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71.
During rough rice drying, gradients of moisture content and glass transition temperature cause thermal and mechanical stresses inside the kernel. These stresses eventuate to kernel fissuring during the milling process. In this study, convective drying of Hashemi (long grain) rough rice was applied to investigate the effect of continuous and stepwise changes in air temperature on stress cracking index and process duration. Toward this objective, the concepts of glass transition and analysis of moisture contents distributions within the rice kernel were determined through a numerical modeling of mass transfer. For stepwise temperature change, the drying experiments were conducted at temperatures above the glass transition temperature. Results indicated that the stress cracking index under stepwise temperature change conditions (i.e., within the rubbery state) was reduced compared to the continuous mode probably due to a drip in the moisture content gradients created inside the kernels during the drying process. Moreover, the drying duration significantly was shortened when the kernel was dried within the rubbery state due to faster diffusion moisture within the kernel. 相似文献
72.
Novel Brönsted acid functionalized magnetic polymeric nanocomposite, Ba0.5Sr0.5Fe12O19@PU-SO3H, has been successfully synthesized and characterized by field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), Fourier transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM) and thermogravimetric analysis (TGA) techniques. The catalytic activity of the nanocomposite was tested in the regioselective synthesis of 7-aryl-benzo[h]tetrazolo [5,1-b] quinazoline-5,6-diones in an eco-friendly and recyclable media, deep eutectic solvent (DES), based on choline chloride and urea. This novel method offers several advantages, such as high yields, short reaction time, environmentally friendly reaction media, easy isolation of the product, and also offers an easy method for the synthesis of nanocatalysts. The catalyst was readily recycled by the use of an external magnetic field and could be reused 6 times without significant loss of activity or mass. DES as one of the most promising environmentally benign and cost-effective alternatives to conventional ionic liquids and volatile organic solvents was recovered from the aqueous filtrate by evaporating the water under vacuum. The recycled DES was used up to 4 runs without any loss in activity. 相似文献
73.
Nersi Jafary Omid Niloofar Babanejad Hossein Amini Mohsen Amini Morteza Rafiee Tehrani Farid Dorkoosh 《Journal of Polymer Research》2014,21(8):1-16
Chitosan and its derivatives are widely used in drug delivery systems due to their bio-degradebility, bio-compatibility and absorption enhancing properties. Many peptide and protein derived therapeutics cannot be administered through oral rout because of the proteolytic condition of gastro-intestinal tract and their low bio-availability. Insulin is a peptide drug which is widely used in diabetics as repeated daily injection. Due to the fact that there are receptors for didpeptides and vitamine B12 in small intestine, in this research work novel derivatives of chitosan and trimethyl chitosan conjugated with glycyl-glycine, alanyl-alaninie and vitamine B12 were synthesized and characterized. The structure of conjugates as well as substitution of different functional groups was confirmed by different instrumental analytical methods such as Fourier transform infrared, magnetic resonance, and X-ray diffraction spectroscopy. Nano-particles of aforementioned loaded with insulin were prepared and their size, surface electrical charge and morphology characterized and their release profile were studied. The results are promising and reveal that these new chitosan and trimethyl chitosan derivatives are potential vehicles for protein and peptide drug molecules. 相似文献
74.
Removal of methylene blue from aqueous solution by electrophoretically deposited titania‐halloysite nanotubes coatings 下载免费PDF全文
Morteza Farrokhi‐Rad Mehrdad Mohammadalipour Taghi Shahrabi 《Journal of the American Ceramic Society》2018,101(11):4942-4955
Two‐component suspensions of titania and halloysite nanotubes (HNTs) were prepared in ethanol with 0.5 g/L (optimum concentration) of polyethyleneimine (PEI) and different wt% of HNTs. Kinetics of Electrophoretic deposition (EPD) decreased with increasing the HNTs content in suspensions due to their less mobility compared with titania particles. HNTs reinforced the microstructure of coatings and reduced or completely prevented from cracking during drying and heat‐treatment steps. Removal of methylene blue (MB) via adsorption by HNTs coatings was faster than its photocatalytic degradation by titania coating. Dispersion of HNTs (up to ≈30 wt%) in the matrix of titania resulted in the synergistic catalytic effect in MB removal. The synergistic effect was because of the shorter traveling distance of MB molecules adsorbed on HNTs toward the photocatalytic active site of titania particles in composite coatings. However, the synergistic effect was destroyed with increasing the HNTs content in coating. Difference between the amount of MB removed by titania and composite coatings increased at longer times (≥60 minutes). Mass transfer of MB adsorbed on HNTs toward the photocatalytic active sites of adjacent titania particles can compensate the decline in the mass transfer from solution at longer times. 相似文献
75.
