Middle distillates from hydrocracking of FT waxes: Composition,characteristics and emission properties

A light cobalt catalyzed Fischer–Tropsch (FT) wax was subjected to hydrocracking in the range of temperature 319–351 °C and hydrogen pressure between 3.5 and 6.0 MPa. The catalyst used was platinum on amorphous silica–alumina. Hydrocracking reaction led to an increase of middle distillate yield up to 85% with a contemporary increase of iso-paraffins concentration which resulted in a remarkable improvement of cold flow properties of the products. The freezing point of C₁₀–C₁₄ fraction passed from ?23 to ?45 °C while the pour point of C₁₅–C₂₂ fraction decreased from 13 to ?23 °C. The latter fraction displayed high cetane numbers ranging between 75 and 80. Changes in carbon distribution and molecular structure of products during hydrocracking have been rationalized in the light of the accepted hydrocracking mechanism where n-paraffins undergo to consecutive isomerization reactions leading to isomers with progressively higher branching degree and concomitant cracking reaction. Experimental evidences support the view that apparent reactivity of n-paraffins is chain length dependent, increasing with the molecular weight. Detailed characterization by NMR and GC showed that branching groups abundance in the middle distillate products was the following: methyl ? ethyl > propyl.Emission tests carried out with FT diesel and commercial ultra low sulfur diesel showed that FT diesel has excellent combustion properties and leads to a reduction of emissions.     

Evaluating Off-Peak Traffic Signal Control Strategies

This article discusses the evaluation of flashing yellow as an off-peak traffic signal control strategy by establishing an interface between a real-time traffic simulation software HUTSIM (Helsinki University of Technology Simulation Model) and a standard NEMA (National Electrical Manufacturers Association) traffic signal controller. The analysis was performed as part of research dealing with evaluation of different off-peak traffic signal operation strategies and their relative impacts on delay, fuel consumption, vehicle emissions, and driver safety. Because of its widespread use, the main emphasis was on the flashing yellow signal control. Delay field study was performed to obtain and analyze real-world data and compare the efficiency of flashing yellow and fixed time control strategies. To widen the research effort and eliminate inaccuracies due to certain assumptions made during the field study, computer simulation was chosen as an effective tool for comparison of different control strategies. Four different strategies were evaluated: fixed time, fully and semiactuated, and flashing yellow. Flashing yellow was found to be the most efficient of the signal strategies. The impact of this type of off-peak signal control on driver safety also was studied, and a summary of results is presented.     

Personality trait development from age 12 to age 18: Longitudinal, cross-sectional and cross-cultural analyses.

Three studies were conducted to assess mean level changes in personality traits during adolescence. Versions of the Revised NEO Personality Inventory (P. T. Costa, Jr., & R. R. McCrae, 1992a) were used to assess the 5 major personality factors. A 4-year longitudinal study of intellectually gifted students (N = 230) was supplemented by cross-sectional studies of nonselected American (N = 1,959) and Flemish (N = 789) adolescents. Personality factors were reasonably invariant across ages, although rank-order stability of individual differences was low. Neuroticism appeared to increase in girls, and Openness to Experience increased in both boys and girls; mean levels of Extraversion, Agreeableness, and Conscientiousness were stable. Results extend knowledge of the developmental curve of penalty traits backward from adulthood and help bridge the gap with child temperament studies. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Myoelectric signal analysis using neural networks

It is shown that the capacity of a discrete Hopfield network for functional minimization allows it to extract the time-series parameters from a myoelectric signal (MES) at a faster rate than the previously used SLS algorithm. With a two-dimensional signal space consisting of one of the parameters and the signal power, a two-layer perceptron trained using back-propagation has been used to classify MES signals from different types of muscular contractions. The results suggest that neural networks may be suitable for MES analysis tasks and that further research in this direction is warranted.     

Effects of gabapentin on the different components of peripheral and central neuropathic pain syndromes: a pilot study

Anticonvulsants are widely used in the treatment of neuropathic pain, and are assumed to act preferentially on lancinating, shooting pain. In the present study, the effects of gabapentin, a novel anticonvulsant, were evaluated systematically on both spontaneous and evoked pain in 18 patients with peripheral nerve injuries or central lesions. Gabapentin was administered orally in gradually increasing doses up to a maximum of 2,400 mg/day. Evaluations of spontaneous ongoing and paroxysmal pain, allodynia and hyperalgesia were performed at the beginning of the study ('baseline') and 6 weeks after the steady-state dose had been reached. Quantitative sensory tests were used to measure detection and pain thresholds to mechanical and thermal stimuli and the responses to suprathreshold stimuli. Gabapentin induced a moderate and statistically significant relief of ongoing spontaneous pain and was particularly effective in reducing paroxysmal pain. A striking finding was the significant effect on brush-induced and cold allodynia. In contrast, no effects were observed on detection and pain thresholds to static mechanical and hot stimuli. Side effects were generally minor and did not interfere with everyday activities. The present study suggests that gabapentin has preferential antihyperalgesic and/or antiallodynic effects, and is equally effective in pain due to peripheral nerve injuries and central lesions.     

An examination of gender and racial differences among Missouri insanity acquittees

This study examines gender and racial differences among Missouri insanity acquittees, which included 42 African American females, 279 African American males, 63 Caucasian females, and 458 Caucasian males. Significant differences across the four groups were not found in age, current marital status, a diagnosis of borderline intellectual functioning/mental retardation, committing crimes of assault and burglary, and whether insanity acquittees ever received conditional releases to reside in the community. Some variations across the four gender/race categories were related to race (diagnoses of schizophrenia, mood disorders, and other Axis I diagnoses), but variations were more frequently related to gender (whether ever married; diagnoses of substance abuse, sexual disorders, antisocial personality disorder, borderline personality disorder, and any personality disorder; committing crimes of murder, sexual offenses, and serious offenses; and current residential status). African American males were identified as being an at-risk population. They were the most likely to have a schizophrenia diagnosis, a substance abuse diagnosis, an antisocial personality disorder diagnosis, and to be hospitalized on the survey date. Implications for treatment and future research are explored.     

Depressive psychomotor disturbance, cortisol, and dexamethasone

The reactivity of sera of 96 individuals infected with human T-cell leukemia virus type I (HTLV-I) was tested against various synthetic peptides corresponding to the gp46 immunodominant antigenic domains: residues 86-107, 175-199, and 239-261. The frequency of reactive sera was higher for 175-199 (93%) than for 239-261 (78%) or 86-107 (24%) with some variations in geographical regions and in diseases. The region 239-261 was extensively analyzed and five (linear or conformational) epitopes were found. The reactivity of sera toward functional or immunodominant domains may depend on the sequence of the infecting virus, and the role of three frequent substitutions (asparagine by tyrosine, proline by serine, and serine by proline or leucine at positions 93, 192, and 250 respectively) was established. Finally, the role of the genetic background of the host may condition the humoral immune response as individuals infected by HTLV-Is harboring the same predicted gp46 peptide sequence may recognize one, several, or all regions examined.