N—氯代丁二酰亚胺8—羟基喹哪啶分光光度法测定水中苯胺类化合物的方法研究

本文提出一种能够方便、快速、灵敏地检测水质中苯胺在化合物的新方法。这种方法是先用 N-氯代丁二酰亚胺氧化苯胺 ,再用 8-羟基喹哪啶作为偶联显色剂 ,在 p H9- 1 1的碱性介质中 1进行显色。显色反应所得蓝色化合物的最大吸收波长为 62 0 nm,摩尔吸光系数为 1 .1× 1 0 4 L· mol- 1· cm- 1,在苯胺为 0 .2～ 1 0 mg/l的浓度范围内符和比尔定律 ,最低检出限为 0 .0 3mg/l,测定的重现性在± 5 %以内。该方法成功地用于环境水样的分析 ,并获得满意的分析结果     

基于线性动态系统稀疏编码的异常事件检测

线性动态系统模型结合稀疏编码实现异常事件检测。线性动态系统可有效地捕捉动态纹理在时间和空间的转移信息,描述视频的时空小块。然而,线性动态系统属于非欧氏空间,无法直接用传统的稀疏编码进行异常检测。基于约束凸优化公式,将相似性变换与稀疏编码结合,可实现线性动态系统稀疏编码的优化求解。实验表明,所提出的方法具有更好的性能。     

Effects of the reinforcement and toughening of acrylate resin/CaCO3 nanoparticles on rigid poly(vinyl chloride)

Novel composite particles based on nanoscale calcium carbonate (nano‐CaCO₃) as the core and polyacrylates as the shell were first synthesized by in situ encapsulating emulsion polymerization in the presence of the fresh slush pulp of calcium carbonate (CaCO₃) nanoparticles. Subsequently, these modified nanoparticles were compounded with rigid poly(vinyl chloride) (RPVC) to prepare RPVC/CaCO₃ nanocomposites. At the same time, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were investigated, and the synergistic effect of modified nanoparticles with chlorinated polyethylene (CPE) was also studied. The results showed that in the presence of nano‐CaCO₃ particles, the in situ emulsion polymerization of acrylates was carried out smoothly, and polyacrylates successfully encapsulated on the surface of nano‐CaCO₃ to prepare the modified nanoparticles, breaking down nano‐CaCO₃ particle agglomerates, improving their dispersion in the matrix, and also increasing the particle–matrix interfacial adhesion. Thus, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were very significant, and the cooperative effect of the nanoparticles with CPE occurred in the united modification system. Scanning electron microscopy analyses indicated that large‐fiber drawing and network morphologies coexisted in the system of joint modification of nanoparticles with CPE. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3940–3949, 2007     

Ozone-Based Advanced Oxidation Processes for the Decomposition of N-Methyl-2-Pyrolidone in Aqueous Medium

The present study investigates the decomposition of N-Methyl-2-Pyrolidone (NMP) using conventional ozonation (O₃), ozonation in the presence of UV light (UV/O₃), hydrogen peroxide (O₃/H₂O₂), and UV/H₂O₂ processes under various experimental conditions. The influence of solution pH, ozone gas flow dosage, and H₂O₂ dosage on the degradation of NMP was studied. All ozone-based advanced oxidation processes (AOPs) were efficient in alkaline medium, whereas the UV/H₂O₂ process was efficient in acidic medium. Increasing ozone gas flow dosage would accelerate the degradation of NMP up to certain level beyond which no positive effect was observed in ozonation as well as UV light enhanced ozonation processes. Hydrogen peroxide dosage strongly influenced the degradation of NMP and a hydrogen peroxide dosage of 0.75 g/L and 0.5 g/L was found to be the optimum dosage in UV/H₂O₂ and O₃/H₂O₂ processes, respectively. The UV/O₃ process was most efficient in TOC removal. Overall it can be concluded that ozonation and ozone-based AOPs are promising processes for an efficient removal of NMP in wastewater.     

Function of sulfur dioxide in the kinetic mechanism of oxidation of carbon

Retardation of the gasification reaction of carbon with oxygen by SO₂ was observed. Rates of oxidation were determined by thermal gravimetric analysis (TGA) of a nuclear graphite in the temperature range of 550–700°C, and of a coconut charcoal in the temperature range of 400–505°C. The oxidant gases were dry air containing 0–6% SO₂. Reduction of the rate by SO₂ varied with burn-off. Differential thermal analysis (DTA) was also applied to detect the retardation effect of SO₂. The technique of infrared internal reflection spectroscopy (IRS) was used to examine the surface species of reacted charcoal samples. Absorption bands were assigned to surface carbonyls, lactones, and a chemisorbed SO₂ in the form of sulfate. Chemisorption of SO₂ was attributed to cause the retardation of the oxidation reaction.     

CDMA干扰对GSM系统的影响及消除方式

本文主要研究CDMA系统对GSM系统的上行干扰,通过实验以及理论计算分析CDMA干扰对GSM系统的影响,并结合天线隔离度分析两系统之间的安全距离.     

后XP时代网络安全防护技术探究

伴随着微软公司不断改革与发展,windows XP服务也在今年2014年4月8日正式退役.世界各个行业与单位都开始在工作中进一步使用计算机技术,但不少老用户依旧习惯使用windowsXp系统,这就需要在后XP时代网络安全防护技术不断适应这部分客户的需求,保障他们电脑使用的安全性,为以后计算机网络安全防护提供有效防护措施.     

微晶纤维素增粘剂的研制

以棉浆为原料，废盐酸为水解催化剂，所得合成革用微晶纤锥素增粘剂的质量指标达到了德国和日本同类产品的标准。     

增强《马克思主义基本原理概论》课程教学实效的体会

上好<马克思主义基本原理课概论>,要对这门课的性质、地位和任务、基本要求以及课程的重点和难点有一个基本认识,并能正确面对教学中的困境.思想政治课教师要苦练内功,不断提高自己的学识水平,开动脑筋,转变观念,采取灵活多样的教学方法和手段,把教师的"教"与学生的"学"有机结合起来,想方设法提高学生的学习积极性,要把理论课教学和实践课教学结合起来,改革思想政治课的评价体系和方式,不断增强思想政治课教学的实效性.     

我国农业保险发展中存在的问题及对策

针对我国农业保险发展现状,分析了农业保险发展中存在的问题.认为目前我国农业保险的发展正处于最困难和最关键的时期.为推动农业保险的快速发展,提出了建立和完善有关法规、加大政策扶持力度,确立农业法定险种、成立综合性农业保险公司、建立再保险机制和多渠道农业保险体系等措施建议.