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41.
M. E. Borges L. Hernández J. C. Ruiz-Morales P. F. Martín-Zarza J. L. G. Fierro P. Esparza 《Clean Technologies and Environmental Policy》2017,19(8):2113-2127
This work deals with the sustainable biodiesel production from low-cost renewable feedstock (waste and non-edible oils) using a heterogeneous catalyst constituted by potassium loaded on an amorphous aluminum silicate naturally occurring as volcanic material (pumice). The main challenge to biodiesel production from low-quality oils (used oils and greases) is the high percentage of free fatty acids (FFAs) and water in the feedstock that causes undesirable side reactions. The catalytic materials studied were tested in the transesterification reaction when using low-quality oils containing a high proportion of free fatty acids (FFAs) and water. Results indicated that the amount of acid and basic sites on the catalytic surface increases upon increasing potassium loading in the catalyst, displaying better performance for biodiesel production. Indeed, the modification of the aluminum silicate substrate upon potassium incorporation results in a catalytic material containing both acidic and basic sites, which are responsible for both triglycerides transesterification and FFA esterification reactions. The studied catalyst not only showed good performance in the biodiesel production reaction but also good tolerance to FFA and water contained in the feedstock for biodiesel production. The catalytic material was microstructured by 3D printing in order to design a catalytic stirring system with high mechanical strength, efficient and reusable. The use of 3D printing in biofuel production is a novelty that brings good solutions for catalyst production. 相似文献
42.
José Augusto de Oliveira Diogo Aparecido Lopes Silva Mariana Guardia Lillian do Nascimento Gambi Otávio José de Oliveira Aldo Roberto Ometto 《Clean Technologies and Environmental Policy》2017,19(6):1761-1774
The companies’ needs to adopt changes in their way of production to maximize the environmental performance required by their stakeholders, and at the same time, to maximize their economic and market performance, have made them seek for environmental strategies and certifications. In this sense, the Cleaner Production and the Environmental Management System based on ISO 14001 have been, respectively, presented, since the main objective of this research is to identify and analyze Cleaner Production contributions to comply with ISO 14001 requirements. For such, a survey research has been carried out in Brazilian industrial companies certified by ISO 14001. We have identified the main performance factors by leading practices and variables of Cleaner Production that contribute to the compliance with the standard requirements by companies. Thus, it has been noted that Cleaner Production is an important strategy for the preparation of companies for certification as well as for improving their environmental performance. 相似文献
43.
44.
O. PostolacheAuthor Vitae H. Geirinhas Ramos Author VitaeA. Lopes Ribeiro Author Vitae 《Computer Standards & Interfaces》2011,33(2):191-200
This work presents an eddy-current testing system based on a giant magnetoresistive (GMR) sensing device. Non-destructive tests in aluminum plates are applied in order to extract information about possible defects: cracks, holes and other mechanical damages. Eddy-current testing (ECT) presents major benefits such as low cost, high checking speed, robustness and high sensitivity to large classes of defects. Coil based architecture probes or coil-magnetoresistive probes are usually used in ECT. In our application the GMR sensor is used to detect a magnetic field component parallel to a plate surface, when an excitation field perpendicular to the plate is imposed. A neural network processing architecture, including a multilayer perceptron and a competitive neural network, is used to classify defects using the output amplitude of the eddy-current probe (ECP) and its operation frequency. The crack detection, classification and estimation of the geometrical characteristics, for different classes of defects, are described in the paper. 相似文献
45.
Chuanjun Liu Marcus C. Lopes Sascha A. Pihan Daniela Fell Mordechai Sokuler Hans-Jürgen Butt Günter K. Auernhammer Elmar BonaccursoAuthor vitae 《Sensors and actuators. B, Chemical》2011,160(1):32
We present a method to measure the absorption of water molecules from the liquid and the vapour phase into polymer nano-films and the diffusion inside these films. Film thickness can be down to 45 nm. To demonstrate the possibilities of this method we use polymer films that are deposited on the upper side of a silicon cantilever by plasma polymerization of norbornene. When a microdrop of water is deposited onto the initially straight cantilever, the drop causes the cantilever to bend while it evaporates. Evaporation of such small water drops usually takes less than a second. An upwards bending is due to capillary forces and a downwards bending is due to the diffusion of water into the polymer film – and the consequent volume expansion (swelling) of the film. The magnitude of the capillary forces and the extent of swelling continuously change during drop evaporation. When drop evaporation is over the cantilever returns to its initial straight position. We simulate the time dependent bending with a numerical model that qualitatively agrees with the experiment. From the time dependence of cantilever bending we are able to determine the diffusion coefficient of water in the thin polymer film. 相似文献
46.
