复合改性纳米碳酸钙/CPE对PVC的协同增韧增强

用改性剂在水相中对纳米碳酸钙进行表面改性,样品烘干后在捏合机中用固相法采用自制的表面改性剂对水相法改性的纳米碳酸钙进一步进行包覆改性;制备了一种具有反应活性的新型改性纳米碳酸钙(R-CaCO3),并对R- CaCO3进行表征。结果表明,R-CaCO3亲油性增加,在液体石蜡中分散性改善,改性剂与碳酸钙之间形成化学吸附; 同时制备了PVC／CPE／R-CaCO3]纳米复合材料,发现R-CaCO3与CPE对PVC有明显的协同增韧增强作用,同时还提高了体系的耐热性,且体系的黏度基本不变。     

A new characterization procedure for aqufous solutions with unknown composition

A new characterization procedure for aqueous solutions with unknown composition was proposed based on the binomial distribution of TOC (total organic carbon) fraction in terms of a characterizing variable, the Freundlich coefficient, k, so that the solution in question can be described by a finite number of pseudo.species identified with a certain k value. The validity and computational accuracy of this procedure has been demonstrated by characterizing three sets of experimental data chosen from different sources. Predictions based on this procedure yielded acceptable results that agreed closely with experimental data.     

Anisotropic geodesics for live‐wire mesh segmentation

We present an interactive method for mesh segmentation that is inspired by the classical live‐wire interaction for image segmentation. The core contribution of the work is the definition and computation of wires on surfaces that are likely to lie at segment boundaries. We define wires as geodesics in a new tensor‐based anisotropic metric, which improves upon previous metrics in stability and feature‐awareness. We further introduce a simple but effective mesh embedding approach that allows geodesic paths in an anisotropic path to be computed efficiently using existing algorithms designed for Euclidean geodesics. Our tool is particularly suited for delineating segmentation boundaries that are aligned with features or curvature directions, and we demonstrate its use in creating artist‐guided segmentations.     

反应型纳米碳酸钙补强NR的研究

采用具有反应性的改性剂,在纳米碳酸钙水悬浮液中进行改性,制备一种新型改性纳米碳酸钙（简称M-CaCO3）及其与NR的复合材料,对改性前后纳米碳酸钙的结构和形态进行分析,并对NR/纳米碳酸钙复合材料的结构和性能进行研究.结果表明,与未改性纳米碳酸钙相比,改性纳米碳酸钙的透过率下降,在正己烷中的分散性明显提高;NR/M-CaCO3复合材料具有良好的界面相容性和耐热分解性能、较高的交联密度以及优良的综合物理性能和耐老化性能,M-CaCO3的最佳用量为8份.     

透明香皂的研制

介绍了生产透明香皂的新配方和新工艺 ,提出了透明香皂的企业标准。新工艺用丙二醇取代传统工艺所用的乙醇做溶剂 ,生产周期大为缩短。采用速冻隧道设备 ,可方便地实现不同品种的切换 ,操作方便 ,设备投资少 ,产品综合成本低 ,具有较大的工业应用价值     

Flexible protocol for quantum private query based on B92 protocol

Jakobi et al. for the first time proposed a novel and practical quantum private query (QPQ) protocol based on SARG04 (Scarani et al. in Phys Rev Lett 92:057901, 2004) quantum key distribution protocol (Jakobi et al. in Phys Rev A 83:022301, 2011). Gao et al. generalized Jakobi et al’s protocol and proposed a flexible QPQ protocol (Gao et al. in Opt Exp 20(16):17411–17420, 2012). When $\theta <\pi /4$ , Gao et al’s protocol exhibits better database security than Jakobi et al’s protocol, but has a higher probability with which Bob can correctly guess the address of Alice’s query. In this paper, we propose a flexible B92-based QPQ protocol. Although SARG04 protocol is a modification of B92 protocol and can be seen as a generalization of B92 protocol, our protocol shows different advantages from Gao et al’s protocol. It can simultaneously obtain better database security and a lower probability with which Bob can correctly guess the address of Alice’s query when $\theta <\pi /4$ . By introducing entanglement, the proposed QPQ protocol is robust against channel-loss attack, which also implies lower classical communication complexity. Similar to Gao et al’s protocol, it is flexible, practical, and robust against quantum memory attack.     

