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101.
Iman Ahmadi Joneidi Mehrdad Ahmadi Kamarposhti Amir Abbas Shayegani Akmal Hossein Mohseni 《Electrical Engineering (Archiv fur Elektrotechnik)》2013,95(4):315-323
In this paper, an experimental test results on silicon rubber insulator with voltage of 20 kV have been shown. Artificial aging on insulator has been done using solid layer methods according to IEC60507 standard. Leakage current waveforms during the experimental studies were measured. Normally Fast Fourier transform method used to find the harmonic spectrum in the leakage currents. Three states of analysis are considered. In the first state, it is done with nominal voltage and without arc. In the second state, it is done in the presence of dry band arcing and corona discharge and in the last case, continuous arc is investigated and in each state harmonic analysis is performed. It is observed that in second state the third harmonic components increase rather than in the first state. Artificial aging on insulator has been done using solid layer methods according to IEC60507 standard. Leakage current waveforms during the experimental studies were measured. Eventually, to distinguishing pollution intensity, equivalent salt deposit density calculations are implemented. At the end, finite element method has been investigated for the results of water droplets existing on the surface of silicone rubber materials and electric field distribution along the surface of insulator. 相似文献
102.
A series of clearcoats separately loaded with different concentrations of functional silicon–polyacrylate and polydimethyl siloxane additives were prepared. Optical performances of the cured films were studied by gonio-spectrophotometry. Dynamic mechanical thermal analysis was used in order to investigate viscoelastic properties of the additive-containing films. Contact angle measurements, (FTIR) spectroscopy, scanning electron microscopy equipped with energy-dispersive analysis of X-ray, and atomic force microscopy techniques were utilized to evaluate surface properties of the clearcoats. It was shown that clearcoat surface free energy decreased and its crosslinking density increased in the presence of the additives. Results revealed that addition of both additives to the clearcoat enhanced its resistance against pancreatin (simulated bird droppings). A decrease in surface degradation was observed in the presence of the additives. Results also showed that functional polydimethyl siloxane influenced coating viscoelastic, surface chemistry, and biological resistance more effectively compared to that of the functional silicon–polyacrylate one. 相似文献
103.
J. Esteban Duran Fariborz Taghipour Madjid Mohseni 《International Journal of Heat and Mass Transfer》2009,52(23-24):5390-5401
A computational fluid dynamics (CFD) investigation of single-phase flow mass transfer prediction in annular reactors was conducted. Different hydrodynamic models including laminar, standard k–ε, realizable k–ε, Reynolds stress (RSM), and the Abe-Kondoh-Nagano (AKN) (a low Reynolds number turbulence model) were evaluated against experimental data in terms of their mass transfer predication capabilities. The laminar model predicted successfully the average mass transfer in the flows under laminar regime (Re < 1500). Among the four evaluated turbulence models, the AKN model provided a better prediction of the average mass transfer rates in the systems when operated both under transitional and turbulent conditions (3000 < Re < 11000). The RSM performed very similarly to the AKN model, except for the entrance region of the reactors where it predicted lower mass transfer rates. These results make the AKN and RSM models very attractive to be integrated in CFD-based simulations of turbulent annular reactors. 相似文献
104.
105.
Pharmaceuticals and personal care products (PPCPs), endocrine disrupting compounds (EDCs) and disinfection by-products are suspected to have potential adverse impact on humans and hence their elimination during drinking water treatment is often desired or regulated. Based on pilot-plant experiments with three raw water sources, conventional treatment poorly removed the selected PPCPs and EDCs, while ozone/H2O2 and UV/H2O2 (both) with conventional treatment effectively removed PPCPs and EDCs. In most of the experiments, ozone/H2O2 + conventional treatment additionally removed THM formation potentials (THM-FPs) compared to those of conventional treatment. However, UV/H2O2 treatment was found to increase THM-FPs compared to conventionally treated water. 相似文献
106.
The work presented here aims at studying the thermomechanical and chemorheological properties of an automotive clearcoat containing an acrylic/melamine resin modified with a hyperbranched poly ester‐amide (HBP) additive. Rheological experiments were conducted at ambient (25°C) and curing temperature (140°C). Dynamic mechanical thermal analysis and hardness measurements were performed to reveal the influence of HBP content on the behavior of the cured samples. It was found that the viscosity of the resin containing HBP samples considerably decreased. Although curing degree and mechanical properties were improved at low HBP loadings, a reverse effect was seen at higher contents. Dynamic rheological results during curing showed that although low amount of HBP resulted in an early gel point (GP), higher HBP loading postponed the GP. This loading‐dependent behavior was explained by the influence of HBP on viscosity and reactivity of the system on which the curing performance was influenced oppositely. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
107.
