The effect of yttrium and thorium on the oxidation behavior of Ni-Cr-Al alloys

The effect of quaternary additions of 0.5% Y and 0.5 and 1.0% Th to a base alloy of Ni-10Cr-5Al on the oxidation behavior and mechanism was studied during oxidation in air over the range of 1000–1200°C. The presence of yttrium decreased the oxidation kinetics slightly, whereas the addition of thorium caused a slight increase. Oxide scale adherence was markedly improved by the addition of the quaternary elements. Although a number of oxides formed on yttrium-containing alloys, quantitative x-ray diffraction clearly showed that the rate-controlling step was the diffusion of oxygen through short-circuit paths in a thin layer of alumina that formed parabolically with time. Mixed oxides containing both aluminum and yttrium formed by the reaction of Y₂O₃ to form YAlOP₃ initially, and Y₃Al₅O₁₂ (YAG) after longer times. Although the scale adherence of the yttrium-containing alloy was considerably better than the base alloys, spalling did occur that was attributed to the formation of the voluminous YAG particles that grew in a mushroom-like manner, lifting the protective scale off the substrate locally. The YAG particles formed primarily at grain boundaries in the substrate in which the yttrium originally existed as YNi₉. This intermetallic compound reacted to form Y₂O₃, liberating metallic nickel that subsequently reacted to form NiO or NiAl₂O₄ spinel or both. The Y₂O₃ reacted with aluminum to ultimately form the YAG mushrooms. Thorium did not form any mixed oxides; the only oxide involving thorium was ThO₂, which existed as small particles at the oxide-metal interface. A highly beneficial effect of the thoria particles in reducing film spalling was observed. Scale spalling in the base alloy was attributed to void formation at the oxide-metal interface, the voids forming by condensation of excess vacancies from the Kirkendall effect associated with fast back-diffusion, of nickel into the substrate as aluminum was preferentially oxidized and diffused slowly outward. The mechanism of improved scale adherence in the quaternary alloys was the elimination of voids by annihilation of the Kirkendall vacancies at vacancy sinks introduced by the noncoherent interfaces between yttrium and thorium-containing intermetallics or oxides or both.This work is based on a portion of the dissertation of Arun Kumar in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Engineering, University of California, Los Angeles.Supported by NASA-Ames under grant No. NGR 05-007-352.     

The effects of silicon on the properties of tantalum

The microalloying of tantalum with silicon has been effectively used on a commercial scale. However, data on effects of microalloying on processibility, microstructure and mechanical properties are not readily available. To develop some data, tantalum powder with various levels of silicon (0–50 ppm) was processed under identical conditions. Sheet samples were then annealed at different temperatures and evaluated via microstructural, chemical and mechanical tests. The recrystallization temperature was found to increase with silicon content, most probably as a result of the presence of an intermetallic (Ta₃Si) phase. The mechanical properties of unrecrystallized tantalum are, as expected, significantly different from those of recrystallized tantalum.     

Generalized differentiability and integrability for fuzzy set-valued functions on time scales

This paper deals with the fuzzy set-valued functions of real variables on time scale whose values are normal, convex, upper semicontinuous and compactly supported fuzzy sets in \(\mathbb {R}^{n}\). We introduce and study the fundamental properties of new class of derivative called generalized delta derivative (\(\Delta _{g}\)-derivative) and generalized delta integral (\(\Delta _{g}\)-integral) for such fuzzy functions.     

Solubility and thermodynamic properties of Y2O3 in LiF-YF3 melts

A systematic investigation was undertaken to measure the solubility of Y₂O₃ in several LiF-YF₂ melts, with the YF₃ composition ranging from 20 to 50 mole pct, in the temperature range of 998 to 1273 K. Experimental results showed that the solubility of Y₂O₄ in the melts increased with increase in temperature and also with increased YF₃ content. The activity of Y₂O₃ was calculated using the free energy of fusion of Y₂O₃, . The was deduced from the values of enthalpy, heat of fusion, and melting point of Y₂O₃. From the known values of activity, the activity coefficients of Y₂O₃ as a function of temperature and melt composition were calculated. Considering the ionic nature of the melt, activity coefficients were also calculated using Temkin’s ideal mixing and electrically equivalent fraction methods. The thermodynamic data, such as integral molar enthalpy, entropy, and free energy of formation, were calculated as a function of composition and temperature. The calculated thermodynamic data showed that the melt exhibited a negative deviation from ideal conditions.     