醇酮装置废酸水中副产物的回收利用探讨

分析了醇田装置副产物的生成过程和借鉴国外辞酮装置废酸水和皂化废碱液的回收利用技术，提出了合并浓缩、脱过氧化氢生产混合二元酸及硝酸后氧化、结晶、真空间歇精馏相结合分高己二酸、戊二酸、丁二酸的两种回收利用的工艺方法，并提出了两个工业化装置的设想，对治理废酸水提出了建设性意见。     

描述逻辑FL0概念及术语公理集的表达能力刻画

表达能力和推理复杂性是一个逻辑的两个重要特征,也是一对相互制约的关系。解释之间的互模拟关系是从语义的角度刻画逻辑表达能力的一个有效途径,其代表性的结果是命题模态逻辑表达能力的刻画定理-van Benthem刻画定理。文中给出了描述逻辑FL0(含构造子:原子概念、顶概念、概念交、全称量词约束)的模拟关系,建立了FL0中概念和术语公理集的表达能力刻画定理,即一阶逻辑公式与FL0概念和术语公理集等价的充分必要条件。上述结果为寻求表达能力与推理复杂性之间的最佳平衡提供了有效的支持。     

Syntheses and biological activities of polymers containing methacryloyl‐2‐oxy‐1,2,3‐propanetricarboxylic acid or 5‐fluorouracil

A series of novel copolymers, poly(methacryloyl‐2‐oxy‐1,2,3‐propanetricarboxylic acid‐co‐exo‐3,6‐epoxy‐1,2,3,6‐tetrahydrophthalic acid) [poly(MTCA‐co‐ETAc)], poly(methacryloyl‐2‐oxy‐1,2,3‐propanetricarboxylic acid‐co‐hydrogenethyl‐exo‐3,6‐epoxy‐1,2,3,6‐tetrahydrophthalate) [poly(MTCA‐co‐HEET)], and poly(methacryloyl‐2‐oxy‐1,2,3‐propanetricarboxylic acid‐co‐α‐ethoxy‐exo‐3,6‐epoxy‐1,2,3,6‐tetrahydrophthaloyl‐5‐fluorouracil) [poly(MTCA‐co‐EETFU)], were prepared from corresponding monomers by photopolymerizations at 25°C for 48 h. The polymers were identified by FTIR, ¹H‐NMR, and ¹³C‐NMR spectroscopies. The number‐average molecular weights of the fractionated polymers determined by GPC were in the range from 9400 to 14,900 and polydispersity indices were 1.2–1.4. The in vitro IC₅₀ values of polymers against mouse mammary carcinoma (FM3A), mouse leukemia (P388), and human histiocytic lymphoma (U937) as cancer cell lines and mouse liver cells (AC2F) as a normal cell line were much higher compared to that of 5‐fluorouracil (5‐FU). The in vivo antitumor activities of monomers and polymers against mice bearing sarcoma 180 tumor cell line were better than those of 5‐FU. The inhibition of DNA replication and antiangiogenesis activities of MTCA and copolymers were better compared to those of 5‐FU. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 57–64, 2004     

Enzyme catalyzed durable and authentic oriental lacquer: a natural microgel-printable coating by polysaccharide–glycoprotein–phenolic lipid complexes

The chemistry and technology of oriental lacquer, proof of long-term durability by a laboratory test, and morphological features of the closely packed shell (polysaccharides–glycoproteins)–core (polymerized urushiol) microgel particles, which are chiefly responsible for degradation due to efflorescence outdoors, are described. The dimerization mechanism of urushiol was demonstrated by separation of over 20 urushiol dimer derivatives. Physiological dimerization of urushiol in the lacquer is very much influenced by the humidity in drying, and the interaction of semiquinone radicals with metal ions, hydrophilic polysaccharides and amphipathic glycoproteins contained in the lacquer. A mechanism for renewable oriental lacquer is proposed, involving harmony of technology and nature within the lacquer tree plantations in south-east Asia. A brief review of studies of lacquer chemistry and synthetic coatings is given.