Synthesis and properties of novel side-chain-sulfonated polyimides from bis[4-(4-aminophenoxy)-2-(3-sulfobenzoyl)]phenyl sulfone

A novel side-chain-sulfonated aromatic diamine of bis[4-(4-aminophenoxy)-2-(3-sulfobenzoyl)]phenyl sulfone (BAPSBPS) was synthesized. Sulfonated copolyimides were synthesized by random and sequenced block copolymerization of 1,4,5,8-naphthalene tetracarboxylic dianhydride, BAPSBPS and nonsulfonated diamine. They displayed good solubility in common aprotic solvents and high desulfonation temperature of 350 °C, suggesting the high stability of sulfonic acid groups. The reduced viscosity was in the range of 0.4-1.8 dl/g at 0.5 g/dl and 35 °C. Flexible and tough membranes with reasonably high mechanical strength were prepared. They showed anisotropic membrane swelling with larger swelling in thickness than in plane. They displayed reasonably high proton conductivity (σ), taking their lower ion exchanging capacity (IEC) into account. For example, the membrane with IEC of 1.54 mequiv/g showed σ values of 81 and 11 mS/cm in water and 70% RH, respectively, at 60 °C.     

Ba-eu (barium-europium)

Several thermodynamic models for calculating binary phase diagrams published in the literature have been reevaluated. Problems in some of these models are already evident in the models themselves and may also be seen in the resulting calculated phase diagrams. When a calculation is attempted, thermodynamic models with quite different formulations may result in very similar proposed phase diagrams. In such cases, if experimental data of a binary phase diagram can be represented reasonably well by several different thermodynamic models, a simpler model often provides the clearest insight into the basic properties of the system. If a calculated phase diagram results in unusual phase relationships, the adopted thermodynamic model may be inappropriate or may involve unrealistic parameters. If the thermodynamic model is clearly unrealistic and yet the calculated phase diagram appears to be normal, errors in calculation or in interpretation may be suspect. Various examples of unlikely combinations of thermodynamic models and phase diagrams are discussed.     

Pu-Zr (plutonium-zirconium)

Journal of Phase Equilibria -     

β-phase transformation and thermoelectric power in FeSi2 and Fe2Si5 based alloys containing small amounts of Cu

The effects of Cu addition on the β phase formation rate and the thermoelectric power in various FeSi₂ and Fe₂Si₅ based alloys was examined. The peritectoid reaction (a+→β) in FeSi₂ alloys was initially enhanced by the addition of Cu but it became slower for longer annealing times. The retained metallic ε was harmful for the thermoelectric power. The inherent thermoelectric properties of (FeSi₂)_99−XMn₁Cu_X (X=0–1.O at.%), (FeSi₂)_99−X Co₁Cu_X (X=0–1.0 at.%) alloys were attained after the elimination of ε. In the case of eutectoid reaction (→β+Si). Differential thermal analysis, X-ray diffraction and microscopic observation clearly confirmed that the eutectoid reaction rate was drastically enhanced by the addition of a small amount of Cu and its rate decreased with decreasing Cu content. The rate also depends on the annealing temperature and reached a maximum at about 1073 K for most alloys. The addition of only 0.1 at.% Cu was still very effective even in Mn or Co doped alloys. The thermoelectric power of these alloys increased very quickly with annealing time. Their final values decreased with Cu content and saturated at 0.2 at.% Cu. The value of the 0.1 at.% Cu added alloy was higher than that of both the conventional p- and a-type FeSi₂ based alloys. These results suggest that the Fe₂Si₅ alloys with a small amount of Cu may be attractive as new thermoelectric materials.     

The Gold-Inert gas systems

Journal of Phase Equilibria -     

Self-identification algorithm for zeolite-based thermal capacity gas sensor

Microsystem Technologies - We demonstrate a new operation mode of thermal gas sensor based on thermal capacity extraction with identification algorithm. The system is a silicon microstructure...