Study on Planar Whispering Gallery Dielectric Resonators. II. A Multiple-Band Device

The basic theory underlying the realization of simple multiple-band non-homogeneous dielectric resonators, whose spectral response is the overlap of single-resonator frequency bands, is developed exploiting a general approach discussed in the previous companion paper. The limit frequencies of the proposed devices, given only by the dielectric properties of the involved materials, can differ in principle by several decades. Experimental confirmations have been obtained on a composite structure built up with teflon and polyethylene; as predicted by the theory, the overall band includes frequencies which range about from 20 GHz to more than 400 GHz, when high frequency resonances are selectively excited. The localization of the higher frequency radiation between the positive steps of the dielectric constant, which is the basic properties of these non-homogeneous resonators, has been experimentally verified by mapping the electromagnetic field intensity. Possible applications of multiple-band Whispering Gallery dielectric resonators are finally outlined.     

Si-Al-O-N Fibers from Polymeric Precursor: Synthesis, Structural, and Mechanical Characterization

Polymeric fibers were produced from a polyaluminocarbosilane obtained by reacting polycarbosilane and an aluminum alkoxide modified with a β-ceto ester. The pre-ceramic fibers were converted into amorphous Si-Al-O-N ceramic fibers after a pyrolysis process under flowing ammonia at 1000°C. ²⁹Si and ²⁷Al magic-angle spinning nuclear magnetic resonance investigations were performed to characterize the conversion process of the polymeric precursor fibers into the ceramic product. However, because of the amount of matter required for the MAS-NMR experiments, the heat treatment applied for fibers was done on powders assuming identical evolution for both materials. Tensile strength was measured at various stages of the pyrolysis process and related to the corresponding structural evolution.     

Reliability improvements in 50 nm MLC NAND flash memory using short voltage programming pulses

For the first time, an innovative programming methodology based on the use of ultra-short voltage pulses is applied in NAND flash architecture. The methodology starts from the physics of SILC dynamics and oxide damage, and relies on the trade-off between duration and amplitude of short voltage programming pulses, minimizing the creation of new traps in the tunnel oxide. The short pulses programming technique is applied on a small 50 nm NAND array designed for multibit application. Benefits of the short-pulse operation lie in that data retention and endurance which show meaningful improvements. The result is relevant for application in multibit technology, and opens the way to more aggressive cell scaling rules.     

Molecular dynamics characterization of crystalline and amorphous TiSi2 phases

Molecular dynamics simulations by a tight binding potential provide new interesting information on the ground state properties of the TiSi₂ phases. In particular, we have compared some structural, elastic, thermodynamic and electronic properties of the C49, the C54 and the amorphous phases. It turns out that the C49 structure is much softer than the C54, also displaying a melting temperature some 300–400 K below the one for the C54, in agreement to very recent experimental results. The amorphous phase is energetically and structurally more akin to the C49 than to the C54 phase. On the basis of these results we suggest the higher formation kinetics of the former to be related to an intrinsic advantage in the growth stage.     

Preparation of polymeric hybrid nanocomposites based on PE and nanosilica

In this study the realization of nanocomposites based on a melt dispersion of nanoscopic silica particles in a polyethylene matrix is described. Different silane coupling agents were used to improve the interaction between nanosilica and polyethylene and then to improve the dispersion of the filler. In one case vinyl groups-containing silane coupling agents containing were used. The nanocomposite obtained with this modifier was transformed in a crosslinked organic-inorganic hybrid after an electron beam radiation treatment. The nanocomposites and the hybrid were characterized with TEM and FTIR. The thermal decomposition was studied in TGA. Mechanical properties were also detected, in a small punch test and wear resistance in a rotative drum abrader.     

Intentions in the Coordinated Generation of Graphics and Text from Tabular Data

To use graphics efficiently in an automatic report generation system, one has to model messages and how they go from the writer (intention) to the reader (interpretation). This paper describes PostGraphe, a system which generates a report integrating graphics and text from a set of writer's intentions. The system is given the data in tabular form as might be found in a spreadsheet; also input is a declaration of the types of values in the columns of the table. The user then indicates the intentions to be conveyed in the graphics (e.g., compare two variables or show the evolution of a set of variables) and the system generates a report in LATEX with the appropriate PostScript graphic files. PostGraphe uses the same information to generate the accompanying text that helps the reader to focus on the important points of the graphics. We also describe how these ideas have been embedded to create a new Chart Wizard for Microsoft Excel. Received 20 August 1998 / Revised 2 September 1999 / Accepted 27 September 1999     

The influence of formulation and cooling rate on the rheological properties of chocolate

Rheological properties of chocolate play a relevant role either in process design or texture definition. Nevertheless, only flow properties of molten product or mechanical properties of samples cooled at fixed temperature (usually 20 °C) are measured, whilst testing conditions close to the industrial applications (temperature close to 30 °C) are less common to be used. In this work, chocolate samples (cooled at 1 and 5 °C min⁻¹) were characterised at 30 °C by using small-amplitude oscillations and low-stress creep tests, aiming at establishing how material properties are related to the chocolate microstructure. The effects of either 3 anhydrous milk fats (AMF), having different melting points, or sugar particle size were evaluated. It was found that addition of AMFs, owing to their solid content, can yield an increase in consistency; however, this effect is less relevant when coarse sugar is used, because of the broader particle size distribution, and it depends on the thermal history because of the different fat crystallisation time. Finally, creep tests resulted to be very sensitive in detecting changes in chocolate rheological properties.     

