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31.
Kirisci Levent; Vanyukov Michael; Dunn Marija; Tarter Ralph 《Canadian Metallurgical Quarterly》2002,16(4):290
This study examined the psychometric characteristics of an index of substance use involvement using item response theory. The sample consisted of 292 men and 140 women who qualified for a Diagnostic and Statistical Manual of Mental Disorders (3rd ed., rev.; American Psychiatric Association, 1987) substance use disorder (SUD) diagnosis and 293 men and 445 women who did not qualify for a SUD diagnosis. The results indicated that men ha4 a higher probability of endorsing substance use compared with women. The index significantly predicted health, psychiatric, and psychosocial disturbances as well as level of substance use behavior and severity of SUD after a 2-year follow-up. Finally, this index is a reliable and useful prognostic indicator of the risk for SUD and the medical and psychosocial sequelae of drug consumption. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
32.
Alcohol biosensors based on conducting polypyrrole (PPy), poly(3,4-ethylenedioxythiophene) (PEDOT) and poly(3,4-ethylenedioxypyrrole) (PEDOP) were constructed. Alcohol oxidase (AlcOx, from Pichia pastoris) was immobilized during electropolymerization of the monomers in sodium dodecylsulfate (SDS) and phosphate buffer electrolysis medium. Optimization of several parameters was carried out. The highest affinity was observed for the PEDOT/AlcOx sensor. Lowry protein determination method was also used to calculate the amount of immobilized enzyme in sensors. Before testing the biosensors on alcoholic beverages effects of interferents (glucose, acetic acid, citric acid, and l-ascorbic acid) were determined. The alcohol contents of the distilled beverages (vodka, dry cin, whisky, and rak?) were determined with the sensors constructed. A good match with the chromatography results was observed. 相似文献
33.
Synthesis and characterization of poly(N-(2-(thiophen-3-yl)methylcarbonyloxyethyl)maleimide) and its spectroelectrochemical properties 总被引:1,自引:0,他引:1
A new monomer; N-(2-(thiophen-3-yl)methylcarbonyloxyethyl) maleimide (NMT) was synthesized. The chemical structure of the
monomer was characterized by Nuclear Magnetic Resonance (1H-NMR) and Fourier Transform Infrared (FTIR) Spectroscopy. Electrochemical polymerization of NMT was performed in acetonitrile
(AN)/borontrifloride ethylether (BFEE) solvent mixture (1:1, v/v) where tetrabutylammonium tetrafluoroborate (TBAFB) was utilized
as the supporting electrolyte. The resulting conducting polymer was characterized by Fourier Transform Infrared (FTIR) Spectroscopy,
thermal analyses and Scanning Electron Microscopy (SEM). Electrical conductivity was measured by the four-probe technique.
The spectroelectrochemical behavior and switching ability of P(NMT) film were investigated by UV–Vis spectrophotometry. P(NMT)
revealed color changes between yellow and blue in the reduced and oxidized states respectively. 相似文献
34.
Ozan Gürbüz Duygu Göçmen Fatih Dagˇdelen Murat Gürsoy Sami Aydin İsmet Şahin Levent Büyükuysal Mehmet Usta 《Food chemistry》2007,100(2):518-525
Concentrations of trans-resveratrol, catechin and epicatechin were analyzed in musts and wines produced from seven red and four white grape cultivars from various wine growing regions of Turkey. Phenolics were quantified using an HPLC method optimized for the separation of wine phenolics. Wine samples contained higher phenolics levels than the corresponding musts. With the exception of Semillion, white wines and musts contained lower concentrations of phenolics than red wines and musts. However, the white cultivar Semillion had the highest concentrations of catechin and epicatechin among all wine and must samples. Semillion wine catechin and epicatechin were 13.7 and 11.8 mg/L, respectively. The highest level of trans-resveratrol among the white cultivars was found in Narince wine (1.93 mg/L). Within the red wine and must cultivars, Bo?azkere, Öküzgozü, and Cabernet contained the highest concentrations of flavan-3-ols and trans-resveratrol. Catechin was the major phenolic in all wines and most musts. Epicatechin was the major phenolic in 6 of the 11 must samples, but none of the wine samples. trans-Resveratrol was generally found in lowest concentrations in both wines and musts. 相似文献
35.
