Optimum design parameters of a squash head projectile

This note first establishes a correlation between post impact fuze delay and the spread of explosives of a squash head gun-fired projectile when hitting a rigid non-yielding plate. Estimations of optimum strike velocity and fuze delay to maximize spread are derived.     

Gas holdup and overall volumetric mass transfer coefficient in a modified reversed flow jet loop reactor

Experiments were conducted in a modified reversed flow jet loop reactor having the liquid outlet at the top of the reactor to determine the gas holdup and overall volumetric mass transfer coefficient in the air-water system. The influence of gas and liquid flow rates, and the draft tube to reactor diameter ratio were studied. It was observed that both gas holdup and volumetric mass transfer coefficient increased with increased gas and liquid flow rates and were found to be significantly higher in the modified reactor compared to the conventional one. The optimum draft tube to reactor diameter ratio was found to be in the range of 0.4 to 0.5. Empirical correlations are presented to predict gas holdup and overall volumetric mass transfer coefficient in terms of operational and geometrical variables.     

The kinetics of the polymerization reaction of toluene diisocyanate with HTPB prepolymer

The uncatalysed and catalysed polymerization of a hydroxyl-terminated polybutadiene with toluene diisocyanate has been studied in toluene solution at four different temperatures. The rate constants (k₁, k₂) and the activation parameters (Ea₁, Ea₂, ΔS₁^?, ΔS₂^?) for the isocyanate groups in the 4 and 2 positions were calculated. It was found that the catalysts enhance the reactivity of the 2 position isocyanate group rather than the 4 position isocyanate group. It was also found that diethylcyclohexylamine has higher selectivity than dibutyltin dilaurate to enhance the reactivity of the isocyanate group in the 2 position. The effect of solvent has also been studied. The reactivity decreased in the following order; benzene = toluene > chlorobenzene > dioxane > nitrobenzene. © 1993 John Wiley & Sons, Inc.     

Photoinduced anisotropy measurements in liquid-crystalline azobenzene side-chain polyesters

Reversible photoinduced anisotropy in a series of liquid-crystalline azobenzene side-chain polyesters is investigated as a function of intensity of the write beam and the sample temperature. Measurements reveal that the erasing takes place at a temperature much higher than the glass transition temperature. Induced anisotropy can be erased by heating the polyesters to approximately 80 °C.     

A unified framework for optimizing locality, parallelism, andcommunication in out-of-core computations

This paper presents a unified framework that optimizes out-of-core programs by exploiting locality and parallelism, and reducing communication overhead. For out-of-core problems where the data set sizes far exceed the size of the available in-core memory, it is particularly important to exploit the memory hierarchy by optimizing the I/O accesses. We present algorithms that consider both iteration space (loop) and data space (file layout) transformations in a unified framework. We show that the performance of an out-of-core loop nest containing references to out-of-core arrays can be improved by using a suitable combination of file layout choices and loop restructuring transformations. Our approach considers array references one-by-one and attempts to optimize each reference for parallelism and locality. When there are references for which parallelism optimizations do not work, communication is vectorized so that data transfer can be performed before the innermost loop. Results from hand-compiles on IBM SP-2 and Inter Paragon distributed-memory message-passing architectures show that this approach reduces the execution times and improves the overall speedups. In addition, we extend the base algorithm to work with file layout constraints and show how it is useful for optimizing programs that consist of multiple loop nests     

Grafting of glycidyl methacrylate onto gelatin

Gelatin was graft copolymerized with poly(glycidyl methacrylate) using potassium peroxydisulfate in aqueous medium. Effect of temperature, time, initiator, monomer, and backbone concentrations were studied. The percent grafting was found to increase initially and then decrease in all the cases except with variation of monomer concentration. The rate of grafting, grafting efficiency, and percent of grafting were calculated. The grafting results have been discussed in the light of the rate of grafting. Mechanical properties, FT IR spectra, percent swelling, and percent dye uptake were carried out on the graft copolymerization and the results discussed.     

Machinability studies on Al 7075/BN/Al2O3 squeeze cast hybrid nanocomposite under different machining environments

Enforcement of stricter environmental policies demands alternative methods that could reduce the usage of cutting fluid during machining. Thus, dry machining and minimum quantity lubrication (MQL) machining are gaining practical importance. Due to enhanced mechanical and thermal properties, aluminium based nanocomposites have wide application in aerospace and automobile industries. In this work, asqueeze cast hybrid nanocomposite is developed with the reinforcement of 0.5?wt% hexagonal boron nitride and 1?wt% alumina particles in the base matrix of Al 7075 that is subjected to a squeezing pressure of 150?MPa. During the turning of this hybrid nanocomposite, thefeed rate is varied (0.1, 0.2, and 0.3?mm/rev)and its influence on the generated forces, tool wear and surface roughness under dry and MQL environments is performed. The results are compared with squeeze cast unreinforced aluminium alloy and presented.