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21.
Male Wistar rats were fed for 4 wk on diets containing 2% oxidized corn oil. Liver tissue was then studied to determine the
effect of feeding peroxidized oil on lipogenic enzymes. Although substances which reacted with thiobarbituric acid increased
in liver microsomes and mitochondria with increasing peroxide values of the dietary corn oil fed, the activities of glucose-6-phosphate
dehydrogenase, malic enzyme and acetyl-CoA carboxylase in liver were unchanged. However, when rats were fed for 2 wk on diets
containing 10% fat, of which 0.5, 5 or 10% was unoxidized corn oil and the remainder was hydrogenated beef tallow filler,
the lipogenic enzyme activities and also the liver triglyceride levels were observed to decrease with increasing amounts of
dietary corn oil. Therefore, although a synthetic diet containing corn oil was easy to oxidize spontaneously, the reductions
of lipogenic enzymes in rats fed the diet would not have been caused by lipid peroxides but by unsaturated fatty acids themselves. 相似文献
22.
23.
The improvement of heat resistance and mechanical properties of phenolic resin was examined with the blend of novolac and copolymers prepared from p-hydroxyphenylmaleimide (HPMI) and styrene. Copolymers of HPMI and styrene with various molecular weights were synthesized. Glass transition (Tg) and thermal decomposition temperatures of the copolymers were measured by differential scanning calorimetry (DSC) and thermogravimetry (TG), respectively. The miscibility of the copolymers with novolac was examined by DSC. It was found that the copolymers had a good heat resistance and a good miscibility with novolac. Molding compounds were prepared by hot roll-kneading of mixtures that involved novolac, copolymer, hexamethylenetetramine (hexamine), and glass fiber. It was found that the test pieces prepared by transfer molding from the molding compounds showed a good heat resistance and better mechanical properties than phenolic resin modified with HPMI homopolymer. 相似文献
24.
Ling Xiao Jinlong Zhang Ye Cong Baozhu Tian Feng Chen Masakazu Anpo 《Catalysis Letters》2006,111(3-4):207-211
Fe3+ doped together with Au deposited TiO2 (Au/Fe3+–TiO2) was successfully prepared, which shows excellent photocatalytic activity for degradation of methyl orange (MO) under both
UV and visible light (λ > 420 nm) illumination. Fe3+ has been confirmed by EPR to substitute for Ti4+ in the TiO2 lattice, and Au exists as Au0 on the surface of the photocatalyst indicated by the results of XRD. Fe3+ and Au have synergistic effects on improving the photocatalytic activity of TiO2. A proposed mechanism concerning the synergistic effects is discussed to explain the improvement of the photocatalytic activities. 相似文献
25.
The characteristics of gas bubbles in a 5 cm diameter bubble column equipped with a single orifice of 1,3 or 5 mm diameter were investigated under system pressure of 0.1-15 MPa. The formation of gas bubbles was strongly affected by the system pressure. Under high pressures a dispersed gas jet was formed at gas velocities where spherical gas bubbles would have been formed at atmospheric pressure. The critical gas velocity between the bubbling regime and the jetting regime was correlated with the liquid phase Weber number and the gas phase Reynolds number based on the gas velocity at the orifice. Bubble size and gas holdup in the main part of the bubble column were also affected by the bubble formation pattern at the distributor 相似文献
26.
Jiunn Yih Lee Hisashi Tanaka Hideo Takezoe Atsuo Fukuda Eiichi Kuze Hiroshi Iwanaga 《应用聚合物科学杂志》1984,29(3):795-802
A novel method is proposed of preparing thin Ag–Hg alloy on PAAm film surface at room temperature: The film of interest is formed by holding PAAm aqueous solution with AgNO3 in Hg-saturated atmosphere. Two kinds of films, one of which is a conductor and the other an insulator, can be selectively formed with pH-controlled PAAm solution by ammonia. The conducting surface is assigned to the α phase of Ag–Hg alloy by means of X-ray analysis. Potentiometric titration and IR spectral studies suggest the existence of PAAm–Ag+ complexes. On the basis of their structure and the oxidation and reduction potential of Ag+ and Hg2+, the mechanism of film formation is also discussed. 相似文献
27.
