An equation for estimating the diffusion coefficient of electrolytes in ion exchange membranes

When operating electrodialysis equipment with ion exchange membranes, the diffusion coefficient in the membrane must be predetermined. We derived an equation to estimate the diffusion coefficient with only one unknown factor by assuming that the mobility of counter-ions in the membrane was proportional to that in the solution.The diffusion experiments were studied by a stirring cell method. The value of an apparent permeability coefficient became constant after 7200 seconds. The value was approximately equal to that of the permeability coefficient in the membrane at 200 rpm. The diffusion coefficients in the membranes were obtained for various electrolytes. The unknown factor was determined by comparing the theoretical with the experimental value of the diffusion coefficient, and a final equation to estimate the diffusion coefficient was derived. The diffusion coefficient in the membrane increased slightly with the increase of the electrolyte concentration.     

Quantitative hydrogen analysis of zircaloy-4 in laser-induced breakdown spectroscopy with ambient helium gas

This experiment was carried out to address the need for overcoming the difficulties encountered in hydrogen analysis by means of plasma emission spectroscopy in atmospheric ambient gas. The result of this study on zircaloy-4 samples from a nuclear power plant demonstrates the possibility of attaining a very sharp emission line from impure hydrogen with a very low background and practical elimination of spectral contamination of hydrogen emission arising from surface water and water vapor in atmospheric ambient gas. This was achieved by employing ultrapure ambient helium gas as well as the proper defocusing of the laser irradiation and a large number of repeated precleaning laser shots at the same spot of the sample surface. Further adjustment of the gating time has led to significant reduction of spectral width and improvement of detection sensitivity to ~50 ppm. Finally, a linear calibration curve was also obtained for the zircaloy-4 samples with zero intercept. These results demonstrate the feasibility of this technique for practical in situ and quantitative analysis of hydrogen impurity in zircaloy-4 tubes used in a light water nuclear power plant.     

Group effect on ultimate lateral resistance of piles against uniform ground movement

In earthquake engineering, pile foundations are designed to withstand the lateral loading that results from large displacements due to ground movement caused by strong earthquakes. The distress and failure of superstructures occurs when the lateral load exceeds the ultimate lateral resistance of the piles. The aim of this study is to estimate the ultimate lateral resistance of piles especially in terms of the group effect induced by the pile arrangement. Several experimental and numerical analyses have been conducted on pile groups to investigate the group effect when the groups are subjected to uniform large horizontal ground movement. However, the ultimate lateral resistance of the pile groups in these studies was calculated by applying load to the piles. The present study directly assesses the ultimate lateral resistance of pile groups against ground movement by systematically varying the direction of the ground movement. Although the load bearing ratio of each pile in a pile group, defined as the ratio of the ultimate lateral resistance of each pile in a pile group to that of a single pile, is an important design criterion, it was difficult to assess in past works. This study focuses on the load bearing ratio of each pile against ground movement in various directions. The use of the finite element method (FEM) provides options for simulating the pile-soil system with complex pile arrangements by taking the complicated geometry of the problem into account. The ultimate lateral resistance is examined here for pile groups consisting of a 2?×?2 arrangement of four piles, as well as two piles, three piles, four piles, and an infinite number of piles arranged in a row through case studies in which the pile spacing is changed by applying the two-dimensional rigid plastic finite element method (RPFEM). The RPFEM was extended in this work to calculate not only the total ultimate lateral resistance of pile groups, but also the load bearing ratio of the piles in the group. The obtained results indicate that the load bearing ratio generally increases with an increase in pile spacing and converges to almost unity at a pile spacing ratio of 3.0 with respect to the pile diameter. Moreover, the group effect was further investigated by considering the failure mode of the ground around the piles.     

Cold Spray Coating Deposition Mechanism on the Thermoplastic and Thermosetting Polymer Substrates

Cold spraying is a successful and promising coating technique for many engineering applications due to its high-rate and high-dense coating development abilities. Nevertheless, their practical use in polymer substrate is still in the fledgling phase. There are very few articles about the cold spray coating on polymers; however, the interaction of metallic particle with the polymer substrate is poorly understood, and thus a thick coating has not successfully been developed on the polymer substrate. In order to rationalize as full as possible the entire behavior of the high velocity particle with the polymer substrate, we used thermoplastic and thermosetting polymer materials as substrates. The particle behaviors with the substrate were observed under various gas pressure and temperature, and with various particles feed rate. The result showed that the particle behaviors were unique with respect to the substrate. Also it was clearly understood that the metal particles not experienced any plastic deformation due to the soft nature of the polymer substrates. The particles attached to the thermoplastic substrate either through adhesive bonding and/or mechanical inter locking, whereas only pure localized fracture observed on the thermosetting substrate and thus no particles attached firmly on the substrate.     