This work aims at improving the surface chemistry and the mechanical properties of a commercial acrylic–melamine clear coat using a functional siliconized additive. The resistance of films against biological degradation was then investigated using pancreatin (simulated bird droppings) and Arabic gum (simulated tree gum). Variations in the surface and bulk chemical structures, as well as the thermomechanical characteristics of the clear coats at different concentrations of the additive, were investigated by a wide range of techniques inclusive of contact angle measurement, gonio‐spectrophotometery, dynamic mechanical thermal analysis (DMTA), energy‐dispersive spectroscopy, atomic force microscope, optical microscope, and attenuated totalreflectance Fourier transform infrared (ATR‐FTIR) spectroscopy. Negligible effect of additive on color change was revealed. It was shown that even at low loadings of additive it could migrate to the surface, producing hydrophobic films with very low surface free energies with water contact angle exceeding 100°. In addition, it was found by DMTA and ATR‐FTIR studies that the functional additive was covalently attached to the acrylic–melamine chains through its hydroxyl groups. However, phase separation was observed at high concentrations of additive, leading to reduced crosslinking density. The clear coat resistance against pancreatin and Arabic gum was improved using optimum concentrations of the additive. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
108.
A permanent anti‐graffiti coating based on a polyurethane resin was prepared by incorporating different levels of an OH‐functional silicone modified polyacrylate additive. Static contact angle measurements and dynamic mechanical thermal analysis (DMTA) were employed to evaluate surface free energy and mechanical properties of the coating specimens, respectively. Effect of ageing condition on the graffiti properties of the coating samples was evaluated utilizing an accelerated weathering test. Color changes, surface morphology, and variations in the mechanical properties were also examined prior to and after being exposed to UV irradiation for 864 h in a QUV chamber. Results showed that surface free energy of the samples decreased with replacement of polyol with additive up to 5 mol %. A Scanning electron microscope equipped with energy dispersive X‐ray detector revealed that for the samples containing more than 5 mol % additive, there was an enrichment of silicone at the interface of films and air. At long exposure times and higher concentrations of additive, depreciation of graffiti properties was seen. DMTA and attenuated total reflectance‐fourier transform infra‐red studies before and after ageing showed that the silicone additive tended to degrade while it could cause an increase in crosslinking density. Water contact angles and atomic force microscopy images after ageing revealed that the cause of the depletion in anti‐graffiti properties was attributed to the deterioration of the silicone additive. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
109.
The effects of artificial and natural tree gums on the mechanical, chemical, and aesthetic performances of two automotive acrylic/melamine clearcoats were studied. To this end, two clearcoats with different acrylic/melamine ratios were investigated. Biological experiments were performed under post-aging conditions using an accelerated weathering test. Analytical techniques including optical microscopy, scanning electron microscopy (SEM), gloss measurement, FTIR, and DMTA analyses were utilized to reveal the responses of the coating system upon exposure to the aforementioned biological materials. Contact angle measurements were also conducted to estimate the surface energy of the coatings. Greater crosslinking density, together with a higher T g and damping behavior of the clearcoat, indicative of a greater degree of cure, were obtained as the ratio of melamine crosslinker increased. It was shown that both Arabic and natural tree gums could strongly attach to the clearcoats’ surface, imposing a significant stress during the drying process, thereby leading to a physical failure. In addition, the acidic nature of these biological materials leads to a chemical alteration in the clearcoats’ structure. The greater crosslinking density and lower hydrophilicity of the clearcoats containing higher melamine crosslinker were responsible for the weaker interaction of gums with the surface. This showed a greater capability for stress damping. Small surface cracks with fracture morphology on the coatings exposed to biological materials at higher exposure times (in the xenon test) were also observed. This is discussed based on the adhesion of the coatings to gums at longer exposure times, because of significant stress. 相似文献
110.
This work is an attempt to study the effect of different latex types containing various auxiliary monomers and emulsifiers on their pigmentation and their corresponding behavior on scrub resistance. The auxiliary monomers investigated were acrylic acid (AA), methacrylic acid (MAA), and itaconic acid and the emulsifiers contained sodium lauryl sulfate (SLS) and sodium dodecylbenzene sulfonate (SDBS). It was shown that a semibatch polymerization technique which led to smaller particles and sharper size distributions is preferable. The best wet scrub results were obtained by using MAA and SLS. It was also shown that the proper selection of an auxiliary monomer generally depended on the range of incorporated pigment volume concentration (PVC). At high PVCs, AA gave better performances compared with MMA. The reverse effect was shown to occur at low PVCs. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献