Optimal temperature control of solar heating systems

Temperature control systems based on solar and wind energy differ in two important ways from existing fossil fuel systems. One is that solar systems, at least active solar systems, all have some kind of energy storage, the other is that the source of energy in a solar and wind energy system is variable and uncontrollable. Because of these added complications and the high capital investment required for solar and wind energy systems, considerably more sophisticated techniques are required for the design of those systems. In this study, a new technique is applied to the optimal control problem of solar heating systems.     

Temperature‐induced surfactant‐ mediated pre‐concentration of uranium assisted by complexation

Cloud‐point extraction (CPE) was used with lipophilic chelating agent to extract uranium(VI) from aqueous solutions. The methodology used is based on the formation of metal complexes soluble in a micellar phase of a non‐ionic surfactant, Triton X‐114. The metal ions complexes are then extracted into the surfactant‐rich phase at a temperature above the cloud‐point temperature. The influence of surfactant concentration on extraction efficiency was studied and the advantage of adding 8‐hydroxyquinoline (8HQ) as lipophilic chelating agent was evidenced. High extraction efficiency was observed, indicating the feasibility of extracting U(VI) using CPE. This study describes a four‐step process—(1) extraction, (2) thermo‐induced phase splitting, (3) back‐extraction and (4) second phase splitting—for the recovery of uranium from water. In our conditions, the extraction yield is quantitative and the concentration factor obtained is superior to 100. After stripping with a diluted nitric acid solution (pH < 1), the system can be recycled through a new four‐step cycle. Copyright © 2006 Society of Chemical Industry     

Continuous dense‐phase CO2 processing of a coconut water beverage

Effects of dense‐phase CO₂ (DPCD) on microbial, physical, chemical and sensorial quality of coconut water (CW) beverage were evaluated. Pressure during DPCD treatment was not significant in microbial reduction whereas temperature and % CO₂ levels were significant. DPCD‐treated (34.5 MPa, 25 °C, 13% CO₂, 6 min), heat‐pasteurised (74 °C, 15 s) and untreated CW beverages were evaluated during 9 weeks of refrigerated storage (4 °C). Total aerobic bacteria of DPCD and heat‐treated samples decreased whereas that of untreated samples increased to >10⁵ CFU mL^?1 after 9 weeks. DPCD increased titratable acidity but did not change pH (4.20) and °Brix (6.0). Likeability of DPCD‐treated CW was similar to untreated. Heat‐treated samples were less liked (α = 0.05) at the beginning of storage. Off flavour and taste‐difference‐from‐control scores of heated samples were higher than DPCD during the first two weeks. DPCD extended shelf life of acidified, sweetened and carbonated CW over 9 weeks at 4 °C.     

Hydration reaction and hardening of calcined clays and related minerals III. Influence of calcination process of kaolinite on mechanical strengths of hardened metakaolinite

Compressive strengths of calcium hydroxide-activated metakaolinite cements have been studied versus both calcination process of kaolinite (use of fixed-bed and stirredbed - or rotary kiln- Laboratory reactors) and calcination temperature. Whatever the curing time from 7 days to 90 days, a maximum of strength is observed for calcination in the 700–850°C temperature range, but metakaolinite obtained in rotary kiln (process which realizes the dehydration of kaolinite in a shorter time, but can lead to a phenomenon of particle aggregation on the furnace wall) is less disordered and strengths of cements derived there from are some weaker than in the case of cements made with metakaolinite from fixed-bed calcination.     

The general theory of thin elastic shells

Variationsl methods can consistently be used to derive the equations of shell theory, by introducing a finite number of internal constraints. A systematic derivation of particular nonlinear and linear theories becomes then possible. Variational methods serve also to prove the existence and in some cases the uniqueness of the solution. They provide also with error estimates.