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41.
Nasim Shokraei Shiva Asadpour Shabnam Shokraei Mehrdad Nasrollahzadeh Sabet Reza Faridi‐Majidi Hossein Ghanbari 《Microscopy research and technique》2019,82(8):1316-1325
Conductive nanofibers have been considered as one of the most interesting and promising candidate scaffolds for cardiac patch applications with capability to improve cell–cell communication. Here, we successfully fabricated electroconductive nanofibrous patches by simultaneous electrospray of multiwalled carbon nanotubes (MWCNTs) on polyurethane nanofibers. A series of CNT/PU nanocomposites with different weight ratios (2:10, 3:10, and 6:10wt%) were obtained. Scanning electron microscopy, conductivity analysis, water contact angle measurements, and tensile tests were used to characterize the scaffolds. FESEM showed that CNTs were adhered on PU nanofibers and created an interconnected web‐like structures. The SEM images also revealed that the diameters of nanofibers were decreased by increasing CNTs. The electrical conductivity, tensile strength, Young's modulus, and hydrophilicity of CNT/PU nanocomposites also enhanced after adding CNTs. The scaffolds revealed suitable cytocompatibility for H9c2 cells and human umbilical vein endothelial cells (HUVECs). This study indicated that simultaneous electrospinning and electrospray can be used to fabricate conductive CNT/PUnanofibers, resulting in better cytocompatibility and improved interactions between the scaffold and cardiomyoblasts. 相似文献
42.
In this study, we demonstrated a facile approach for the synthesis of nanocontainers using the encapsulation of a 2-mercaptobenzothiazole (MBT) inhibitor; these nanocontainers were capable of responsively releasing a corrosion inhibitor and of self-healing performances. The anticorrosive performance of the CeO2 nanocontainers was investigated with electrochemical impedance spectroscopy (EIS) measurement in a saline electrolyte via the incorporation of different weight percentages (0.5, 1, and 2 wt %) of synthesized nanocontainer in epoxy (EP) resin. The EIS results show that the loading of 1 wt % CeO2 nanocontainer containing MBT inhibitor in the epoxy (EP) coating [EP/NC MBT–CeO2 (1%)] provided the highest Rcoat, the lowest constant phase element of coating, and the optimum release of MBT at different operating pHs. The highest coating resistance Rcoat values of this coating (7.81 × 107 Ω cm2) were about 12 and 8573 times greater than those considered for EP–CeO2 and EP coatings, respectively. Different releases of the MBT inhibitor were detected at various pHs. We found that the coating operating in acidic media exhibited a better self-healing performance. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47297. 相似文献
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44.
Wireless Networks - Nowadays, resource allocation is one of the major problems in the cellular networks. Due to the increasing number of autonomous heterogeneous devices in future mobile networks,... 相似文献
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46.
Majid Etminan Gholamreza Nabiyouni Davood Ghanbari 《Journal of Materials Science: Materials in Electronics》2018,29(3):1766-1776
In this work, tin ferrite nanoparticles were first synthesized by simple chemical procedures such as co precipitation, sol–gel auto combustion and hydrothermal methods. In general, all three methods were compared in the synthesis of nanoparticles. Then tin ferrite–tin oxide (50%:50%) nanocomposites were prepared using co precipitation method. Crystal structures of nanoparticles and nanocomposite were studied using X-ray diffraction pattern. The particle size was determined by Scanning Electron Microscopy. Vibrating sample magnetometer was used to study the magnetic property of the products. And also, by applying Fourier transform infrared spectrometer, the purity of the material was determined. Photocatalytic activity of nanoparticles and nanocomposites was investigated under ultra-violet and visible spectroscopy (UV–Vis). The results show that prepared nanocomposites are applicable for magnetic and photocatalytic performance and they were able to degrade azo dyes (organic dyes) under UV–Vis radiation. 相似文献
47.
Niloofar Nazeri Mohammad Ali Derakhshan Reza Faridi-Majidi Hossein Ghanbari 《Journal of materials science. Materials in medicine》2018,29(11):168
Electro-conductive nanocomposites have several applications in biomedical field. Development of a biocompatible electro-conductive polymeric materials is therefore of prime importance. In this study, electro-conductive nanofibrous mats of PLGA/CNT were fabricated through different methods including blend electrospinning, simultaneous PLGA electrospinning and CNT electrospraying and ultrasound-induced adsorption of CNTs on the electrospun PLGA nanofibers. The morphology and diameter of fibers were characterized by SEM and TEM, showing the lowest average diameters of 477?±?136?nm for PLGA/MWCNT blend nanocomposites. MWCNT-sprayed PLGA specimens showed significant lower water contact angle (83°), electrical resistance (3.0?×?104?Ω) and higher mechanical properties (UTS: 5.50?±?0.46?MPa) compared to the untreated PLGA scaffolds. Also, results of PC12 cell study demonstrated highest viability percentage on the MWCNT-sprayed PLGA nanofibers. We propose that the conductive nanocomposites have capability to use as tool for the neural regeneration and biosensors. 相似文献
48.