Evaluation of antimicrobial and dyeing properties of walnut (Juglans regia L.) green husk extract for cosmetics 下载免费PDF全文
Walnut green husk is one of the main waste products from walnut and could be used as a source of natural dyeing compounds such as juglone. The present study was conducted to evaluate the effective use of walnut green husk extract as a natural hair dye. Dyeing properties, fastness and antimicrobial behaviours of dyed hair and also a skin irritation test for natural hair dye on rat skin were examined. When the extract was mixed with ascorbic acid as a developer, ferrous sulphate as a mordant, and Aloe vera extract used as a secondary mordant and also a cosmetic ingredient, the reaction resulted in a dark‐brown colour on hair samples. The dyed hair exhibited appropriate colour strength having excellent morphology for a hair surface coated with dye molecules. In addition, the dyed hair possessed good resistance to washing and daylight fastness, without any irritant properties as shown in a rat model, although high concentrations of iron‐based mordant may be problematic for long‐term usage. This paper also suggests the use of natural mordants such as lactic and oxalic acids to avoid any probable risks. Walnut green husk extract was an appropriate natural hair dyeing agent in practice and showed maximum antimicrobial activity compared with semi‐synthetic and commercial hair dyes. The results demonstrated that walnut green husk can be used as an economical, valuable, eco‐friendly and safe source of dyeing and antimicrobial agents for cosmetic products. 相似文献
76.
Sorahi Abedinifar Keikhosro Karimi Morteza Khanahmadi Mohammad J. Taherzadeh 《Biomass & bioenergy》2009,33(5):828-833
Rice straw was successfully converted to ethanol by separate enzymatic hydrolysis and fermentation by Mucor indicus, Rhizopus oryzae, and Saccharomyces cerevisiae. The hydrolysis temperature and pH of commercial cellulase and β-glucosidase enzymes were first investigated and their best performance obtained at 45 °C and pH 5.0. The pretreatment of the straw with dilute-acid hydrolysis resulted in 0.72 g g?1 sugar yield during 48 h enzymatic hydrolysis, which was higher than steam-pretreated (0.60 g g?1) and untreated straw (0.46 g g?1). Furthermore, increasing the concentration of the dilute-acid pretreated straw from 20 to 50 and 100 g L?1 resulted in 13% and 16% lower sugar yield, respectively. Anaerobic cultivation of the hydrolyzates with M. indicus resulted in 0.36–0.43 g g?1 ethanol, 0.11–0.17 g g?1 biomass, and 0.04–0.06 g g?1 glycerol, which is comparable with the corresponding yields by S. cerevisiae (0.37–0.45 g g?1 ethanol, 0.04–0.10 g g?1 biomass and 0.05–0.07 glycerol). These two fungi produced no other major metabolite from the straw and completed the cultivation in less than 25 h. However, R. oryzae produced lactic acid as the major by-product with yield of 0.05–0.09 g g?1. This fungus had ethanol, biomass and glycerol yields of 0.33–0.41, 0.06–0.12, and 0.03–0.04 g g?1, respectively. 相似文献
77.
