs) and two new memetic algorithms (MAs) are proposed and compared. Furthermore, two measures, namely the improved modularity Q and the improved modularity density D-value, are used as the objective functions. The improved measures not only preserve all properties of the original ones, but also have the ability of dealing with negative links. Moreover, D-value can also control the partition to different resolutions. To fully investigate the performance of these four algorithms and the two objective functions, benchmark social networks and various large-scale randomly generated signed networks are used in the experiments. The experimental results not only show the capability and high efficiency of the four algorithms in successfully detecting communities from signed networks, but also indicate that the two MAs outperform the two EAs in terms of the solution quality and the computational cost. Moreover, by tuning the parameter in D-value, the four algorithms have the multi-resolution ability.     

Morphologies-Controlled Synthesis and Optical Properties of Bismuth Tungstate Nanocrystals by a Low-Temperature Molten Salt Method

Well-crystallized bismuth tungstate (Bi₂WO₆) powders with different morphologies were successfully synthesized via a low-temperature molten salt method. The powders were characterized by X-ray diffraction, transmission electron microscopy, and UV-Vis, respectively. It was found that the variation of morphology of the obtained Bi₂WO₆ powder mainly depends on the different reaction temperatures and the weight ratio of LiNO₃–NaNO₃ salt to precursor. In addition, the UV-Visible absorption spectra showed that the synthesized powders had strong light absorption properties not only in the ultraviolet light but also in the visible light region.     

乳液聚合中单体醋酸乙烯酯与保护胶体聚乙烯醇的接枝反应研究

研究了以聚乙烯醇为保护胶体的醋酸乙烯乳液聚合中,聚乙烯醇与单体的接枝反应。探讨了引发剂用量、聚合反应温度、保护胶体聚合度等因素对接枝反应的影响。     

Preparation,characterization and salt-resistance of a coal based super absorbent composite

Potassium humate was extracted from brown coal.A novel super absorbent composite,poly (acrylic acid-co-acrylamide)/potassium humate (PAA-AM/KHA),was prepared by graft polymerization of acrylic acid,acrylamide and coal based potassium humate using N,N'-methylenebisacrylamide as a crosslinker and potassium peroxydisulfate as an initiator.The effects of reaction temperature,degree of neutralization of the poly (acrylic acid) and the amounts of crosslinker,initiator and potassium humate were investigated.Salt resistance tests were also carried out.The composite prepared under optimal conditions had a potassium humate content of 10% and exhibited a water absorption of 770 g/g in distilled water,and 349,286 and 41 g/g in 0.5 mol/L KC1,MgCl2 and AlCl3 solutions respectively.The results indicate that the salt resistance of PAA-AM/KHA was superior to that of poly (acrylic acid-co-acrylamide) because of the collaborative effect of functional groups of the coal based potassium humate.The PAA-AM/KHA micro powder was characterized by IR spectroscopy and the micrographic surface was characterized by scanning electron microscopy.Introduction of potassium humate into the poly (acrylic acid-co-acrylamide) structure creates a composite more suitable for use as a water-managing material in the renewal of arid and desert environments.The salt resisting property of the composite is improved,production costs are reduced and the growth stimulant effect is still present.     

An improvement to the simulation of phase-change heat-transfer during soil freezing and thawing

A new variable time step method, which is called the backwards calculating time step method, is presented in this paper. It allows numerical simulation of soil freezing and thawing while avoiding "phase change missing and overflowing". A sensitive heat capacity model is introduced through which the calculation errors are analyzed. Then the equation using the self-adjusted time step is presented and solved using finite differences. Through this equation, the time needed for a space cell to reach the phase change point temperature is calculated. Using this time allows the time step to be adjusted so that errors caused by "phase change missing and overflowing" are successfully eliminated. Above all, the obvious features of this method are an accelerated rate for adjusting the time step and simplifing the computations. An actual example proves that this method can accurately calculate the temperature fields during soil freezing and thawing. It is an improvement over traditional methods and can be widely used on com- plicated multi-dimensional phase change problems.     

乳胶制品生产的工序能力分析及质量控制

本文分析了乳胶制品的生产过程，并对工序能力指数进行了分析，从而推断出产品的质量。     

基于Kanai-Tajimi模型的地震作用荷载新型识别方法

目的研究一种识别地震作用荷载的方法,为地震作用荷载的识别与相应结构的动力特性、损伤的识别提供一种新的途径,进一步为结构的安全性、损伤进程和耐久性等研究提供理论参考.方法利用Kanai-Tajimi模型将单位强度白噪声过程模拟为未知的地震作用,并将其作用在结构上,然后根据数值模拟计算得到的结构体系响应作为观测量,采用Kalman滤波对未知荷载状态加以识别.结果最终可以利用结构的加速度响应反演得出地震作用的等效荷载,在人工添加5%观测噪声的条件下,最大误差率为7%左右,而在人工添加10%观测噪声的条件下,最大误差率为8%左右.结论通过算例的验证,说明笔者所采用的方法精度较高,获得了较好的识别效果.     

Bone Tissue Response to the Bone-like Tissue Coating on Titanium

The objective of this study was to investigate the effects of mineralized bone nodules, formed in vitro by bone marrow stromal cells(BMSCs), on the new bone formation in bone defect and on implant surface. The mineralized bone nodules were generated by culture of Lewis rats BMSCs on titanium disks in osteogenic induction medium. The gap-healing animal model was used to create the bone defect facing the disk. The titanium disks in the presence of B group or in the absence of NB group bone nodules were randomly placed into one of the rat distal femurs. This self-control design was used to compare the bone formation in defects and on titanium surface, by Micro-CT, fluorescence staining, histological and histomorphometric analysis. The new bone formation parameters in bone defect area of B group were significantly higher than those of NB group at 2 weeks, including bone volume fraction, trabecular thickness and bone area ratio. The bone nodules pre-stained with Alizarin red disappeared mostly at 2 weeks, while the red fluorescence reappeared in the newly formed bone away from the disk surface. For the bone-implant contact, B group showed lower values than NB group at 2 weeks, but no significant difference was found at 4 weeks. Our results indicate that the mineralized bone nodules can be resorbed in vivo and promote the early osteogenesis in the bone defects, and bone nodules may be applicable for new bone generation in bone defect or modification of tissue engineering scaffold.