The Joyce language report

This paper defines a programming language for distributed processing called Joyce. Joyce is based on CSP and Pascal. A Joyce program defines concurrent agents which communicate through synchronous channels. The agents may be recursive.     

Surface modification of cellulose fibers. I. Spectroscopic characterization of surface-modified cellulose fibers and their copolymerization with styrene

Two coupling agents based on trichloro-s-triazine with different terminal unsaturated groups were synthesized in order to improve the bonding between cellulose fibers and an unsaturated polyester matrix. The products of the reactions between hydroxyl groups of cellulose and reactive species of coupling agents were analysed by Fourier-transform infrared spectroscopy (FTIR) and by elemental microanalyses. ESCA was used for surface characterization of treated fibers. The coupling agents were found to be concentrated on the fiber surface. Polymerization of styrene was carried out in the presence of treated fibers. That the unsaturated groups of the treated fibers were able to copolymrize with styrene was shown by FTIR. Further evidence of the presence of grafted polystyrene on the surfaces of the cellulose fibers was provided by ESCA measurements.     

Randomized trial of internet-delivered self-help with telephone support for pathological gamblers.

Although effective therapies for pathological gambling exist, their uptake is limited to 10% of the target population. To lower the barriers for help seeking, the authors tested an online alternative in a randomized trial (N = 66). The participants were pathological gamblers not presenting with severe comorbid depression. A wait-list control was compared with an 8-week Internet-based cognitive behavior therapy program with minimal therapist contact via e-mail and weekly telephone calls of less than 15 min. Average time spent on each participant, including phone conversations, e-mail, and administration, was 4 hr. The Internet-based intervention resulted in favorable changes in pathological gambling, anxiety, depression, and quality of life. Composite between-group effect size (Cohen's d) at posttreatment was 0.83. Follow-ups carried out in the treatment group at 6, 18, and 36 months indicated that treatment effects were sustained (ds = 2.58, 1.96, and 1.98). This evidence is in support of Internet-delivered treatment for pathological gamblers. However, it is not clear how effective the treatment is for more severely depressed individuals. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Nanometer-thick films of titanium oxide acting as electrolyte in the polymer electrolyte fuel cell

0-18 nm-thick titanium, zirconium and tantalum oxide films are thermally evaporated on Nafion 117 membranes, and used as thin spacer electrolyte layers between the Nafion and a 3 nm Pt catalyst film. Electrochemical characterisation of the films in terms of oxygen reduction activity, high frequency impedance and cyclic voltammetry in nitrogen is performed in a fuel cell at 80 °C and full humidification. Titanium oxide films with thicknesses up to 18 nm are shown to conduct protons, whereas zirconium oxide and tantalum oxide block proton transport already at a thickness of 1.5 nm. The performance for oxygen reduction is higher for a bi-layered film of 3 nm platinum on 1.5 or 18 nm titanium oxide, than for a pure 3 nm platinum film with no spacer layer. The improvement in oxygen reduction performance is ascribed to a higher active surface area of platinum, i.e. no beneficial effect of combining platinum with zirconium, tantalum or titanium oxides on the intrinsic oxygen reduction activity is seen. The results suggest that TiO₂ may be used as electrolyte in fuel cell electrodes, and that low-temperature proton exchange fuel cells could be possible using TiO₂ as electrolyte.     

网络拱桥──一种适合中国的桥梁

阐述了网络拱桥的特点，设计原理，节点形式及架设安装。对中国大跨度简支架桥的发展有一定的借鉴作用．     

The interpersonal structure of family interaction settings: Parent–adolescent relations in dyads and triads.

Observed parental interactive patterns in the presence (a triadic setting) and in the absence (a dyadic setting) of the spouse in 44 families with 16 female and 28 male early adolescents (approximately 13 yrs old). Findings indicate that in accordance with hypotheses, the presence of the father enhanced the quality of mother–son relations, whereas the presence of the mother reduced the quality of father–son relations. The presence of the spouse influenced the extent to which parents treated girls and boys differently: Mothers differentiated more between girls and boys in the presence of the spouse, whereas fathers differentiated more between girls and boys in the absence of the spouse. Relative to the dyad, parental role differentiation increased in the triad but only in families of boys. In demonstrating interdependencies among family relationships and the responsivity of parental behaviors to the interpersonal structure of interaction settings, the results support a systems model of family processes. Implications for the study of family relations and sex typing at early adolescence are discussed. (60 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Microkinetic modeling as a tool in catalyst discovery

We propose a new approach for catalyst development that combines different scientific disciplines: experimental design, surface science, reaction kinetics and simulations with the objective of accelerating catalyst development. In this paper we present a study of the possibilities of using small data sets in microkinetic modeling, and studies of the required precision of temperature measurement.     

Mechanism and kinetics of the free radical ring-opening polymerization of cyclic allylic sulfide lactones

The polymerization of 7-, 8- and 11-membered lactones, 6-methylene-1,4-oxathiepan-7-one, 3-methylene-1,5-oxathiocan-2-one and 3-methylene-1-oxa-5-thiacycloundecan-2-one in benzene at 70, 40–70 and 40–65 °C, respectively, is presented. All polymerizations proceeded with complete ring-opening up to approximately 25% conversion, where insoluble polymer was formed. Evidence is given attributing polymer double bond loss to crosslinking, although redistribution of the molecular weights via addition to polymer double bonds followed by β-fragmentation also appears to occur for polymerizations of the 8- and 11-membered lactones. Michael adducts of lactones with 2-methyl-2-propanethiol were prepared as models for chain-transfer products of hydrogen abstraction by carbon-centred radicals. Polymerization rates were found to increase marginally with ring size. Arrhenius parameters obtained for the polymerizations of the 8- and 11-membered lactones indicated that the addition step was more important than fragmentation in determining the rate of propagation.     

The Sephadex story

The environment and the circumstances leading to the Sephadex group of products for gel filtration (SEC, size exclusion chromatography) are described. The importance of Porath's and the author's experience from zone electrophoresis is stressed. To be able to get high resolution the technique for packing columns was of decisive importance for electrophoresis. It paved the way for the observation of the separation properties of dextran gels. The synthesis of dextran-based gels at AB Pharmacia and the development of varieties of them for varying applications are described together with the project leading to their marketing in 1959. The work of the author on gel filtration is summarized. The story is based on publication and memory. Aids to the latter have been laboratory notebooks and other documents still in the possession of the author.