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121.
A variety of iron-metallated functional porphyrins have been synthesized and their catalytic activity to oxidize polycyclic aromatic hydrocarbons, (PAHs) using hydrogen peroxide as oxidant was investigated. It was found that iron-metallated porphyrins bearing strong electronegative groups at β-pyrrolic positions show an exceptionally high catalytic efficiency. 相似文献
122.
Solution of linear systems in arterial fluid mechanics computations with boundary layer mesh refinement 总被引:1,自引:1,他引:0
Murat Manguoglu Kenji Takizawa Ahmed H. Sameh Tayfun E. Tezduyar 《Computational Mechanics》2010,46(1):83-89
Computation of incompressible flows in arterial fluid mechanics, especially because it involves fluid–structure interaction,
poses significant numerical challenges. Iterative solution of the fluid mechanics part of the equation systems involved is
one of those challenges, and we address that in this paper, with the added complication of having boundary layer mesh refinement
with thin layers of elements near the arterial wall. As test case, we use matrix data from stabilized finite element computation
of a bifurcating middle cerebral artery segment with aneurysm. It is well known that solving linear systems that arise in
incompressible flow computations consume most of the time required by such simulations. For solving these large sparse nonsymmetric
systems, we present effective preconditioning techniques appropriate for different stages of the computation over a cardiac
cycle. 相似文献
123.
Ozan Gürbüz Duygu Göçmen Fatih Dagˇdelen Murat Gürsoy Sami Aydin İsmet Şahin Levent Büyükuysal Mehmet Usta 《Food chemistry》2007,100(2):518-525
Concentrations of trans-resveratrol, catechin and epicatechin were analyzed in musts and wines produced from seven red and four white grape cultivars from various wine growing regions of Turkey. Phenolics were quantified using an HPLC method optimized for the separation of wine phenolics. Wine samples contained higher phenolics levels than the corresponding musts. With the exception of Semillion, white wines and musts contained lower concentrations of phenolics than red wines and musts. However, the white cultivar Semillion had the highest concentrations of catechin and epicatechin among all wine and must samples. Semillion wine catechin and epicatechin were 13.7 and 11.8 mg/L, respectively. The highest level of trans-resveratrol among the white cultivars was found in Narince wine (1.93 mg/L). Within the red wine and must cultivars, Bo?azkere, Öküzgozü, and Cabernet contained the highest concentrations of flavan-3-ols and trans-resveratrol. Catechin was the major phenolic in all wines and most musts. Epicatechin was the major phenolic in 6 of the 11 must samples, but none of the wine samples. trans-Resveratrol was generally found in lowest concentrations in both wines and musts. 相似文献
124.
Environmental concerns and limited resource of petroleum fuels have caused interests in the development of alternative fuels for internal combustion (IC) engines. For diesel engines, alcohols are receiving increasing attention because they are oxygenated and renewable fuels. Therefore, in this study, the effect of injection timing on the exhaust emissions of a single cylinder, naturally aspirated, four-stroke, direct injection diesel engine has been experimentally investigated by using methanol-blended diesel fuel from 0% to 15% with an increment of 5%. The tests were conducted for three different injection timings (15°, 20° and 25 °CA BTDC) at four different engine loads (5 Nm, 10 Nm, 15 Nm, 20 Nm) at 2200 rpm. The experimental test results showed that Bsfc, NOx and CO2 emissions increased as BTE, smoke opacity, CO and UHC emissions decreased with increasing amount of methanol in the fuel mixture. When compared the results to those of original injection timing, NOx and CO2 emissions decreased, smoke opacity, UHC and CO emissions increased for the retarded injection timing (15 °CA BTDC). On the other hand, with the advanced injection timing (25 °CA BTDC), decreasing smoke opacity, UHC and CO emissions diminished, and NOx and CO2 emissions boosted at all test conditions. In terms of Bsfc and BTE, retarded and advanced injection timings gave negative results for all fuel blends in all engine loads. 相似文献
125.
126.
Murat Manguoglu Ahmed H. Sameh Tayfun E. Tezduyar Sunil Sathe 《Computational Mechanics》2008,43(1):73-80
We present an effective preconditioning technique for solving the nonsymmetric linear systems encountered in computation of
incompressible flows in long domains. The application category we focus on is arterial fluid mechanics. These linear systems
are solved using a nested iterative scheme with an outer Richardson scheme and an inner iteration that is handled via a Krylov
subspace method. Test computations that demonstrate the robustness of our nested scheme are presented. 相似文献
127.
Optimal Distributed Location Management in Mobile Networks 总被引:4,自引:0,他引:4
Krishnamurthi Govind Azizoğlu Murat Somani Arun K. 《Mobile Networks and Applications》2001,6(2):117-124
An important issue in the design of future Personal Communication Services (PCS) networks is the efficient management of location information. In this paper, we consider a distributed database architecture for location management in which update and query loads of the individual databases are balanced. We obtain lower bounds to the worst-case delay in locating a mobile user, to the average delay, and to the call blocking probability. We then propose a dynamic location management algorithm that meets these lower bounds. The optimality of this algorithm with respect to these three performance measures, as well as simplicity, make it an appealing candidate for distributed location management in PCS networks. 相似文献
128.
Murat Oztas Peter Rojan 《流程工业》2008,(1):56-57
通过将滤布翻转过来的方法将过滤出来的固体物质排出,这一获取高价值过滤材料的基本方法30多年来一直被成功使用,没有改变。然而现在一切似乎都在悄悄地发生着变化,本文所介绍的德国Heinkel公司第三代翻袋过滤器式离心机就印证了这种变化。 相似文献
129.
Friction and wear behavior of styrene butadiene rubber‐based composites reinforced with microwave‐devulcanized ground tire rubber 下载免费PDF全文
In this work, the tribological properties of a new material obtained by revulcanization with styrene butadiene rubber (SBR) and devulcanized ground tire rubber (GTR) were investigated. GTR was devulcanized using the microwave method at a constant power while varying the microwave exposure time. Devulcanized rubber (DV‐R) and untreated GTR were revulcanized by mixing with SBR at different rates (10, 30, 50 phr). To determine friction and wear characteristics of the samples, pin (ball) on disc and abrasion tests were conducted. Scanning electron microscopy (SEM) was employed to observe the worn surfaces of the composites to correlate the experimental test results to the wear mechanisms. All of these tests and experiments were performed on original vulcanized rubber samples for comparison. The composites exhibited different friction and wear behavior due to morphology, dispersion behavior and devulcanization functionalization of ground tire rubber. In general, DV‐R/SBR composites exhibited improvement in both mechanical and tribological properties. However, the enhanced compatibility of DV‐R resulting from the specific chemical coupling of DV‐R with SBR was crucial for the mechanical, friction and wear properties. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42419. 相似文献
130.
Carolin Braun Eduard Spuling Niklas B. Heine Murat Cakici Martin Nieger Stefan Brse 《Advanced Synthesis \u0026amp; Catalysis》2016,358(10):1664-1670
Pyridyl‐substituted [2.2]paracyclophanes build a multifunctional structural motif that is useful in material chemistry, catalysis and for luminescent structures. Nonetheless, there is still a lack of general methods for the synthesis of these structures tolerating easily accessible bromides as well as different isomeric pyridyl groups. Hence the coupling of functionalized [2.2]paracyclophanes with various substituted and functionalized pyridyl derivatives was achieved using Stille, Suzuki and Kumada coupling conditions. Hereby the Stille coupling of a [2.2]paracyclophane is presented as a versatile reaction for the formation of heteromeric [2.2]paracyclophane‐containing biaryl structures.