Computational analysis of citric acid pertraction in emulsion liquid membranes

Citric acid is one of the most widely used acids in industry, and its recovery from waste streams is critical. Emulsion liquid membrane (ELM) is one of the most effective recovery methods that has been investigated in recent years. Numerous transport phenomena parameters affect the efficiency of this process. From the process equipment design point of view, optimization based on overall cost is of great importance, and important equipment sizing decisions/constraints must be considered. A physics-based model for a full-scale simulation of ELM systems is very useful. This work is focused on developing and verifying such a model. A coupled particle/mixture simulation was carried out in this work, and the modelling results were fitted on the experimental data. The novelty of this modelling work is physics-based results based on the system's geometry and its effects on the mass transfer resistances. Since the model is physics-based, the model is capable of simulating similar systems with any geometry or experimental conditions.     

The effect of foamed cement nanocomposite as counter electrode on the performance of dye-sensitized solar cell

Improper interparticle connection between carbon-based materials, poor interface bonding between the carbon counter electrodes (CEs) and substrate, and low surface area are the main limitations of carbon-based CEs in dye-sensitized solar cells. In this study, we utilized foamed cement and binder for adherence and surface area improvement in carbon-based CEs, such as graphite, multi-walled carbon nanotubes, and carbon black (CB). The results revealed that incorporating foamed cement into carbon materials improved the resistance, short-circuit current density, fill factor, and power conversion efficiency of the device. The porous cement/CB nanocomposite CE with a photoconversion efficiency of 5.51% exhibited the best photovoltaic performance. Moreover, this nanocomposite electrode showed an enhancement catalytic activity by high current density in cyclic voltammogram, low charge transfer resistance $(R_{CT}$) in electrochemical impedance spectroscopy, and high exchange current density in Tafel measurements compared to other electrodes. The porosity of foamed cement has been found to be the main cause of its superior photovoltaic performance, which expands the contact area with the electrode and enables rich ion transport. Additionally, the enhanced performance was due to strong bonding, crack-free deposited films, superior conductivity, and high catalytic activity.     

Manufacturing Porous Materials Using Dabco-Based Ionic Liquid

Silicon - The long-chain ionic liquid (IL) hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide was used as a template to prepare the hexagonally ordered siliceous mesoporous molecular sieve MCM-41...