Next-generation 100-gigabit metro ethernet (100 GbME) using multiwavelength optical rings

This paper investigates the challenges for developing the current local area network (LAN)-based Ethernet protocol into a technology for future network architectures that is capable of satisfying dynamic traffic demands with hard service guarantees using high-bit-rate channels (80...100 Gb/s). The objective is to combine high-speed optical transmission and physical interfaces (PHY) with a medium access control (MAC) protocol, designed to meet the service guarantees in future metropolitan-area networks (MANs). Ethernet is an ideal candidate for the extension into the MAN as it allows seamless compatibility with the majority of existing LANs. The proposed extension of the MAC protocol focuses on backward compatibility as well as on the exploitation of the wavelength domain for routing of variable traffic demands. The high bit rates envisaged will easily exhaust the capacity of a single optical fiber in the C band and will require network algorithms optimizing the reuse of wavelength resources. To investigate this, four different static and dynamic optical architectures were studied that potentially offer advantages over current link-based designs. Both analytical and numerical modeling techniques were applied to quantify and compare the network performance for all architectures in terms of achievable throughput, delay, and the number of required wavelengths and to investigate the impact of nonuniform traffic demands. The results show that significant resource savings can be achieved by using end-to-end dynamic lightpath allocation, but at the expense of high delay.     

Improving bandwidth efficiency in fault‐tolerant opaque IP over optical mesh networks

Adequately providing fault tolerance while using network capacity efficiently is a major topic of research in optical networks. In order to improve the network utilization, grooming of low‐rate connections in optical networks has been usually performed at the edge of the network. However, in all‐optical networks once a channel is assigned, its entire capacity is dedicated to the users independently of its grooming capabilities. As current users don't usually require such big capacities, bandwidth inefficiencies still occur. In this paper we address this issue introducing unlimited grooming per link (UGPL), a new restoration mechanism for opaque mesh optical networks that grooms connections on a per‐link basis. Simulation results show that UGPL provides the best bandwidth efficiency and the best blocking probability compared to traditional 1 + 1 protection and 1 : N end‐to‐end sharing schemes. Furthermore, we show that the 1 : N end‐to‐end restoration scheme provides no benefits over the simpler and faster 1 + 1 protection scheme. Copyright © 2004 John Wiley & Sons, Ltd.     

Spreading Codes Generator for Wireless CDMA Networks

The prime characteristic of spread spectrum modulated signals is that their bandwidth is greater than the information rate. In this way a redundancy is introduced that allows the severe levels of inteference inherent in the transmission of digital information over radio and satellite links to be overcome. Current spread spectrum applications are primarily in military communications; nevertheless, there is growing interest in this technique for third generation mobile radio networks (UMTS, FPLTS, etc.) with open discussion regarding the practicality of using a multiple access system based on spread spectrum techniques (CDMA). However, in order to support as many users in the same bandwidth as other multiple access techniques such as TDMA or FDMA, it is important how to generate large families of sequences that present low cross-correlation. The aim of this paper is to describe a spreading codes generator that can produce a large number of PN sequences with good properties of auto- and cross-correlation. Moreover, the codes generated shows high unpredictability and good statistical behaviour. This also allows the implementation of some features that are common on military networks such as message privacy (increasingly important in commercial networks) without additional cost. The structure presented shows itself to be advantageous for high speed generation of codes at a low cost, low power consumption (allowing longer life for batteries), small size and simplicity of implementation, essential ingredients for commercial equipment. Another attractive feature is its structural parallelism, useful in VLSI implementations. All of these features render it potentially suitable for the implementation of channel bandwidth sharing systems in future wireless personal communications networks.     

Optical feedback on self-pulsating semiconductor lasers

Weak optical-feedback effects on the statistical properties of self-pulsations in narrow-stripe semiconductor lasers are analyzed using Lang-Kobayashi-type equations. The self-pulsation features are compared with the characteristics of excited relaxation oscillations. We determine the operating regime in which the randomizing effect of spontaneous-emission noise destroys pulse coherence. In this regime, only phase-insensitive effects of optical feedback are possible, and optimum jitter reduction is achieved with delay times of the order of an integer-odd multiple of the free-running pulsation period. In the high-pump operating regime, interpulse coherence is retained and the optical-feedback phase is shown to be instrumental for pulse-jitter control. Our results show that for cavity lengths up to 10 cm, variations on the order of half an optical wavelength induce jitter variations of one order of magnitude     

Optimizing the solar photo-Fenton process in the treatment of contaminated water. Determination of intrinsic kinetic constants for scale-up

The elimination of aromatic compounds present in surface water by photo-Fenton with sunlight as the source of radiation was studied. The concentrations of Fe³⁺ and H₂O₂ are key factors for this process. A solar simulator and a prototype parabolic collector were used as laboratory-scale reactors to find the parameters of those key factors to be used in the CPC (compound parabolic collector) pilot plant reactor. The initial mineralization rate constant (k_obs) was determined and evaluated at different Fe³⁺ and H₂O₂ concentrations to find the best values for maximum efficiency. In all the experiments the mineralization of an aqueous phenol solution was described by assuming a pseudo-first-order reaction. The intrinsic kinetic constants not dependent on the lighting conditions were also estimated for scale-up.     

