Controlled synthesis of crosslinked polyamide 6 using a bis-monomer derived from cyclized lysine

The controlled synthesis of polyamide 6 chemical networks by anionic ring-opening copolymerization of ε-caprolactam (CL) with synthesized bis-ε-caprolactam derived from α-amino-ε-caprolactam, i.e. N-functionalized α-amino-ε-caprolactam bis-monomers, using sodium ε-caprolactamate as an initiator and hexamethylene-1,6-dicarbamoylcaprolactam as di-functional fast activator was examined in bulk at 140 °C. An urea-based bis-monomer and CL were first shown to copolymerize with a decreasing polymerization rate due to side reactions. On the contrary, quantitative copolymerization of CL with various amounts of bis-N(2-oxo-3-azepanyl)-1,6-tetramethylenediamide, an amide-based bis-monomer, leads to fast kinetics similar to the homopolymerization of CL. Crosslinked PA6 with network exhibiting elastic or viscoelastic behaviors, depending on the amount of crosslinker, were observed and characterized by swelling in hexafluoroisopropanol, dynamic mechanical analysis and rheology measurements. Crystallinity and swelling were shown to decrease with the increasing content of the crosslinking agent.     

Experimental and theoretical investigations of the lateral vibrations of an unbalanced Jeffcott rotor

The current work experimentally explores and then theoretically examines the lateral vibrations of an unbalanced Jeffcott rotor-system working at several unbalance conditions. To this end, three conditions of eccentric masses are considered by using a Bently Nevada RK-4 rotor kit. Measurements of the steady-state as well as the startup data at rigid and flexible rotor states are captured by conducting a setup that mimics the vibration monitoring industrial practices. The linear governing equation of the considered rotor is extracted by adopting the Lagrange method on the basis of rigid rotor assumptions to theoretically predict the lateral vibrations. The dynamic features of the rotor system such as the linearized bearing induced stiffness are exclusively acquired from startup data. It is demonstrated that, with an error of less than 5%, the proposed two-degrees-of-freedom model can predict the flexural vibrations at rigid condition. While at flexible condition, it fails to accurately predict the dynamic response. In contrast to the other works where nonlinear mathematical models with some complexities are proposed to mathematically model the real systems, the present study illustrates the applicability of employing simple models to predict the dynamic response of a real rotor-system with an acceptable accuracy.     

Novel design of a triple band PIFA antenna by using a binary genetic algorithm

Journal of Computational Electronics - In this study, we propose a miniature triple band PIFA antenna (planar inverted-F antenna) composed of uniform semi-patches for LTE2600/WLAN/WIMAX/HIPERLAN-2...     

NUMERICAL STUDY OF DEVELOPING NATURAL LAMINAR CONVECTION IN A VERTICAL HYPERBOLIC DUCT OF A FIXED LENGTH AND WITH A CONSTANT WALL TEMPERATURE

The natural laminar convection in a vertical hyperbolic duct of a fixed length and with a constant wall temperature is numerically investigated. The governing equations are solved by a finite difference method. The results are obtained for the velocity, temperature, and pressure fields, and for the mean heat transfer coefficient. The numerical calculations are fulfilled for Rayleigh numbers ( Ra ) ranging from 5 to 3 · 104 and for the numerical eccentricity ranging from 5 to 100. The effects of the numerical eccentricity and Ra are examined and the results are compared with those of a cylindrical vertical duct. It was found that the flow fields and Nusselt number ( Nu ) are affected significantly at small values of the numerical eccentricity and Ra .     

Natural occurrence of ochratoxin A in Tunisian cereals

Ochratoxin A (OTA) is a mycotoxin produced by several fungal species from Aspergillus and Penicillium genera. It is widespread in food and feed and its occurrence has been reported in cereals, cereal-derived products, dried fruits and spices. This mycotoxin was implicated in several human and animal pathologies such as the Balkan Endemic Nephropathy (BEN) and the Tunisian Chronic Interstitial Nephropathy (CIN) of unknown cause. In Tunisia, a clear correlation has been established between the consumption of OTA contaminated food and the induction of specific pathologies. Thereby, OTA was detected in human blood and tissues. The aim of our study was to investigate the presence of OTA in widely consumed cereals commercialized in Tunisia. The analytical methods used in our study involved the extraction of OTA by acidified toluene, immunoaffinity (IAC) clean-up and HPLC quantification with fluorescence detection. Levels and percentages of OTA contamination in different types of cereals, 110 wheat, 103 barley, 113 sorghum and 96 rice samples, were evaluated with incidences of 38%, 40%, 38% and 28%, respectively. The average of contamination by OTA found were 55, 96, 44 and 117 μg/kg, respectively, for wheat, barley, rice and sorghum. Our results showed that contamination percentages and levels in the period from 2004 to 2005 were higher then usual norms (5.0 μg OTA/kg) established by the European commission in 2002. The present report is the first one ever carried out on the natural occurrence of OTA in cereals, largely consumed by the Tunisian population.     

Entropy generation in Poiseuille–Benard channel flow

The issue of entropy generation in Poiseuille–Benard channel flow is analyzed by solving numerically the mass, momentum and energy equations with the use of the classic Boussinesq incompressible approximation. The numerical scheme is based on Control Volume Finite Element Method with the SIMPLER algorithm for pressure–velocity coupling. Results are obtained for Rayleigh numbers Ra and irreversibility φ ranging from 10³ to 5×10⁴ and from 10⁻⁴ to 10 respectively. Variations of entropy generation and the Bejan number as a function of Ra and φ are studied. The limit value φ_l for which entropy generation due to heat transfer is equal to entropy due to fluid friction is evaluated. It has been found that φ_l is a decreasing function of the Rayleigh number Ra. φ_l varies from 0.0015 to 0.096 when Ra decrease from 5×10⁴ to 10³. Stream lines and entropy generation maps are plotted at six times over one period at Ra =10⁴ and φ=10⁻³. It has been found that the maximum entropy generation is localized at areas where heat exchanged between the walls and the flow is maximum. No significant entropy production is seen in the main flow.     

Evolution of ochratoxin A content during red and rose vinification

BACKGROUND: This work aims to investigate the effects of the common vinification steps on the fate of the ochratoxin A (OTA) during wine making. Two assays of red and rose microvinification, with artificially contaminated grapes, were performed. The content of this mycotoxin was also monitored throughout the process of red wine making from naturally contaminated grapes in a winery. RESULTS: The results from the different assays revealed that the maceration of pomace have a significant effect on the increase of OTA content in red wine (P < 0.05) whereas the alcoholic fermentation had a reducing effect. However, the spontaneous malolactic fermentation showed no significant effect on the OTA content in wine (P > 0.05). Storage of red wine in tanks followed by draining caused a significant decrease of OTA of about 55%. Clarification with a gelatin oenological fining agent contributed to the removal of up to 58% of OTA from red wine. CONCLUSION: Overall, a consistent decrease in OTA concentration was noticed throughout either red or rose vinification. This work has contributed to the understanding of the fate of OTA during different vinification processes, especially from naturally contaminated grapes. Copyright © 2008 Society of Chemical Industry     

Uncertainty of shape memory alloy micro-actuator using generalized polynomial chaos method

Microsystem Technologies - In last decades, there has been an increasing interest in the use of micromachining technology. Intelligent materials such as shape memory alloy are considered for the...