Coprecipitation of arsenate with metal oxides: nature, mineralogy, and reactivity of aluminum precipitates

Arsenic mobilization in soils is mainly controlled by sorption/desorption processes, but arsenic also may be coprecipitated with aluminum and/or iron in natural environments. Although coprecipitation of arsenic with aluminum and iron oxides is an effective treatment process for arsenic removal from drinking water, the nature and reactivity of aluminum- or iron-arsenic coprecipitates has received little attention. We studied the mineralogy, chemical composition, and surface properties of aluminum-arsenate coprecipitates, as well as the sorption of phosphate on and the loss of arsenate from these precipitates. Aluminum-arsenate coprecipitates were synthesized at pH 4.0, 7.0, or 10.0 and As/Al molar ratio (R) of 0, 0.01, or 0.1 and were aged 30 or 210 d at 50 degrees C. In the absence of arsenate, gibbsite (pH 4.0 or 7.0) and bayerite (pH 10.0) formed, whereas in the presence of arsenate, very poorly crystalline precipitates formed. Short-range ordered materials (mainly poorly crystalline boehmite) formed at pH 4.0 (R = 0.01 and 0.1), 7.0, and 10.0 (R= 0.1) and did not transform into Al(OH)3 polymorphs even after prolonged aging. The surface properties and chemical composition of the aluminum precipitates were affected by the initial pH, R, and aging. Chemical dissolution of the samples by 6 mol L(-1) HCl and 0.2 mol L(-1) oxalic acid/ oxalate solution indicated that arsenate was present mainly in the short-range ordered precipitates. The sorption of phosphate onto the precipitates was influenced by the nature of the samples and the amounts of arsenate present in the precipitates. Large amounts of phosphate partially replaced arsenate only from the samples formed at R = 0.1. The quantities of arsenate desorbed from these coprecipitates by phosphate increased with increasing phosphate concentration, reaction time, and precipitate age butwere always lessthan 30% of the amounts of arsenate present in the materials and were particularly low (<4%) from the sample prepared at pH 4.0. Arsenate appeared to be occluded within the network of short-range ordered materials and/or sorbed onto the external surfaces of the precipitates, but sorption on the external surfaces seemed to increase by increasing pH of sample preparation and aging. Furthermore, at pH 4.0 more than in neutral or alkaline systems the formation of aluminum arsenate precipitates seemed to be favored. Finally, we have observed that greater amounts of phosphate were sorbed on an aluminum-arsenate coprecipitate than on a preformed aluminum oxide equilibrated with arsenate under the same conditions (R = 0.1, pH 7.0). In contrast, the opposite occurred for arsenate desorption, which was attributed to the larger amounts of arsenate occluded in the coprecipitate.     

Long-term aerobic cometabolism of a chlorinated solvent mixture by vinyl chloride-, methane- and propane-utilizing biomasses

The aerobic cometabolic biodegradation of a mixture of chlorinated aliphatic hydrocarbons (CAHs) including vinyl chloride (VC), cis- and trans-1,2-dichloroethylene (cis-DCE, trans-DCE), trichloroethylene (TCE), 1,1,2-trichloroethane (1,1,2-TCA) and 1,1,2,2-tetrachloroethane (1,1,2,2-TeCA) was investigated at both 25 and 17 degrees C by means of bioaugmented and non-bioaugmented sediment-groundwater slurry microcosm tests. The goals of the study were (i) to study the long-term aerobic biodegradation of a CAH mixture including a high-chlorinated solvent (1,1,2,2-TeCA) generally considered non-biodegradable in aerobic conditions; (ii) to investigate the efficacy of bioaugmentation with two types of internal inocula obtained from the indigenous biomass of the studied site; (iii) to identify the CAH-degrading bacteria. VC, methane and propane were utilized as growth substrates. The non-bioaugmented microcosms were characterized, at 25 degrees C, by an average 18-day lag-time for the direct metabolism of VC (accompanied by the cometabolism of cis- and trans-DCE) and by long lag-times (36-264 days) for the onset of methane or propane utilization (associated with the cometabolism of the remaining CAHs). In the inoculated microcosms the lag-phases for the onset of growth substrate utilization and CAH cometabolism were significantly shorter (0-15 days at 25 degrees C). Biodegradation of the 6-CAH mixture was successfully continued for up to 410 days. The low-chlorinated solvents were characterized by higher depletion rates. The composition of the microbial consortium of a propane-utilizing microcosm was determined by 16s rDNA sequencing and phylotype analysis. To the best of our knowledge, this is the first study that documents the long-term aerobic biodegradation of 1,1,2,2-TeCA.     

Nonparaxial fields with maximum joint spatial-directional localization. I. Scalar case

In paraxial optics, the spatial and angular localization of a beam are usually characterized through second moments in intensity. For these measures, Gaussian beams have the property of achieving a minimum angular spread for a given spatial spread (or beam waist). For wide-angle fields, however, the standard measures of spatial and angular localization become inappropriate, and new definitions must be used. Previously proposed definitions [J. Opt. Soc. Am. A 17, 2391 (2000)] are adopted, and the scalar monochromatic wave fields that achieve a minimum angular spread for a given spatial spread are found.