Rodrigo Costa Mateus Thiago Luís Lopes Siqueira Valéria Cesário Times Ricardo Rodrigues Ciferri Cristina Dutra de Aguiar Ciferri 《Distributed and Parallel Databases》2016,34(3):425-461
Cloud computing systems handle large volumes of data by using almost unlimited computational resources, while spatial data warehouses (SDWs) are multidimensional databases that store huge volumes of both spatial data and conventional data. Cloud computing environments have been considered adequate to host voluminous databases, process analytical workloads and deliver database as a service, while spatial online analytical processing (spatial OLAP) queries issued over SDWs are intrinsically analytical. However, hosting a SDW in the cloud and processing spatial OLAP queries over such database impose novel obstacles. In this article, we introduce novel concepts as cloud SDW and spatial OLAP as a service, and afterwards detail the design of novel schemas for cloud SDW and spatial OLAP query processing over cloud SDW. Furthermore, we evaluate the performance to process spatial OLAP queries in cloud SDWs using our own query processor aided by a cloud spatial index. Moreover, we describe the cloud spatial bitmap index to improve the performance to process spatial OLAP queries in cloud SDWs, and assess it through an experimental evaluation. Results derived from our experiments revealed that such index was capable to reduce the query response time from 58.20 up to 98.89 %. 相似文献
47.
We thoroughly study the behavioural theory of epi, a ??-calculus extended with polyadic synchronisation. We show that the natural contextual equivalence, barbed congruence, coincides with early bisimilarity, which is thus its co-inductive characterisation. Moreover, we relate early bisimilarity with the other usual notions, ground, late and open, obtaining a lattice of equivalence relations that clarifies the relationship among the ??standard?? bisimilarities. Furthermore, we apply the theory developed to obtain an expressiveness result: epi extended with key encryption primitives may be fully abstractly encoded in the original epi calculus. The proposed encoding is sound and complete with respect to barbed congruence; hence, cryptographic epi (crypto-epi) gets behavioural theory for free, which contrasts with other process languages with cryptographic constructs that usually require a big effort to develop such theory. Therefore, it is possible to use crypto-epi to analyse and to verify properties of security protocols using equational reasoning. To illustrate this claim, we prove compliance with symmetric and asymmetric cryptographic system laws, and the correctness of a protocol of secure message exchange. 相似文献
48.
Distributed planning and control systems for the virtual enterprise: organizational requirements and development life-cycle 总被引:9,自引:2,他引:7
Anto´nio Lucas Soares Ame´rico Lopes Azevedo Jorge Pinho de Sousa 《Journal of Intelligent Manufacturing》2000,11(3):253-270
This paper describes the requirements analysis and system specification of an Order Promise module to be used as part of a broader Decision Support System for production and operations planning of a Virtual Enterprise. This work is part of a broader project with a particular focus on the microelectronics industry which is a good example of Virtual Enterprise, and where a quick response to the customers needs and to unpredictable changes in production conditions is considered a major factor for success. First, the analysis and specification are presented within a development framework that involves the study of organizational issues of semiconductor enterprises. The use of ontological engineering for supporting the communication and shared understanding of the system concepts is explained and a virtual enterprise ontology is outlined. Following the clarification of the concept of virtual enterprise, the generic techno-organizational requirements for the information system are derived. Finally, a specification of the global planning module and a more detailed one regarding the order promise module is presented. 相似文献
49.
Summary In 1985 China began the reform of its Science & Technology (S&T) sector inherited from the planned economy. To disclose the
impact of the drawn-out reform on the efficiency of the whole sector, we measure the scientific productivity of China's S&T
institutes. The analysis is based on R&D input and output data at the country aggregate and provincial level. We utilize Polynomial
Distributed Lag model to uncover the structure of the lag between R&D input and output. The findings reveal that the growth
rate of scientific productivity of China's S&T institutes has been negative since the 1990s. 相似文献
50.
This paper reports on the affect of lead content on the absorption and emission spectra of the Ho3+ ion doped lead-zinc-borate glasses in the composition (mol%) of (20 − x)PbO-20ZnO-(59 + x)B2O3-1.0Ho2O3 where x = 0, 5,10,15 of PbO content with λexc = 405 nm. The experimental absorption band energies have satisfactorily been correlated with the theoretical results with an r.m.s deviation of zero with the following correction factors obtained by a least square fit analysis: ΔE1 = 348.495936 cm− 1, ΔE2 = 1.436043 cm− 1, ΔE3 = 46.481575 cm− 1, Δξ4f = − 28.512979 cm− 1, Δα = 55.508936 cm− 1, Δβ = − 1394.339908 cm− 1 and Δγ = 1208.424336 cm− 1. By applying the Judd-Ofelt intensity parameter Ω2 has been found to be linearly decreasing with the PbO content from 5 to 10 mol% and then increasing. And also radiative (A, AT, β, τr) characteristic factors of the luminescent transitions (5I8 ← 5F3,4,5 and 5S2) of the glasses have been evaluated. Stimulated emission cross-sections (σpE) of the measured emission transitions of holmium glasses have also been computed. 相似文献