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991.
Abstract:

Researchers say that teachers can implement an educational innovation without adhering to the principles underpinning its design. Such principles may not adequately take typical classroom conditions into account. The goal of this study was to explore tensions between attempts to implement the principles underpinning knowledge building and the influence of contextual factors that compete for the teacher's attention. To this end, we discuss five excerpts from a discussion of the motion of spinning tops held by a class of Grade‐4 students, coming at the end of a five‐month implementation of knowledge building. Each excerpt is followed first by the teacher's perspective and then by the researcher's perspective. Our analysis highlights two tensions that constrain agency, arising from the students’ need for social development and their need to learn scientific concepts. We offer some suggestions for addressing these tensions.  相似文献   
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A wide variety of motivations for engaging with narratives have been proposed and studied. We propose that underlying these motivations is another, more fundamental motivation. Our premise is that maintenance, defense, and regulation of the personal and social self in daily life are demanding both emotionally and cognitively. Moreover, any individual self is constrained by capability, situation, and social role. Stories and identification with story characters provide a means individuals may use for temporary relief from the task of self‐regulation and from the limitations of individual personal and social identities. Existing supportive research is acknowledged and implications explored, concerning contexts in which story involvement will be particularly attractive and possible impacts on attitudes and acceptance of out‐groups including stigmatized others.  相似文献   
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Hydrogenation of p‐nitrophenol (PNP) to p‐aminophenol (PAP) using NaBH4 as a reducing agent was studied as a test reaction for determining the catalytic activity of supported Pt catalysts. The initial reaction rate, which is accessible within less than 10 min via online UV‐vis spectroscopy at room temperature, ambient pressure, and in water as solvent, was applied as measure for catalytic activity. For three Pt catalysts supported on porous SiO2, porous glass, and Al2O3, respectively, significant differences in the catalytic activity by almost one order of magnitude were observed. However, especially in the case of very active catalysts, limitations of the reaction by internal or external mass transfer have to be considered.  相似文献   
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Uric acid (UA) was detected in the presence of ascorbic acid (AA) at GC electrode by cyclic voltametry (CV) and differential pulse voltametry (DPV) in aqueous media of cationic polyelectrolyte (poly(diallyldimethylammonium chloride) (PDDA)). Both, UA and AA are anionic nature and electro-static attraction with cationic solution. This lowered their oxidation potentials and increased anodic current. In CV studies, the UA oxidation potential was decreased by 400 mV in the presence of PDDA along with increase in peak current. Effect of PDDA and pH on Epa and Ipa were also studied. About 360 mV difference in oxidation peak potentials was observed for AA and UA in PDDA media, which established a quick method for their simultaneous determination. The detection limit of UA in the presence of 200 folds AA was found as 1 μM with correlation coefficient of 0.994 and sensitivity of 0.05 μA μM−1. The proposed method has been also applied for determining the UA in human urine without any pretreatment, and found to be satisfactory.  相似文献   
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