Elham Poonaki Mohammad Esfandyar Hadi Hejazinia Seyed Esmaeil Sadat Ebrahimi Morteza Pirali Hamedani Jafar Farzaneh Mehdi Shafiee Ardestani 《IET nanobiotechnology / IET》2020,14(6):470
Gadolinium as a contrast agent in MRI technique combined with DTPA causes contrast induced nephropathy (CIN) and nephrogenic systemic fibrosis (NSF) which can reduce by usage of antioxidants such as N‐acetyl cysteine by increasing the membrane''s permeability leads to lower cytotoxicity. In this study, N ‐acetyl cysteine‐PLGA Nano‐conjugate was synthesized according to stoichiometric rules of molar ratios andafter assessment by FTIR, NMR spectroscopy and Atomic Force Microscopy (AFM) imaging was combined with Magnevist® (gadopentetate dimeglumine) and its effects on the renal cells were evaluated. MTT [3‐(4,5‐Dimethylthiazol‐2‐yl)‐2,5‐Diphenyltetrazolium Bromide] and cellular uptake assays have indicated relatively significant toxicity of magnevist (P < 0.05) on three cell lines including HEK293, MCF7 and L929 compared to other synthesized ligands that shown no toxicity. Moreover, systemic evaluation has shown no notable changes of blood urea nitrogen (BUN) and creatinine in kidney of mice. In consequence, antioxidant effect was increased as well as the renal toxicity of the contrast agent reduced at the cell level. As a result, PLGA‐NAC nano‐conjugate can be a promising choice for decreasing the magnevist toxicity for treatment and prevention of CIN and will be able to open a new horizon to research on reduction of toxicity of contrast agents by using nanoparticles.Inspec keywords: blood, toxicology, nanofabrication, cellular biophysics, biomedical materials, nanoparticles, chromatography, cancer, biodegradable materials, biomedical MRI, kidney, pH, nanomedicine, patient treatment, diseases, atomic force microscopy, Fourier transform infrared spectraOther keywords: cellular toxicity, gadopentate dimeglumine, contrast agent, magnetic resonance imaging technique, diethylenetriamine pentaacetate, contrast‐induced nephropathy, nephrogenic systemic fibrosis, stoichiometric rules, molar ratios, dimethyl sulphoxide solution, chromatography techniques, nuclear magnetic resonance spectroscopy, atomic force microscopy imaging, Magnevist®, gadopentetate dimeglumine, renal cells, MTT cytotoxicity, human embryonic kidney‐293, L929 cell lines, in vitro conditions, cellular uptake assays, Magnevist uptake, antioxidant effect, renal toxicity, cell level, PLGA nanocarrier, acetylcysteine nanoconjugate, Magnevist toxicity, N‐acetylcysteine–PLGA nano‐conjugate, N‐acetyl cysteine‐poly‐lactic‐co‐glycolic acid nanoconjugate 相似文献
78.
The multi-period multi-product (MPMP) production planning problems, generally, deal with matching production levels of individual products with fluctuated demands over planning horizon. The conventional MPMP optimisation models suffer from insufficient utilisation of available capacity of machines. This fallacy is due to inappropriate formulation of machine capacity and material handling constraints. In this study, a novel mathematical model is proposed to simultaneously optimise production quantities and provide information about managerial decisions such as subcontracting, carrying inventory/backordering, and also hiring/layoff personnel. The problem is then formulated as a mixed integer linear programming (MILP) model by applying appropriate linearisation of non-linear components. The objective is to minimise production costs comprising of production, storage, shortage, subcontracting costs and costs associated with hiring/dismissing labourers. Superiority of the proposed model over existing ones, has been initially evaluated by solving the case presented by Byrne and Bakir [Byrne, M.D. and Bakir, M.A., 1999. Production planning using a hybrid simulation-analytical approach. International Journal of Production Economics, 59 (1), 305–311], and then evaluated by comparing the results obtained from solving both the proposed and the conventional MPMP production planning models using a 100-randomly-generated-test-problem. 相似文献
79.
Farzaneh Khorasani Morteza Mohammadi Zanjireh Mahdi Bahaghighat Qin Xin 《计算机系统科学与工程》2022,40(3):1085-1098
With a sharp increase in the information volume, analyzing and retrieving this vast data volume is much more essential than ever. One of the main techniques that would be beneficial in this regard is called the Clustering method. Clustering aims to classify objects so that all objects within a cluster have similar features while other objects in different clusters are as distinct as possible. One of the most widely used clustering algorithms with the well and approved performance in different applications is the k-means algorithm. The main problem of the k-means algorithm is its performance which can be directly affected by the selection in the primary clusters. Lack of attention to this crucial issue has consequences such as creating empty clusters and decreasing the convergence time. Besides, the selection of appropriate initial seeds can reduce the cluster’s inconsistency. In this paper, we present a new method to determine the initial seeds of the k-mean algorithm to improve the accuracy and decrease the number of iterations of the algorithm. For this purpose, a new method is proposed considering the average distance between objects to determine the initial seeds. Our method attempts to provide a proper tradeoff between the accuracy and speed of the clustering algorithm. The experimental results showed that our proposed approach outperforms the Chithra with 1.7% and 2.1% in terms of clustering accuracy for Wine and Abalone detection data, respectively. Furthermore, achieved results indicate that comparing with the Reverse Nearest Neighbor (RNN) search approach, the proposed method has a higher convergence speed. 相似文献
80.
Bui Hang Thanh Hussain Omar Khadeer Saberi Morteza Hussain Farookh 《World Wide Web》2021,24(2):483-509
World Wide Web - Blockchain, with its ever-increasing maturity and popularity, is being used in many different applied computing domains. To document the advancements made, researchers have... 相似文献