Khadijeh Paymooni Elham Doroodchi Behdad Moghtaderi 《Advanced Powder Technology》2017,28(6):1531-1539
This study examines the oxygen adsorption and desorption characteristics of La0.5Sr0.5Co0.8Fe0.2O3?δ (LSCF5582) membranes prepared at sintering temperatures of 1200–1300 °C, with the aim of gaining an insight into their performance in the surface reaction limited regime for oxygen separation applications. The findings of this work are then compared with our experimental data on Ba0.5Sr0.5Co0.8Fe0.2O3?δ (BSCF5582) membranes. It is demonstrated that the adsorption rate constants of both membranes are two orders of magnitude greater than their respective oxygen desorption rate constants as the oxygen adsorption occurs in less than 24 s whilst the oxygen desorption takes approximately one hour to reach equilibrium. The activation energy for oxygen adsorption of LSCF5582 reduced to a quarter of its value with increasing the sintering temperature from 1200 °C to 1300 °C. This is attributed to the oxygen exchange occurring more rapidly along the grain boundaries resulting in a lower activation energy. The LSCF5582 grain sintered at 1200 °C is the optimum selection for oxygen separation applications at an operating temperature of 850 °C and oxygen partial pressure of 0.21 bar. 相似文献
49.
Khadijeh Soleimani Abbas Dadkhah Tehrani Mohsen Adeli Shabnam Sattari 《Iranian Polymer Journal》2018,27(9):689-699
A new graphene oxide (GO)-based hydrogel was synthesized through cross-linking of biofunctionalized graphene oxide nanosheets by di-alkyne polyethylene glycol as cross-linking agent. In this respect, nitrene chemistry as a convenient and straightforward protocol was developed for biofunctionalization of GO using an azido-starch as an eco-friendly, biodegradable and cost-effective material. In the next step, 1,3-dipolar cycloaddition chemistry, a green and highly efficient approach was utilized in cross-linking of functionalized GO by PEG through click reaction between remaining azido groups of starch on the surface of GO sheets and terminal alkyne groups of polyethylene glycol. Formation of aziridine and triazole rings during functionalization and cross-linking in this method could evidently improve biological activities of the obtained hydrogel compared to the conventional methods. The antibacterial activity of the new compounds was explored. The synthesized hydrogel showed antibacterial properties against Gram-positive and Gram-negative bacteria due to the presence of triazole rings. Also, the resulting hydrogel exhibited high dye removal efficiency and it can be utilized in water treatment effectively. The adsorption kinetics was analyzed through the effects of adsorption time and the dye concentration on the adsorption capacity. Kinetic data were accurately described by a pseudo-second-order model. 相似文献
50.
Comparison of pristine and polyaniline‐grafted MWCNTs as conductive sensor elements for phase change materials: Thermal conductivity trend analysis 下载免费PDF全文
Maryam Halvaee Khadijeh Didehban Vahabodin Goodarzi Mehdi Ghaffari Morteza Ehsani Mohammad Reza Saeb 《应用聚合物科学杂志》2017,134(47)
Phase change materials (PCMs) function based on latent heat stored on or released from a substance over a slim temperature range. Multiwalled carbon nanotubes (MWCNTs) and polyaniline are important elements in sensor devices. In this work, pristine and polyaniline‐grafted MWCNTs (PANI‐g‐MWCNTs) were applied as conductive carbon‐based fillers to make PCMs based on paraffin. The attachment of PANI to the surface of MWCNTs was proved by Fourier transform Infrared analysis. Dispersion of MWCNTs in paraffin was studied by wide‐angle X‐ray scattering. Heating and solidification of PCM nanocomposites were investigated by differential scanning calorimetry, while variation in nanostructure of PCMs during heating/solidification process was evaluated by rheological measurements. It was found that after 30 min of sonication, the samples filled with 1 wt % MWCNTs have melting and solidification temperatures of 29 and 42 °C, respectively. It was also found that PANI attachment to MWCNTs significantly changes thermal conductivity behavior of PCM nanocomposites. The developed MWCNTs‐based sensor elements responded sharply at low MWCNTs content, and experienced an almost steady trend in conductivity at higher contents, while PANI‐g‐MWCNTs sensor followed an inverse trend. This contradictory behavior brought insight for understanding the response of PCMs against thermal fluctuations. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45389. 相似文献