Tritium retention to the first wall of JT-60U

For economic and safety reasons, tritium (T) accumulation on plasma facing wall (PFW) of fusion reactor is strictly limited. In this study, T inventory in the graphite tiles used at the first wall of JT-60U was measured by a full combustion method. It was found that T was only retained near plasma facing surfaces sides of the tiles and the amount of retained T increased from <10¹¹ to <10¹³ T atoms/cm² with increasing the exposed discharge period of the tiles. Integrating the T retention with the total surface area of the outer first wall tiles, the fraction of retained T in that area was estimated to be 13% of the total T production. It was confirmed that these retained T were part of the energetic T produced by DD reactions without being replaced by HH discharges. Based on the retained fraction, the annual amount of T retention in the outer first wall of a demo-size reactor was calculated to be 360 g/burn-year at maximum. Even the value would be much less in the reactor, the accumulation of this kind of inventory could have significant contribution to the total T inventory.     

Effect of Ambient Pressure on Flattening Behavior of Thermal Sprayed Particles

Cu splats were thermally sprayed onto the mirror polished SUS304 substrate surface at various ambient pressures ranging from 6.66 to 101.33 kPa. The effect of ambient pressure on the flattening behavior of the particle was systematically investigated. It was observed that only around 10% or less of disk-shaped splats deposited at atmospheric pressure. The splat shape on the flat substrate had a transitional changing tendency from a splash splat to a disk one with a decrease of the ambient pressure. The tendency of splash splat change with increasing the ambient pressure agreed with the BET curve, which indicates that adsorption/desorption of the adsorbed gas/condensation plays an important role on the flattening behavior of thermal sprayed particles. Moreover, a part of substrates were polished to a mirror finish and heated to 573 K for 10 min, then elapsed to air atmosphere for different duration of up to 1 h. The fundamental static wetting behavior of the once heated substrate surface by a water droplet was investigated. The contact angle measurement results agreed well with the splat morphologies. No chemical change and surface topography change took place with the elapse time increasing. Hence, the occurrence of desorption caused by reducing the ambient pressure or by substrate preheating provided good wetting. Wetting of substrate surface by molten particles may dominate the flattening behavior of thermal sprayed particles.     

Cold Spraying of TiO<Subscript>2</Subscript> Photocatalyst Coating With Nitrogen Process Gas

Titanium dioxide (TiO₂) is a promising material for photocatalyst coatings. However, it is difficult to fabricate a TiO₂ coating with anatase phase by conventional thermal spray processes due to a thermal transformation to rutile phase. In this paper, anatase TiO₂ coatings were fabricated by the cold spray process. To understand the influence of process gas conditions on the fabrication of the coatings, the gas nature (helium or nitrogen) and the gas temperature are investigated. It was possible to fabricate TiO₂ coatings with an anatase phase in all spraying conditions. The process gas used is not an important factor to fabricate TiO₂ coatings. The thickness of the coatings increased with the process gas temperature increasing. It indicates that the deposition efficiency of the sprayed particles can be enhanced by controlling the spray conditions. The photocatalytic activity of the coatings is similar or better than the feedstock powder due to the formation of a large reaction area. Concludingly, cold spraying is an ideal process for the fabrication of a TiO₂ photocatalyst coating.     

Cs–Te corrosion depth dependence on distribution of chromium carbide precipitation in high chromium steel

In an attempt to investigate Cs–Te corrosion depth dependence on distribution of chromium carbide precipitation in high chromium steel, Cs–Te corrosion out-pile tests of two 9Cr steels with different distributions of chromium carbide were carried out at 975 K for 100 h, and their corrosion depths were compared. The corrosion is obviously more advanced in a specimen which has grain boundary carbide than in the one that does not. A considerable reason of the result is that the carbide distributed at grain boundaries promoted the corrosion reaction and the corrosion extended along the grain boundary. This is the first case in which the Cs–Te corrosion depth dependence on distribution of chromium carbide precipitation in Fe–Cr steel is clarified experimentally.