German codes and standards concerning metallic nuclear power plant components — Present state and trends expected

The German codes and standards for the design of nuclear power plants are the KTA Safety Standards. For integrating them into the international code activities the following aspects are presented: Organisation and function of the KTA, extend of standard activities, standards for metallic components, bases for the standard development, structure of a representative standard, comparison with international standards, and current activities in the standard work.     

The herbicide propachlor--14 C synthesis, toxicologic problems and methodology studies on the determination of residues in corn, potatoes, water and soil

Using the synthesized agent propachlor (N-isopropyl-2-chloroacetanilid) labelled with 14C, methodical investigations revealed an extremely high steam volatility not being assumed before because of the low vapour pressure. The method of steam distillation basing on this fact is of universal application to the processing of maize, potatoes, water, and soil, in which propachlor could be quantitatively determined by gas chromatography with a detection sensitivity of 0.02 ppm. Furthermore, this methods allows a simple purification of the raw product of synthesis containing impurities up to 20%. Propachlor codistilled with steam had a purity of more than 99%. Possibly, the high steam volatility of propachlor could have economic and toxicological consequences as to its application (volatilization in the open air with a high atmospheric humidity along with high temperatures). Therefore, an investigation of the steam volatility in the general screening programme for new agents is to be recommended in addition to the usual investigations of steam pressure.     

Stoichiometric dye-binding procedure for the determination of the reactive lysine content of soya bean protein

A new analytical method has been developed for the determination of the reactive lysine content of soya bean protein. The method is based on the reaction of the free basic groups of the protein with 1-phenylazo-2 naphthol-6,8 disulphonic acid. With regard to the stoichiometry of the procedure, it has been proved, contrary to earlier reports, that the basic amino acids, histidine, arginine and lysine, each combine with one mole of the dye. After acylation with propionic anhydride lysine alone loses its dye reactivity. The usefulness of the proposed method has been demonstrated by the determination of the reactive lysine content of several untreated, heat-treated and acid-treated soya bean samples. The results show that heat damage of about 5% in reactive lysine content can be measured in 1·5 h with good reproducibility.     

Effect of Methionine Supplementation on Nitrogen Balance in Infants Fed a Low-Cost Soy-Oats Formula

A nitrogen balance study, comparing a low-cost soy-oats infant formula with and without supplemental methionine, was carried out with infants of ages 3 - 26 months at a single equivalent level of nitrogen intake (approximately 850 mg/kg/day). Nitrogen retention was found to be unaffected by methionine supplementation. Com- parison of data obtained in this study with previous research re- vealed that a critical value for intake of total L-sulfur amino acids apparently exists in infants 3 - 26 months of age, below which methionine supplementation will increase nitrogen retention, but above which it will not. This value appears to coincide with that of 49 mg/kg/day recommended for infants by the FNB.     

Influence of weld misalignment and weld metal overmatch on the prediction of fracture in pipeline girth welds

$\text{J-}\text{integral}$ estimates using elastic-plastic finite element calculations, are shown to compare well with experimental results from single edge-notch bend (SENB) specimens made of X483 grade line pipe steel.The influence of weld misalignment and weld metal overmatch on fracture of cracked girth welds is predicted, also using elastic-plastic finite element calculations. Weld metal overmatch reduces plastic strain levels in the weld and appears beneficial in reducing $\text{J-}\text{integral}$ magnitudes. Predicted values of $\text{J-}\text{integral}$ are shown to increase with weld misalignment. However, $\text{J-}\text{integral}$ magnitudes near the critical value for crack growth initiation were only attained after considerable plastic straining at or near limit load. This result suggests that limit load calculations may be more appropriate for prediction of failure of cracked girth welds than conventional fracture techniques.     

Using precise data sets on farming and pesticide properties to verify a diffuse pollution hydrological model for predicting pesticide concentration.

Verification of a diffuse pollution model involves comparing results actually observed with those predicted by precise model inputs. Acquisition of precise model inputs is, however, problematic. In particular, when the target catchment is large and substantial estimation uncertainty exists, not only model verification but also prediction is difficult. Therefore, in this study, rice-farming data were collected for all paddy fields from all farmers in a catchment and pesticide adsorption and degradation rates in paddy field soil samples were measured to obtain precise model inputs. The model inputs successfully verified the model's capability to predict pesticide concentrations in river water. Sensitivity analyses of the model inputs elucidated the processes significantly affecting pesticide runoff from rice farms. Pesticide adsorption and degradation rates of the soil did not significantly affect pesticide concentrations, although pesticide discharge to river water accounted for less than 50% of the total quantity of pesticide applied to fields, possibly owing to pesticide adsorption and degradation. The timing of increases in pesticide concentrations in river water was affected mostly by the farming schedule, including the time of pesticide application and irrigation, and secondarily by rainfall events.     

Comparison of the efficacy of oxidative processes and flocculation for the removal of colour from Eop effluent.

Up to 30% of the released colour arising from bleached kraft pulp and paper production comes from the alkaline extraction stage. This waste stream can therefore be readily targeted to remove colour at source in mills where improved colour management is required. The efficacy of five advanced oxidative treatment and physico-chemical technologies in removing colour from a typical Eop stage effluent was compared. The most effective oxidative treatment was peroxymonosulphate (79% colour removal in 15 minutes). Ozone and TAML treatments removed 74% and 58% of colour respectively within 30 minutes. In comparison, hydrogen peroxide alone was only able to remove 35% of the colour over 4 hours. Coagulation with polyaluminium chloride achieved 89% colour removal within 5 minutes. However, this treatment produced an undesirable sludge, and may cause toxicity in the treated wastewater. Overall, colour removal ability of the five technologies ranked from highest to lowest was polyaluminium chloride > peroxymonosulfate > ozone > TAML > hydrogen peroxide. Other factors, such as operating costs, feedstock modification and capital infrastructure, also need to be taken into account when selecting the most suitable colour management option.     

Ochratoxin A in pork kidneys--description of a method

A rapid procedure for the isolation and clean-up on a silica gel column is described for the determination of Ochratoxin A from pork kidneys. The detection limit is 0.3 microgram/kg.     

Microstructure of Selected Binary Food Powder Mixtures

Binary mixtures of sugar, citric acid, malic acid, soy protein and starch, after exposure to various relative humidities, were analyzed by Scanning Electron Microscopy (SEM). It is shown that depending on interparticle surfaceaffinity, concentration and relative humidity, the mixtures could be random, partially random, ordered or partially ordered. The type of bridging, between the aggregated particles depended on their chemical species and the availability of surface moisture.