Effect of Using CuO–Oil Nanofluid on Surface Roughness and Thermal Performance during Superfinishing Process

This research aims to investigate the effect of adding copper oxide nanoparticles to the oil Gr-6004 base fluid and its concentration changes from 0.1% to 0.4% on the surface roughness of gudgeon pin and the thermal conductivity of the nanofluids during the superfinishing process. The main novelty of this investigation is analyzing the impact of utilizing CuO/oil Gr-6004 nanofluid on thermal conductivity of oil and surface quality of gudgeon pin during superfinishing process. Based on the results, adding nanoparticles to the oil Gr-6004 has significantly reduced the surface roughness. In addition, by increasing the concentration of nanoparticles to 0.4%, the surface roughness has decreased by 57% compared to oil Gr-6004. Also, by adding nanoparticles, the thermal conductivity of the nanofluids has increased to 19.5%. In addition, dispersing CuO nanoparticles into base fluid reduces oil temperature by 17.44%.     

Breathable,Flexible, Transparent,Hydrophobic, and Biotic Sustainable Electrodes for Heating and Biopotential Signal Measurement Applications

Pressure to reduce the global amount of e-waste has increased in recent years. The optimal use of natural resources is a demanding area especially due to the overabundance of the use of resources and challenges with after-life disposal. Herein, an easy method is developed to fabricate an improved version of leaf skeleton-based biodegradable, transparent, flexible, and hydrophobic electrodes. A fractal-like rubber leaf skeleton is used as the substrate, physical vapor deposited Au interlayer to promote adhesion, and uniform deposition of overlayer silver nanowires. The fabricated surfaces present a high level of electrical stability, optical transparency, hydrophobicity, and robust mechanical properties. The prepared electrodes demonstrate a comparable level of optical transmittance to the virgin leaf skeleton. The mechanical sturdiness of the electrodes is verified by 1k bending cycles. To demonstrate the functionality of these hybrid biotic conductive network (HBCN) electrodes, their performance is evaluated as flexible transparent heating elements and as biosignal measurement electrodes. The heater can reach a temperature of 140 °C with only 2.5 V in ≈5 s and Ag nanowire loading of ≈160 μg cm⁻². Likewise, electrocardiogram (ECG) and electromyogram (EMG) signals are successfully obtained from the electrodes without using any electrode gel or other electrolytes.     

Advanced Functional Carbon Nitride by Implanting Semi-Isolated VO2 Active Sites for Photocatalytic H2 Production and Organic Pollutant Degradation

It is critical to facilitate surface interaction for liquid–solid two-phase photocatalytic reactions. This study demonstrates more advanced, efficient, and rich molecular-level active sites to extend the performance of carbon nitride (CN). To achieve this, semi-isolated vanadium dioxide is obtained by controlling the growth of non-crystalline VO₂ anchored into sixfold cavities of the CN lattice. As a proof-of-concept, the experimental and computational results solidly corroborate that this atomic-level design has potentially taken full advantage of two worlds. The photocatalyst comprises the highest dispersion of catalytic sites with the lowest aggregation, like single-atom catalysts. It also demonstrates accelerated charge transfer with the boosted electron–hole pairs, mimicking heterojunction photocatalysts. Density functional theory calculations show that single-site VO₂ anchored into the sixfold cavities significantly elevates the Fermi level, compared with the typical heterojunction. The unique features of semi-isolated sites result in a high visible-light photocatalytic H₂ production of 645 µmol h⁻¹ g⁻¹ with only 1 wt% Pt. They also represent an excellent photocatalytic degradation for rhodamine B as well as tetracycline, surpassing the activities obtained from many conventional heterojunctions. This study presents exciting opportunities for the design of new heterogeneous metal oxide for a variety of reactions.