A nano-plasmonic HMIM waveguide based concurrent dual-band BPF using circular ring resonator

This article analyzes the transmission line characteristics of plasmonic hybrid metal insulator metal (HMIM) waveguide, circular ring resonator (CRR) based dual-band band-pass filters with two transmission poles in both pass-bands in the optical regime using coupled line feed. The transmission line characteristics of an HMIM waveguide, such as characteristic impedance (ZPV), effective refractive index (neff) and propagation length (Lspp), have been obtained by using full wave simulation. Using basic HMIM slot waveguide, a CRR with periodic loading of double- and triple-ring CRR is numerically analyzed. Two input ports have been used for excitation, which are located at the separation of 180° positions along the CRR, and are coupled with the ring by parallel coupled lines, producing the dual pass-bands with the synchronous excitation of two transmission poles. The proposed double-ring dual-band band-pass filter (DR-DB-BPF) offers 35 dB extinction ratio (ER), 299.69 nm free spectral range (FSR) and narrow band full width half maximum (FWHM) of 78.057—112.43 nm. The triple-ring DB-BPF (TR-DB-BPF) has 22.5 dB ER, FSR of 292.18 nm and FWHM of 42.751—59.58 nm. The proposed filters are very useful in the development of dual-band filters for electronic photonic integrated circuits (EPICs), as the optical signals are filtered at two wavelengths simultaneously.     

Outage Performance of Uplink (UL) NOMA Network

Wireless Personal Communications - This paper proposes and analyses the power allocation coefficient normalization for successive interference cancellation in power-domain non-orthogonal multiple...     

Compact MIMO-Antenna with Enhanced Isolation for Ultra-Wide-Band and Ku-Band Applications

Journal of Communications Technology and Electronics - A Compact U-shaped multiple-inputs and multiple-output (MIMO)-antenna with dimensions of 23 × 47 mm2 has been proposed for...     

Effects of Hall current and two temperatures in transversely isotropic magnetothermoelastic with and without energy dissipation due to ramp-type heat

The present article is concerned with the investigation of disturbances in a homogeneous transversely isotropic thermoelastic rotating medium with two temperatures, in the presence of the combined effects of Hall currents and magnetic field. The formulation is applied to the thermoelasticity theories developed by Green-Naghdi theories of type-II and type-III. Laplace and Fourier transform techniques are applied to solve the problem. The analytical expressions of displacements, stress components, temperature change, and current density components are obtained in the transformed domain. A numerical inversion technique has been applied to obtain the results in the physical domain. Numerical simulated results are depicted graphically to show the effect of Hall current and two temperatures on resulting quantities. Some special cases are also deduced from the present investigation.     

A Comparative Investigation of Optical and Structural Properties of Cu-Doped CdO-Derived Nanostructures

In this report, we studied various structural and optical properties of pure and copper-doped cadmium oxide (CdO) thin films. Nanostructured Cu-doped CdO films were deposited using sol–gel spin-coating technique. The structural and morphological changes have been observed by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and atomic force microscopy (AFM) studies. The optical and electrical properties of the pure and Cu-doped CdO thin films were studied by UV–vis spectroscopy and four-point probe method, respectively. The XRD peaks show the formation of nanocrystalline CdO with cubic face-centered crystal structure. The band gaps of the as deposited films were found in the range of 2.32–2.73 eV, while after doping, it decreases due to structural deformation. The electrical resitivity was found to decrease approximately ～10 in Cu-doped CdO thin films.