Cu-P-silicon carbide(SiC)composite coatings were deposited by means of electroless plating.The effects ofpH values,temperature,and different concentrations of sodium hypophosphite(NaH2PO2·H2O),nickel sulfate(NiSO4·6H2O),sodium citrate(C6H5Na3O7·2H2O)and SiC on the deposition rate and coating compositions were evaluated,and the bath formulation for Cu-P-SiC composite coatings was optimised.The coating compositions were determined using energy-dispersive X-ray analysis(EDX).The corresponding optimal operating parameters for depositing Cu-P-SiC are as follows:pH 9; temperature,90℃; NaH2PO2·H2O concentration,125 g/L; NiSO4·6H2O concentration,3.125 g/L; SiC concentration,5 g/L; and C6H5Na3O7·2H2O concentration,50 g/L.The surface morphology of the coatings analysed by scanning electron microscopy(SEM)shows that Cu particles are uniformly distributed.The hardness and wear resistance of Cu-P composite coatings are improved with the addition of SiC particles and increase with the increase of SiC content. 相似文献
The effect of an external electric field on laser-generated plasma has been studied. It is observed that the laser-generated plasma can be used for the ignition of a spark in the presence of a low voltage external electric field. An eight-fold emission intensity enhancement in Cu Ⅰ spectral lines are measured as compared to the signal intensity in the absence of an external electric field.The plasma parameters remain the same initially, up to a few microseconds after the generation of plasma, and this feature makes it more interesting for the quantitative analysis of any sample using laser induced breakdown spectroscopy(LIBS). In the presence of an external electric field,fluctuations(contraction and expansion) in the laser-generated plasma are observed which increase the plasma decay time and consequently result in enhanced signal intensity. 相似文献
Mn doped ZnO nanostructures have been prepared using low temperature simple, quick, and versatile synthesis approach. The structural, microstructural, and vibrational investigations reveal that as prepared nanostructures with low Mn doping concentration have single hexagonal phase and are grown along the preferred c-axis. The X-rays photoelectron spectroscopy demonstrates that the Mn ions are in mixed oxidation states for high doping concentration of Mn, while are in 2+ oxidation state for low concentration into ZnO lattice. The photoluminescence spectrum (PL) exhibits a significant red-shift of 22 nm in the optical band gap of doped ZnO and shows the improved luminescence properties, which makes it potential for its use in the photocatalyst, optoelectronics and solar cell nanodevices. Furthermore, the magnetic measurement of Mn doped ZnO nanostructures exhibits the ferromagnetism at room temperature. 相似文献
A correlation-based double-directional stochastic channel model for indoor multiple-input multiple-output (MIMO) ultra-wideband (UWB) propagation channels is proposed. The proposed model extends the IEEE 802.15.3a standard model to spatially correlated MIMO channels. Both angular and temporal statistics are taken into account in the modelling procedure. Spatial correlation is introduced into the multipath amplitude and time-of-arrival (ToA) matrices of the channel model. Each amplitude matrix consists of entries of correlated lognormal random variables, whereas each ToA matrix is obtained as the sum of a reference matrix and a difference matrix. The frequency-dependent spatial correlation function is derived to give an insight of model properties. Model parameters are determined based on well-known measurement campaigns. In addition, simulation-based analysis indicates that this model has desirable spatial correlation properties in both the time and frequency domains. The ToA correlation matrix was also found to have dominant effects on the correlation characteristics. This suggests that future research into spatial correlation properties of MIMO-UWB channels should focus on ToA correlation characteristics, rather than amplitude correlation characteristics, which are the current focus of narrowband and wideband MIMO channel research. 相似文献
A new definition of scale-space is suggested, and a class of algorithms used to realize a diffusion process is introduced. The diffusion coefficient is chosen to vary spatially in such a way as to encourage intraregion smoothing rather than interregion smoothing. It is shown that the `no new maxima should be generated at coarse scales' property of conventional scale space is preserved. As the region boundaries in the approach remain sharp, a high-quality edge detector which successfully exploits global information is obtained. Experimental results are shown on a number of images. Parallel hardware implementations are made feasible because the algorithm involves elementary, local operations replicated over the image 相似文献
