Hydrothermally Synthesizing Nanospheres of Pd Loaded TiO<Subscript>2</Subscript> for Photocatalytically Reducing CO<Subscript>2</Subscript> in Isopropanol to Isopropyl Formate

Photocatalytic reduction of CO₂ was carried out on villiform spherical catalysts of Pd-TiO₂ in isopropanol solution. The catalysts were synthesized by hydrothermal method, their structures, morphologies and optical absorption properties were characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) and UV-vis absorption spectroscopy (UV-vis). The photocatalytic activities with different loading amounts and morphologies were evaluated for determining the dominant effect and optimizing the catalyst preparation. Based on a villiform spherical TiO₂ with the largest specific surface area in our experiments, we prepared a set of catalysts with various loading amounts of palladium and tested them by bubbling CO₂ through the slurry of catalyst and isopropanol. The highest formation rate of isopropyl formate was 276.6 μmol/g·cat/h. Eventually we proposed the reaction mechanism.     

First-principles Investigation of the Structural,Electronic and Elastic Properties of Al2Ca and Al4Sr Phases in Mg-Al-Ca（Sr） Alloy

First-principles calculations have been carried out to investigate the structural stabilities, electronic structures and elastic properties of Mg17Al12, Al2Ca and Al4Sr phases. The optimized structural parameters are in good agreement with the experimental and other theoretical values. The calculated formation enthalpies and cohesive energies show that Al2Ca has the strongest alloying ability, and Al4Sr has the highest structural stability. The densities of states （DOS）, Mulliken electronic populations, and electronic charge density difference are obtained to reveal the underlying mechanism of structural stability. The bulk modulus, shear modulus, Young＇s modulus, and Poisson＇s ratio are estimated from the calculated elastic constants. The mechanical properties of these phases are further analyzed and discussed. The Gibbs free energy and Debye temperature are also calculated and discussed.     

Thermophysical properties of difluoromethane (HFC-32)

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集成光场三维显示亮度均匀性校正方法

针对集成光场三维显示亮度不均匀的问题,提出基于光场重构的提高三维显示亮度均匀性的方法.该方法通过调制每台投影机投射画面各颜色通道的各处亮度,从而提高三维画面的整体亮度均匀性.实验样机主要由76台小投影机构成的投影阵列和光场调控屏幕组成,通过实验验证了提出的改善亮度均匀性的方法.实验结果表明,采用该方法可以克服现有基于多投影的光场三维显示中画面亮度不均匀的缺陷.     

风机远程监测与故障诊断系统的研究

在比较了CORBA技术与OPC技术各自优缺点的基础上,提出采用OPC技术与SOAP/WebSer-vice相结合的方法进行风机的远程监测与故障诊断系统开发,介绍了系统的硬件及软件组成.     

灰土挤密桩成孔过程中孔周土体的应力分析

基于平面应变问题的假定前提,应用弹塑性理论,分析了灰土挤密桩成孔过程中孔周土体的应力变化,建立了孔周土体有效挤密半径的计算公式．     

高职人才培养目标的演进与重构

随着人们对职业教育认识的不断深入,我国高职教育自产生30多年来,人才培养目标进行了多次调整,从高层次实用技术人才到高技能人才,再到高素质技术技能型人才.这种变化反映了我国经济社会不同发展阶段对教育的不同要求.根据高职人才培养目标定位中存在的实际问题,我们试图对其进行重新建构.笔者认为,在现代信息社会中,具有巨大发展潜力的现代高素质技术人才,是高职人才培养目标的必然选择.     

基于水声信道的TE—LCMMSE均衡算法仿真研究

论述了应用于水声信道的Turbo均衡技术,针对水声信道多径衰落引起的码间干扰,提出了一种低复杂度的TE-LCMMSE算法,并在给定的水声信道下进行了仿真,仿真结果表明;基于软输入软输出的TE-LCMMSE均衡算法与理论最优的Map算法相比,在误码率为10-5时性能接近;与Max-Log-Map算法相比,具有近3 dB的性能增益,且算法复杂性大大降低,有效地提高了水声通信系统可靠性.     

淬火处理对(Ti-Fe)-Al-C体系TiCp/Fe复合材料组织及性能的影响

采用淬火工艺对原位TiC颗粒增强Fe基复合材料进行了热处理。热处理后,复合材料的相组成不变,但是TiC颗粒由方形变成球形,固溶析出的TiC颗粒在某些TiC颗粒的表面沉积,使后者粗化;另一些方形颗粒的尖角处溶解形成直径更小的球形TiC颗粒。复合材料的硬度和耐磨性均提高。轻载条件下,复合材料的耐磨性能更好。     

Preparation and microstructure of glass-ceramics and ceramic composite materials

The technology and microstructure of glass-ceramics and ceramic composite materials were studied. A suitable ceramic body was chosen on the basis of the sintering temperature of CaO-Al2O3-SiO2 system glass-ceramics. According to the expansion coefficient of the ceramic body, that of CaO-Al2O3-SiO2 system glass-ceramics was adjusted, fl-wollastonite was found present as the major crystalline phase in glass- ceramic. The CaO-Al2O3-SiO2 system glass-ceramic layer and ceramic body could be sintered together by adjusting the sintering period. The compositions of glass-ceramic layer and ceramic body diffuse mutually at 1 100 ℃, resulting in an interface between them. To achieve good sintered properties of glass-ceramics and the chosen ceramic body, at least a four-hour sintering time is used.