The liver lipogenic enzymes are compared among rats, chickens, frogs and fish. Although the apparent Km values of glucose-6-phosphate
dehydrogenase for glucose-6-phosphate are not much different among all the species, those of malic enzyme for malate are much
higher in chickens and fish than in rats and frogs. Glucose-6-phosphate dehydrogenase showed very high activities compared
with malic enzyme in fish liver, and malic enzyme showed high activities in chicken liver. Although the apparent Km values
of acetyl-CoA carboxylase and fatty acid synthetase for substrates are in the same range among all the animals, the activity
of acetyl-CoA carboxylase seems to be extremely low in fish and frog livers, and that of fatty acid synthetase is low in frog
livers only. In addition, the apparent Km values of α-glycerophosphate acyltransferase of fish liver are very high, and the
enzyme activity appears to be extremely low compared to the others. Therefore, the enzymes at the first steps of both fatty
acid and glycerolipid syntheses of poikilothermos animals appear to be very low. On the other hand, the Ouchterlony double-diffusion
patterns showed that the lipogenic enzymes of chickens, frogs and fish are immunologically different from those of rats, with
the exception of acetyl-CoA carboxylase in chickens. Therefore, it is suggested that the fatty acid and glycerolipid forming
systems of poikilothermos animals are quite different from those of homoiothermos and the lipogenesis is very low in poikilothermos. 相似文献
28.
Chengzhi Hu Masahiro Nakajima Tao Yue Masaru Takeuchi Minoru Seki Qiang Huang Toshio Fukuda 《Microfluidics and nanofluidics》2014,17(3):457-468
Alginate hydrogel has widespread applications in tissue engineering, cancer therapy, wound management and drug/cell/growth factor delivery due to its biocompatibility, hydrated environment and desirable viscoelastic properties. However, the lack of controllability is still an obstacle for utilizing it in the fabrication of 3D tissue constructs and accurate targeting in mass delivery. Here, we proposed a new method for achieving magnetic alginate hydrogel microfibers by dispersing magnetic nanoparticles in alginate solution and solidifying the magnetic alginate into hydrogel fiber inside microfluidic devices. The microfluidic devices have multilayered pneumatic microvalves with hemicylindrical channels to fully stop the fluids. In the experiments, the magnetic nanoparticles and the alginate solution were mixed and formed a uniform suspension. No aggregation of magnetic nanoparticles was found, which is crucial for flow control inside microfluidic devices. By regulating the flow rates of different solutions with the microvalves inside the microfluidic device, magnetic hydrogel fibers and nonmagnetic hydrogel fibers were fabricated with controlled sizes. The proposed method for fabricating magnetic hydrogel fiber holds great potential for engineering 3D tissue constructs with complex architectures and active drug release. 相似文献
29.
Hiroshi Mori Noritaka Mizuno Masahiro Tajima Shuichi Kagawa Masakazu Iwamoto 《Catalysis Letters》1991,10(1-2):35-39
Proton exchanged ultrastable Y-type zeolite with silica/alumina = 40 showed a pronounced catalytic activity for the formation of ethyl methyl ketone directly from 1-butene and water. The formation rate of ethyl methyl ketone was much higher than those on MoO3-based catalysts in the oxidation of 1-butene by oxygen. It was suggested that the basic site necessary for the formation of ethyl ketone directly from 1-butene and water would be the pentacoordinated Al. 相似文献
30.
Summary Segmented polymers with random sequences of conjugated and non-conjugated blocks are produced by partial dehydrogenation of poly(-thiophenediyl)benzylidene. The fraction of conjugated block was controlled by the elimination time. The polymers gave photoluminescence. Absorption coefficients of the polymers increased with the rate of dehydrogenation, and the highest fluorescence intensity were achieved around 9 % conjugation conversion. The polymers were characterized by 1H- and 13C-n.m.r. and infrared spectra, and were soluble in common organic solvents, which suggests a good processability. 相似文献