首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   6288篇
  免费   429篇
  国内免费   39篇
电工技术   119篇
综合类   6篇
化学工业   1926篇
金属工艺   206篇
机械仪表   184篇
建筑科学   213篇
矿业工程   14篇
能源动力   337篇
轻工业   606篇
水利工程   50篇
石油天然气   99篇
无线电   613篇
一般工业技术   1151篇
冶金工业   366篇
原子能技术   41篇
自动化技术   825篇
  2023年   69篇
  2022年   171篇
  2021年   228篇
  2020年   167篇
  2019年   238篇
  2018年   347篇
  2017年   254篇
  2016年   263篇
  2015年   214篇
  2014年   261篇
  2013年   541篇
  2012年   314篇
  2011年   370篇
  2010年   323篇
  2009年   314篇
  2008年   277篇
  2007年   209篇
  2006年   210篇
  2005年   143篇
  2004年   131篇
  2003年   167篇
  2002年   132篇
  2001年   93篇
  2000年   107篇
  1999年   95篇
  1998年   143篇
  1997年   85篇
  1996年   69篇
  1995年   56篇
  1994年   43篇
  1993年   49篇
  1992年   33篇
  1991年   38篇
  1990年   27篇
  1989年   36篇
  1988年   32篇
  1987年   50篇
  1986年   37篇
  1985年   32篇
  1984年   39篇
  1983年   34篇
  1982年   27篇
  1981年   28篇
  1980年   38篇
  1979年   20篇
  1978年   25篇
  1977年   26篇
  1976年   34篇
  1975年   26篇
  1973年   21篇
排序方式: 共有6756条查询结果,搜索用时 13 毫秒
71.
Super-resolution: a comprehensive survey   总被引:3,自引:0,他引:3  
Super-resolution, the process of obtaining one or more high-resolution images from one or more low-resolution observations, has been a very attractive research topic over the last two decades. It has found practical applications in many real-world problems in different fields, from satellite and aerial imaging to medical image processing, to facial image analysis, text image analysis, sign and number plates reading, and biometrics recognition, to name a few. This has resulted in many research papers, each developing a new super-resolution algorithm for a specific purpose. The current comprehensive survey provides an overview of most of these published works by grouping them in a broad taxonomy. For each of the groups in the taxonomy, the basic concepts of the algorithms are first explained and then the paths through which each of these groups have evolved are given in detail, by mentioning the contributions of different authors to the basic concepts of each group. Furthermore, common issues in super-resolution algorithms, such as imaging models and registration algorithms, optimization of the cost functions employed, dealing with color information, improvement factors, assessment of super-resolution algorithms, and the most commonly employed databases are discussed.  相似文献   
72.
Medical data feature a number of characteristics that make their classification a complex task. Yet, the societal significance of the subject and the computational challenge it presents has caused the classification of medical datasets to be a popular research area. A new hybrid metaheuristic is presented for the classification task of medical datasets. The hybrid ant–bee colonies (HColonies) consists of two phases: an ant colony optimization (ACO) phase and an artificial bee colony (ABC) phase. The food sources of ABC are initialized into decision lists, constructed during the ACO phase using different subsets of the training data. The task of the ABC is to optimize the obtained decision lists. New variants of the ABC operators are proposed to suit the classification task. Results on a number of benchmark, real-world medical datasets show the usefulness of the proposed approach. Classification models obtained feature good predictive accuracy and relatively small model size.  相似文献   
73.
Miscible polymer blends based on various ratios of poly(vinyl acetate) (PVAc) and poly(methyl methacrylate) (PMMA) were prepared in film form by the solution casting technique using benzene as a common solvent. The thermal decomposition behavior of these blends and their individual homopolymers before and after γ‐irradiation at various doses (50–250 kGy) was investigated. The thermogravimetric analysis technique was utilized to determine the temperatures at which the maximum value of the rate of reaction (Tmax) occurs and the kinetic parameters of the thermal decomposition. The rate of reaction curves of the individual homopolymers or their blends before or after γ‐ irradiation displayed similar trends in which the Tmax corresponding to all polymers was found to exist in the same position but with different values. These findings and the visual observations of the blend solutions and the transparency of the films gave support to the complete miscibility of these blends. Three transitions were observed along the reaction rate versus temperature curves; the first was around 100–200°C with no defined Tmax, which may arise from the evaporation of the solvent. The second Tmax was in the 340–380°C range, which depended on the polymer blend and the γ‐irradiation condition. A third transition was seen in the rate of reaction curves only for pure PVAc and its blends with PMMA with ratios up to 50%, regardless of γ‐ irradiation. We concluded that γ‐irradiation improved the thermal stability of PVAc/PMMA blends, even though the PMMA polymer was degradable by γ irradiation. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1773–1780, 2006  相似文献   
74.
Electrosynthesis of peroxodiphosphate ions (P2O84–) was performed in 2m K3PO4, 1m K2HPO4 medium, using a platinum anode. The results showed that under conditions of potentiostatic polarization at constant potential, the reaction rate reaches a maximum value of 125mAcm–2 and a faradaic yield of 30%. From about 1.9V, the reaction kinetics are increasingly inhibited as the potential shifts positively. Rapid scanning potential voltammetry was used to characterize the oxidation state of the electrode surface. This method shows that the growth of (PtO) and (PtO2 or PtO3) oxides depend on the applied potential. It also establishes a correlation between the inhibition of P2O84– ion electrosynthesis and the oxide coating surface. When 2×10–3m KSCN is added to the solution, some oxygen evolution sites are selectively blocked and oxide occurs at more positive potential values. Consequently, the rate of peroxodiphosphate ion formation and the faradaic efficiency are increased to 380mAcm–2 and 75%, respectively. Under pulsed potential conditions it was possible to reach 1200mAcm–2 for P2O84– ion electrosynthesis with a faradaic yield of 82%.  相似文献   
75.
