全文获取类型
收费全文 | 2128篇 |
免费 | 155篇 |
国内免费 | 4篇 |
专业分类
电工技术 | 28篇 |
综合类 | 1篇 |
化学工业 | 465篇 |
金属工艺 | 43篇 |
机械仪表 | 75篇 |
建筑科学 | 104篇 |
能源动力 | 184篇 |
轻工业 | 375篇 |
水利工程 | 14篇 |
石油天然气 | 9篇 |
无线电 | 125篇 |
一般工业技术 | 431篇 |
冶金工业 | 71篇 |
原子能技术 | 13篇 |
自动化技术 | 349篇 |
出版年
2024年 | 8篇 |
2023年 | 23篇 |
2022年 | 53篇 |
2021年 | 93篇 |
2020年 | 87篇 |
2019年 | 92篇 |
2018年 | 103篇 |
2017年 | 90篇 |
2016年 | 121篇 |
2015年 | 70篇 |
2014年 | 101篇 |
2013年 | 208篇 |
2012年 | 126篇 |
2011年 | 172篇 |
2010年 | 119篇 |
2009年 | 151篇 |
2008年 | 135篇 |
2007年 | 110篇 |
2006年 | 76篇 |
2005年 | 61篇 |
2004年 | 55篇 |
2003年 | 40篇 |
2002年 | 40篇 |
2001年 | 12篇 |
2000年 | 14篇 |
1999年 | 24篇 |
1998年 | 23篇 |
1997年 | 11篇 |
1996年 | 17篇 |
1995年 | 6篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 6篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有2287条查询结果,搜索用时 15 毫秒
111.
Tünçay Mehmet Masum Nguyen Lucie Hendrickx Philippe Brochu Mathieu 《Journal of Materials Engineering and Performance》2016,25(10):4521-4528
Journal of Materials Engineering and Performance - Spark plasma sintering (SPS) is a powder metallurgy process that sinters powder materials within a short time by simultaneous application... 相似文献
112.
Safdar Muhammad Ozaslan Mehmet 《Journal of Inorganic and Organometallic Polymers and Materials》2022,32(5):1819-1827
Journal of Inorganic and Organometallic Polymers and Materials - In this study, the nanosized spherical erythromycin capped gold nanoparticles (eryth-Au(0)NPs) were fabricated for the first time.... 相似文献
113.
Effects of reactive and nonreactive POSS types on the mechanical,thermal, and morphological properties of plasticized poly(lactic acid)
下载免费PDF全文
![点击此处可从《Polymer Engineering and Science》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The aim of this study is to investigate the effects of the reactive and nonreactive polyhedral oligomeric silsesquioxane (POSSs) types and their composition on the mechanical, thermal, and morphological properties of poly(ethylene glycol) plasticized poly(lactic acid) (PLA) composites prepared with melt compounding. The results showed that the incorporation of POSS decreased the melt viscosity of the compounds regardless of POSS type. The lowest viscosity was obtained with epoxy‐POSS, which is the only one that is liquid at processing temperature in comparison to the others. It was revealed from the mechanical tests that the toughness‐related properties such as impact strength and elongation at break improved by the addition of POSS without remarkable deterioration in stiffness. The chemical structure of the POSS influenced the level of dispersion and hence the mechanical performance of the composites. Octaisobutyl‐POSS, being the nonreactive and nonpolar one, had the best dispersion among the other reactive and polar POSS types. The glass transition temperature of the matrix decreased in the presence of POSS types. In addition, the POSS particles also had an impact on the crystallization of PLA. The thermal stability of the composites improved in the presence of POSS particles with respect to the POSS content and the POSS type. POLYM. ENG. SCI., 54:264–275, 2014. © 2013 Society of Plastics Engineers 相似文献
114.
Electrochemical polymerization of aniline, on a Pt foil electrode coated with poly(methyl methacrylate) (PMMA), produces a homogeneous, free-standing, flexible, and conductive polymer film. The conductivity of the films depends on the aniline content and reaches 0.1–0.2 S/cm for films having aniline content of 15% or more. The optimum thickness of precoated PMMA to obtain durable conducting films was found to be in the range of 10–15 μm. Cyclic voltammetric investigation revealed that aniline exhibits a similar electrochemical behavior on a PMMA coated platinum electrode similar to a bare Pt surface. The film gives a fast and reproducible response against ammonia gas within a concentration range of 1.0–0.01%. Scanning electron micrographs indicate that the films have a rough structure consisting of globular regions. © 1996 John Wiley & Sons, Inc. 相似文献
115.