Numerical modelling of honeycomb core crush behaviour 总被引:3,自引:0,他引:3
In this work several numerical techniques for modelling the transverse crush behaviour of honeycomb core materials were developed and compared with test data on aluminium and Nomex™ honeycomb. The methods included a detailed honeycomb micromechanics model, a homogenised material model suitable for use in FE code solid elements, and a homogenised discrete/finite element model used in a semi-adaptive numerical coupling (SAC) technique. The micromechanics model is shown to be suitable for honeycomb design, since it may be used to compute crush energy absorption for different honeycomb cell sizes, cell wall thicknesses and cell materials. However, the very fine meshes required make it unsuitable for analysis of large sandwich structures. The homogenised FE model may be used for such structures, but gives poor agreement when failure is due to core crushing. The SAC model is shown to be most appropriate for use in structural simulations with extensive compression core crushing failures, since the discrete particles are able to model the material compaction during local crushing. 相似文献
36.
Up to date there are few studies reporting the use of selenophene derivatives as electrochromic polymers. This report highlights the synthesis of a selenophene containing multi-ring aromatic polymer which possesses reasonable optical contrasts at both visible and near-IR regions. Electrochemical synthesis of a conducting polymer from a multi-ring aromatic monomer, 2-(2,5-bis(hexyloxy)-4-(selenophen-2-yl)phenyl)selenophene (BSB(OC6H13)2), was achieved at a lower potential than its corresponding parent, selenophene. The strong absorption band for the undoped polymer was 474 nm and the onset energy for the π–π* transition (Eg) was 1.9 eV (645 nm).A novel dual-polymer electrochromic device was constructed in sandwich configuration where poly(BSB(OC6H13)2) was used as the anodically coloring material. It is the first electrochromic device where a selenophene-containing polymer was used as an active layer. The device switches between a rose-colored state and a blue-colored state with a fast response time (less than 1 s). 相似文献
37.
Kıvanç Köse A. Enis Çetin Uğur Güdükbay Levent Onural 《Journal of Visual Communication and Image Representation》2010,21(1):17-28
Connectivity-Guided Adaptive Wavelet Transform based mesh compression framework is proposed. The transformation uses the connectivity information of the 3D model to exploit the inter-pixel correlations. Orthographic projection is used for converting the 3D mesh into a 2D image-like representation. The proposed conversion method does not change the connectivity among the vertices of the 3D model. There is a correlation between the pixels of the composed image due to the connectivity of the 3D mesh. The proposed wavelet transform uses an adaptive predictor that exploits the connectivity information of the 3D model. Known image compression tools cannot take advantage of the correlations between the samples. The wavelet transformed data is then encoded using a zero-tree wavelet based method. Since the encoder creates a hierarchical bitstream, the proposed technique is a progressive mesh compression technique. Experimental results show that the proposed method has a better rate distortion performance than MPEG-3DGC/MPEG-4 mesh coder. 相似文献
38.
Donor-acceptor-donor (DAD) type benzimidazole (BIm) and 3,4 ethylenedioxythiophene (EDOT) bearing monomers were synthesized and electrochemically polymerized. Pendant group at 2-C position of the imidazole ring was functionalized with phenyl (P1), EDOT (P2) and ferrocene (P3) in order to observe substituent effect on electrochemical and electrochromic properties of corresponding polymers. Spectroelectrochemical results showed that different pendant groups resulted in polymers with slightly different optical band gaps (1.75, 1.69 and 1.77 eV respectively) and different number of achievable colored states. Optoelectronic performance and comparison of results with other well known π-accepting benzazole bearing DAD type polymers were reported in detail. 相似文献
39.
This paper considers the possibility of using artificial neural network models to identify model for swelling behavior as new techniques. Multi-layer feed-forward, radial basis function and generalized regression neural network models were employed to predict the swelling behaviors of Ca2+-alginate hydrogels under different environmental conditions of pH and temperature. The results show that an excellent correlation between the experimental and predicted swelling ratios was obtained by the artificial neural networks. Generalized regression neural network has a better performance than the other neural network models. The absolute mean error, the determination coefficient and the standard error of prediction were used as performance criteria. In addition, the performances of the neural network models are significantly superior compared with those of second-order swelling kinetics, quadratic and cubic models of response surface methodology. 相似文献
40.
Tin-zinc (Sn-Zn) alloy with low tin content was deposited on gold electrode and steel substrate with use of chronoamperometric technique from an acidic bath. In order to evaluate coating efficiency of Sn-Zn alloy in 0.5 M NaCl solution, open circuit potential-time curve (EOCP-t), polarization curves, mass change of the electrode (Δm-t) using quartz crystal microbalance (QCM) were compared to those of pure Sn and Zn coatings. Anodic stripping measurements were carried out simultaneously with the mass loss of the deposit. Scanning electron microscopy (SEM) and energy dispersive X-ray spectra (EDS) analysis were performed to characterize the surface morphology. Anodic stripping experiment and EDS analysis indicated that Sn, Zn, and SnO2 formed on the electrode surface when Sn-Zn was coated from acidic bath. Furthermore, local mapping demonstrated homogeneous distribution of Sn and Zn atoms throughout the surface. 相似文献