Global hydrodynamic characteristics, liquid mixing and gas‐liquid mass transfer for a 63 L split‐rectangular airlift reactor were studied. Correlations for gas holdup and overall liquid circulation velocity were derived for the air‐water system as a function of the specific power input; these were compared to data and correlations for reactor volumes between 4.7 L and 4600 L. A partial recirculation of small bubbles in the riser was observed when Ugr > 0.03 m/s, which was attributed to the use of a single‐orifice nozzle as the gas phase distributor. The dimensionless mixing time and the overall axial dispersion coefficient were nearly constant for the range of gas flow rates studied. However, values of KL/dB were greater than those reported in previous studies and this is caused by the partial recirculation of the gas phase in the riser. While scale effects remain slight, the use of a gas distributor favouring this partial recirculation seems adequate for mass transfer in split‐rectangular airlift reactors.  相似文献   
76.
Although leather has a number of desirable properties such as thermal stability and fire retardancey, in addition to high toughness, it has a few drawbacks such as weight, high water absorption, poor soil and rot resistance, and nonuniformity. If these defects are overcome, leather's usefulness would be further enhanced and its competitive position with respect to synthetics would increase. This study reports the physical and mechanical properties of buffalo leather after chemical graft copolymerization with ethyl acrylate, butyl acrylate, and 2‐ethyl hexyl acrylate using benzoyl peroxide as an initiator. The optimum conditions for grafting (e.g., monomer and initiator concentrations, temperature and time of grafting, and solvent leather ratio) were extensively investigated. The study achieved outstanding properties for buffalo leather in reduction of water uptake after grafting, especially on using 2‐ethyl hexyl acrylate and butyl acrylate monomers. FT‐IR and solid 13C‐NMR for leather before and after grafting confirmed the grafting process.© 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1478–1483, 2003  相似文献   
77.
A novel mechanism to form binary polymer blends is through phase separation by spinodal decomposition in the unstable region of the phase diagram. The present work investigates the effects of thermally‐induced phase separation by spinodal decomposition on the morphology development of liquid crystalline polymer/polycarbonate blends. Moreover, a thermodynamic binary phase diagram is obtained using a twin‐screw extruder at various processing melt temperatures. Differential scanning calorimetry and scanning electron microscopy were used to study the miscibility of the blends and the resulting morphology. A thermodynamic binary phase diagram exhibiting a lower critical solution temperature was obtained. The droplet size distribution of the blend was also obtained and discussed in light of the Cahn‐Hilliard theory.  相似文献   
78.
The functional properties of Caryodendron orinocense protein product were investigated and compared with those of soybean (Glycina maxima). The product protein content was 24.47 g/100 g (Nx6.25). Solubility increased at both sides of the isoelectric point (pH 4.0) and with increased NaCl concentration up to 0.5M. Compared with soybean flour (50% protein), the protein product exhibited higher water and oil absorption, but lower emulsifying activity, emulsion stability, foaming capacity, and foam stability, the last one increase at higher pH. Emulsifying activity, foaming capacity, and foam stability were ionic strength dependent. C. orinocense protein product increased its emulsifying activity steadily from 0.05M to 0.75M NaCl, while it remained almost constant for soybean flour. Foaming capacity increased drastically at pH 10. The minimum time and concentration to form a gel was 20% in 4 min and 10% in 8 min for the Caryodendron protein product and soybean flour, respectively. The bulk density was 0.5056+/-0.0041 g/mL.  相似文献   
79.
An interfacial grafting radical polymerization method for amphiphilic comb copolymer and shell crosslinked polymer nanocapsules was reported. Macropolyradicals on a water soluble long chain polyamine were generated with hydrogen peroxide in the water phase and subsequent grafting radical polymerization of a vinylic monomer at the water/oil interface proceeded at 65°C. In the presence of a crosslinker, the resulting graft copolymer formed a defined core‐shell structure with hydrophilic aqueous core functionalized by the polyamine and a hydrophobic crosslinked polymer shell. The structure of the core‐shell material was characterized by NMR, FTIR, DSC, TGA, SEM, TEM, and the mechanism of the graft polymerization is proposed. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1905–1911, 2007  相似文献   
80.
The effects of poly(vinyl alcohol) (PVA), poly(acrylic acid) (PAA), sodium polyacrylate (NaPA), poly(ethylene glycol) (PEG), pectin (P), and carboxymethyl cellulose (CMC) on the corrosion of cadmium in a 0.5M hydrochloric acid (HCl) solution were studied with both electrochemical impedance spectroscopy and Tafel plot techniques. Measurements were carried out at cathodic, open‐circuit, and anodic potentials. All the investigated polymers had inhibitory effects on both the cathodic (except for NaPA, P, and CMC) and anodic processes, with a predominant anodic inhibiting action. However, NaPA, P, and CMC exhibited a slight cathodic inhibiting action only at higher polymer concentrations. This behavior may be attributed to the very weak adsorbability of the polymers on the cathodic sites. Because PVA and PEG had hydroxy groups, there could be bridging between the polymer and the surface, resulting in an inhibiting effect in the HCl solution. However, PVA had much greater adsorbability on the surface than PEG at the anodic potential. The adsorption of most of the polymers obeyed a Temkin adsorption isotherm, and this indicated indicating that the main process of inhibition was adsorption. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 866–871, 2003  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号