This study proposes a novel prediction approach for human breast and colon cancers using different feature spaces. The proposed scheme consists of two stages: the preprocessor and the predictor. In the preprocessor stage, the mega-trend diffusion (MTD) technique is employed to increase the samples of the minority class, thereby balancing the dataset. In the predictor stage, machine-learning approaches of K-nearest neighbor (KNN) and support vector machines (SVM) are used to develop hybrid MTD-SVM and MTD-KNN prediction models. MTD-SVM model has provided the best values of accuracy, G-mean and Matthew's correlation coefficient of 96.71%, 96.70% and 71.98% for cancer/non-cancer dataset, breast/non-breast cancer dataset and colon/non-colon cancer dataset, respectively. We found that hybrid MTD-SVM is the best with respect to prediction performance and computational cost. MTD-KNN model has achieved moderately better prediction as compared to hybrid MTD-NB (Naïve Bayes) but at the expense of higher computing cost. MTD-KNN model is faster than MTD-RF (random forest) but its prediction is not better than MTD-RF. To the best of our knowledge, the reported results are the best results, so far, for these datasets. The proposed scheme indicates that the developed models can be used as a tool for the prediction of cancer. This scheme may be useful for study of any sequential information such as protein sequence or any nucleic acid sequence. 相似文献
Crowded urban environments are composed of different types of dynamic and static elements. Learning and classification of features is a major task in solving the localization problem in such environments. This work presents a gradual learning methodology to learn the useful features using multiple experiences. The usefulness of an observed element is evaluated by a scoring mechanism which uses two scores – reliability and distinctiveness. The visual features thus learned are used to partition the visual map into smaller regions. The robot is efficiently localized in such a partitioned environment using two-level localization. The concept of active map (AM) is proposed here, which is a map that represents one partition of the environment in which there is a high probability of the robot existing. High-level localization is used to track the mode of the AMs using discrete Bayes filter. Low-level localization uses a bag-of-words model to retrieve images and accurately localize the robot. The pose of the robot is the one retrieved from the AM that has maximum a posteriori. Experiments have been conducted on a unique highly crowded data-set collected from Indian roads. The results support the proposed method due to speed and localization accuracy. 相似文献
Emotion recognition from speech signals is an interesting research with several applications like smart healthcare, autonomous voice response systems, assessing situational seriousness by caller affective state analysis in emergency centers, and other smart affective services. In this paper, we present a study of speech emotion recognition based on the features extracted from spectrograms using a deep convolutional neural network (CNN) with rectangular kernels. Typically, CNNs have square shaped kernels and pooling operators at various layers, which are suited for 2D image data. However, in case of spectrograms, the information is encoded in a slightly different manner. Time is represented along the x-axis and y-axis shows frequency of the speech signal, whereas, the amplitude is indicated by the intensity value in the spectrogram at a particular position. To analyze speech through spectrograms, we propose rectangular kernels of varying shapes and sizes, along with max pooling in rectangular neighborhoods, to extract discriminative features. The proposed scheme effectively learns discriminative features from speech spectrograms and performs better than many state-of-the-art techniques when evaluated its performance on Emo-DB and Korean speech dataset.
The effect of Ag on the stationary and non-stationary anodic corrosion rates of PbSbCd and PbSb alloys in H2SO4 has been studied. Anodic polarization curves were constructed under galvanostatic and potentiostatic conditions. Optical microscopic examination and microprobe analysis of the alloys were conducted. The beneficial effect of Ag was ascribed to a delay in closure of pores in the initial PbSO4 film. The leaching out of Sb from the outermost layers and the simultaneous nucleation of PbSO4 and Ag2SO4 from supersaturated solutions in the pores is thus made possible. 相似文献