SPETA: Social pervasive e-Tourism advisor

Tourism is one of the major sources of income for many countries. Therefore, providing efficient, real-time service for tourists is a crucial competitive asset which needs to be enhanced using major technological advances. The current research has the objective of integrating technological innovation into an information system, in order to build a better user experience for the tourist. The principal strength of the approach is the fusion of context-aware pervasive systems, GIS systems, social networks and semantics. This paper presents the SPETA system, which uses knowledge of the user’s current location, preferences, as well as a history of past locations, in order to provide the type of recommender services that tourists expect from a real tour guide.     

Revealing Nanomechanical Domains and Their Transient Behavior in Mixed-Halide Perovskite Films

Halide perovskites are a versatile class of semiconductors employed for high performance emerging optoelectronic devices, including flexoelectric systems, yet the influence of their ionic nature on their mechanical behavior is still to be understood. Here, a combination of atomic-force, optical, and compositional X-ray microscopy techniques is employed to shed light on the mechanical properties of halide perovskite films at the nanoscale. Mechanical domains within and between morphological grains, enclosed by mechanical boundaries of higher Young's Modulus (YM) than the bulk parent material, are revealed. These mechanical boundaries are associated with the presence of bromide-rich clusters as visualized by nano-X-ray fluorescence mapping. Stiffer regions are specifically selectively modified upon light soaking the sample, resulting in an overall homogenization of the mechanical properties toward the bulk YM. This behavior is attributed to light-induced ion migration processes that homogenize the local chemical distribution, which is accompanied by photobrightening of the photoluminescence within the same region. This work highlights critical links between mechanical, chemical, and optoelectronic characteristics in this family of perovskites, and demonstrates the potential of combinational imaging studies to understand and design halide perovskite films for emerging applications such as photoflexoelectricity.     

Structural Aspects of P2-Type Na0.67Mn0.6Ni0.2Li0.2O2 (MNL) Stabilization by Lithium Defects as a Cathode Material for Sodium-Ion Batteries

A known strategy for improving the properties of layered oxide electrodes in sodium-ion batteries is the partial substitution of transition metals by Li. Herein, the role of Li as a defect and its impact on sodium storage in P2-Na_0.67Mn_0.6Ni_0.2Li_0.2O₂ is discussed. In tandem with electrochemical studies, the electronic and atomic structure are studied using solid-state NMR, operando XRD, and density functional theory (DFT). For the as-synthesized material, Li is located in comparable amounts within the sodium and the transition metal oxide (TMO) layers. Desodiation leads to a redistribution of Li ions within the crystal lattice. During charging, Li ions from the Na layer first migrate to the TMO layer before reversing their course at low Na contents. There is little change in the lattice parameters during charging/discharging, indicating stabilization of the P2 structure. This leads to a solid-solution type storage mechanism (sloping voltage profile) and hence excellent cycle life with a capacity of 110 mAh g^-1 after 100 cycles. In contrast, the Li-free compositions Na_0.67Mn_0.6Ni_0.4O₂ and Na_0.67Mn_0.8Ni_0.2O₂ show phase transitions and a stair-case voltage profile. The capacity is found to originate from mainly Ni³⁺/Ni⁴⁺ and O^2-/O^2-δ redox processes by DFT, although a small contribution from Mn⁴⁺/Mn⁵⁺ to the capacity cannot be excluded.     

Electronic properties of silicon nanowires

The electronic structure and transmission coefficients of Si nanowires are calculated in a sp/sup 3/d/sup 5/s/sup */ model. The effect of wire thickness on the bandgap, conduction valley splitting, hole band splitting, effective masses, and transmission is demonstrated. Results from the sp/sup 3/d/sup 5/s/sup */ model are compared to those from a single-band effective mass model to assess the validity of the single-band effective mass model in narrow Si nanowires. The one-dimensional Brillouin zone of a Si nanowire is direct gap. The conduction band minimum can split into a quartet of energies although often two of the energies are degenerate. Conduction band valley splitting reduces the averaged mobility mass along the axis of the wire, but quantum confinement increases the transverse mass of the conduction band edge. Quantum confinement results in a large increase in the hole masses of the two highest valence bands. A single-band model performs reasonably well at calculating the effective band edges for wires as small as 1.54-nm square. A wire-substrate interface can be viewed as a heterojunction with band offsets resulting in reflection in the transmission.     

Application of the LP-DP approach to Andong and Imha parallel reservoirs,Korea

This paper presents an application of a previously developed linear programming-dynamic programming (LP-DP) methodology to the operation of Andong and Imha parallel reservoirs in South Korea. The model allows for multioptimization of power generation and municipal, industrial, and irrigation water use. It is shown that the annual average energy and the annual average water supply generated from the joint operation of the two parallel reservoirs by the LD-DP approach is 15.2 and 1.7% more than the contracted power production and water supply respectively.