Reat Apak Mehmet Hugül 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1996,67(3):221-226
A number of chlorophenols, namely 2-, 3-, and 4-chlorophenol, 2,4-dichlorophenol and 2,4,6-trichlorophenol, have been decomposed in aqueous solution by using hydrogen peroxide as the oxidizing agent under UV radiation emitted by a 400 W high-pressure mercury lamp in a thermostatted Pyrex-glass column photoreactor, and the organic-bound chlorine has been converted into the environmentally harmless inorganic chloride. For H2O2/chlorophenol mole ratios between 1: 1 and 16: 1, the photooxidation reaction approached pseudo-first order kinetics, and the rate constants increased with increasing ratio of the oxidant. A theoretical model for the degradation pathway is proposed. The fact that the reaction order was not simply unity could be attributed to the complex reaction sequence processing via a radical mechanism through colored intermediates possibly comprising hydroquinone, catechol and resorcinol. 相似文献
116.
Mehmet Fatih Cengiz M. Zeki Durak Sukriye Nilufer Ayşe Kevser Bilgin 《International Journal of Food Properties》2013,16(4):746-756
An ion chromatographic method for the quantitative determination of free cyanide in bottled natural mineral waters were measured in terms of selectivity, linearity, the limit of detection, limit of quantification, repeatability, precision, and accuracy. Chromatographic separation of free cyanide ions was accomplished with an anion-exchange column and detected by pulsed amperometric detection with a silver working electrode. The method was found to be selective, linear (r2 = 0.999) at a concentration range of 0.5 to 134 μg L?1, precise, and accurate. Recovery values of free cyanide in all classes of natural mineral water varied from 65.9 ± 1.6 to 95.2 ± 0.7 at different spiking levels (5–70 μg L?1). Parameters (total dissolved solids, mineral interferences, and added sodium hydroxide) affecting the recovery values were studied in this project. The limit of detection and limit of quantification were found to be 0.295 and 0.983 μg L?1, respectively. The proposed method was applied to 27 different brands of commercially available bottled natural mineral water products sold in Turkish markets. These natural mineral waters were classified as: (i) very low mineral concentration, (ii) low mineral concentration, (iii) intermediate mineral concentration, and (iv) high mineral concentration based on their total dissolved solids contents according to European Union Directive (Directive 80/777/EEC). Levels of free cyanide residues in the samples ranged from > limit of detection to 6.12 μg L?1. The highest average concentration of free cyanide residues was found in the class of “high mineral concentration waters.” However, the determined free cyanide values in all of the tested natural mineral water samples were found to be within the limits of European Union legislation. 相似文献
117.
118.
Baki Hazer Songun I. Demirel Mehlika Borcakli Mehmet S. Eroglu Miko Cakmak Burak Erman 《Polymer Bulletin》2001,46(5):389-394
Summary
Poly(-3-hydroxy alkanoate) containing unsaturated side chains, PHA-soybean, were produced by feeding Pseudomonas oleovorans with soybean oily acids obtained from soybean oil. Unsaturation of PHA-soybean were found to be 10 mol-% of unsaturated side
chains.
Main saturated part of the biopolymer was Poly(3-hydroxy octanoate) with minor hexanoate and decanoate units. PHA films were
crosslinked via free radical mechanism by means of thermally or under UV irradiation in the presence of benzoyl peroxide,
benzophenon, and /or ethylene glycol dimethacrylate (EGDM). Crosslinking yield of the PHA films were found to be from 81 to
93 wt.-% from the sol-gel analysis. Swelling properties of the crosslinked PHA films in chloroform and toluene were also studied.
Mc values of crosslinked PHAs were also calculated using Flory-Rehner equation. The crosslinked biopolyester obtained by thermally
at 60 °C with benzoyl peroxide indicated the highest crosslinking density. Glass transition temperatures (Tg) of crosslinked
biopolyester samples were changed from −33 to −45 °C while that of PHA-soybean was −60 °C.
Received: 16 June 2000/Revised version: 22 January 2001/Accepted: 20 May 2001 相似文献
119.
The concentrations of myricetin in medicinal plants such as Rosa canina L. (rosa hip), Terebinthina chica L. (terebinth), Urtica dioica L. (nettle), and Portuca oleracea L. (purslane) were determined by high-performance liquid chromatography-mass spectrometry (HPLC-MS). The aglycones of myricetin were extracted using methanol–ascorbic acid– hydrochloric acid, methanol–hydrochloric acid, and methanol, separated within 5 min, and individually quantitated in the positive ionization mode using optimized conditions for HPLC-MS. Methanol–ascorbic acid–hydrochloric acid was the optimum extraction solvent. The myricetin concentration in the plants were between 3 and 58 mg kg?1, with a limit of quantification equal to 0.1 mg L?1. 相似文献
120.
Modelling and boundary control for the Burgers equation is studied in this paper. Modelling has been done via processing of numerical observations through proper orthogonal decomposition (POD) with Galerkin projection. This results in a set of spatial basis functions together with a set of ordinary differential equations (ODEs) describing the temporal evolution. Since the dynamics described by the Burgers equation are non-linear, the corresponding reduced-order dynamics turn out to be non-linear. The presented analysis explains how the free boundary condition appears as a control input in the ODEs and how controller design can be accomplished. The issues of control system synthesis are discussed from the point of practicality, performance and robustness. The numerical results obtained are in good compliance with the theoretical claims. A comparison of various different approaches is presented. 相似文献