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41.
Durai Mani Kumaravel Sakthivel Mukannan Arivanandhan Krishnakumar Balu Thiripuranthagan Sivakumar Ahn Young-Ho 《Journal of Porous Materials》2021,28(6):1907-1917
Journal of Porous Materials - Valeric acid can be produced by selective hydrogenation of biomass-derived levulinic acid. The present work aims to synthesize ethyl valerate (EV), a fuel, fuel... 相似文献
42.
The influence of inlet gas concentration cycling on the optimal temperature policy of catalytic transport reactors is studied theoretically. The model considered is based on plug flow of gas and catalyst particles with negligible interand intra-particle diffusional resistances and concentration dependent deactivation kinetics. To utilise the concentration of the reactant and the activity of the deactivating catalyst fully a proper temperature sequence along the reactor is needed. Thus, a general optimal temperature policy using the continuous minimum principle is derived for the reactor under periodic operation. The model equations are solved analytically for gas concentration, activity and temperature profiles. Resonance behaviour (maximum in conversion with pulse width) is obtained using the optimal temperature policy for certain sets of parameters. The effects of activation energy groups, reaction and deactivation constant groups and inlet temperature on the optimal temperature policy under periodic operation are evaluated. In all cases an improvement in conversion with the optimal temperature policy under periodic operation over that with an isothermal policy under periodic operation is obtained. A suboptimal policy, comprising constant temperature over different reactor sections, which is useful for implementation purposes is also discussed. 相似文献
43.
There has been much debate in the literature over the past 60 years regarding an appropriate oven-drying temperature for water content determinations in peat and other organic soils. For inorganic soils, the water content is usually based on the equilibrium dry mass corresponding to drying temperatures in the range 100–110°C. However, for peat and other organic soils, several researchers have recommended lower drying temperatures in the range 60–90°C in an attempt to prevent possible charring, oxidation, and/or vaporization of substances other than pore water. However, all of the relevant water is not fully evaporated at too low a temperature, and because specimen dry mass is a function of drying temperature, the resulting water content values are lower than those determined for the temperature range 100–110°C. Experimental data reported in this article show that oven drying of peat and other organic soils at 100–110°C using either gravity–convection or forced-draft ovens is acceptable for routine water content determinations. Because a standardized oven temperature is desirable when correlating water content with other material properties, it is recommended that oven drying of peat and other organic soils be performed over temperature ranges of either 105–110°C or 105 ± 5°C, in line with standardized ranges for inorganic soils. 相似文献
44.
John Abraham V. Ramesh Saravanakumar V. V. Kulkarni K. Sivakumar Anandha Prakash Singh P. Visha 《Journal of the American Oil Chemists' Society》2014,91(1):133-141
Whole dead poultry birds obtained from commercial layer farms were assessed for fat in the whole carcass and then dry rendered in three different rendering regimens T1, T2 and T3 (temperature = 120, 130 and 140 °C and shell pressure = 1, 2 and 3 kg/cm2 respectively) and the effect on the yield and quality of the rendered chicken oil were studied. The overall fat percentage of the whole dead poultry carcass was 14.55 ± 0.17 % and the fat content of ‘greaves’ was 14.49 ± 0.38 %. In the dry batch rendering trials, the mean overall fat recovery was 24.46 ± 1.19, 26.78 ± 3.14 and 22.42 ± 2.32 % and the overall fat yield was 3.52 ± 1.72, 3.84 ± 0.44 and 3.22 ± 0.33 % of the carcass weight in T1, T2 and T3 respectively. Solvent extraction of fat could recover 96.10 ± 0.14 % of fat from ‘greaves’ which was significantly higher than the mechanical centrifugation method. Among the quality characteristics of the rendered chicken oil (RCO), moisture content ranged from 0.61 % (T2) to 1.09 % (T1) and the mean specific gravity was 0.91 at 30 °C. The FFA values of RCO obtained from the T3 rendering regimen were significantly (p < 0.05) higher than the FFA values of T2 and T1. The mean acid value, iodine number, peroxide value, saponification value and unsaponifiable matter present in RCO showed no significant difference. The fatty acid profile and calorific values were studied. The RCO was converted to biodiesel by transesterification and the physico-chemical properties of the biodiesel were studied and compared with the Indian biodiesel specification. 相似文献
45.
Zhenyun Zhuang Tae-Young Chang Sivakumar R. Velayutham A. 《Mobile Computing, IEEE Transactions on》2009,8(9):1280-1295
A tremendous amount of research has been done toward improving transport-layer performance over wireless data networks. The improved transport layer protocols are typically application-unaware. In this paper, we argue that the behavior of applications can and does dominate the actual performance experienced. More importantly, we show that for practical applications, application behavior all but completely negates any improvement achievable through better transport layer protocols. In this context, we motivate an application-aware, but application transparent, solution suite called A3 (application-aware acceleration) that uses a set of design principles realized in an application-specific fashion to overcome the typical behavioral problems of applications. We demonstrate the performance of A3 through both emulations using realistic application traffic traces and implementations using the NetFilter utility. 相似文献
46.
Anil Sawhney Kenneth D. Walsh Howard H. Bashford Sivakumar Palaniappan 《Canadian Metallurgical Quarterly》2009,135(4):319-329
This paper examines the production implications of quality control inspections conducted on the buffer between processes in a construction project by modeling the linkage between these processes. Inspection of partially completed work at the end of one activity but before the beginning of work by the next activity is fairly common. Work that is deemed to be of sufficient quality is then made available for the next activity. Work that is deemed insufficient requires rework, typically by the trade appropriate to the activity that fed into the buffer, to bring the work into compliance. This has implications for workload management for that trade, of course, as well as for the reliability of work flow to the successor or downstream processes. While such situations are common in all construction sectors, an example from the residential construction sector was examined via a simulation model augmented by field data collected from residential construction projects. The impacts of the work flow into the predecessor process, the inspection pass rate, and resource availability were examined. The inspection pass rate was found to dramatically affect the reliability of work flow, unless resources are unlimited. Furthermore, the inspection pass rate was found to be functionally related to the production parameters of the process. 相似文献
47.
A Web-based remote interactive laboratory (RIL) developed to deliver Internetworking laboratory experience to geographically remote graduate students is presented in this paper. The onsite Internetworking program employs hands-on laboratories in a group setting that correlates with the constructivist and collaborative pedagogical approach. This paper discusses the pedagogical and technical considerations that influence the design and implementation of the remote laboratory environment given the constraints of the special hardware and learning outcomes of the program. For wide-ranging usability, the remote Internetworking (INWK) laboratory uses de facto networking standards and commercial and broad-band Internet connectivity to ensure real-time secure interaction with equipment. A four-tier role architecture consisting of faculty, local facilitators, remote facilitators, and students has been determined appropriate to maintain academic integrity and ensure good quality of interaction with the remote laboratory. A survey employing a five-point scale has been devised to measure the usability of the remote access INWK laboratory. 相似文献
48.
Manjubala I Sivakumar M Sampath Kumar TS Panduranga Rao K 《Journal of materials science. Materials in medicine》2000,11(11):705-709
The partial conversion of coralline hydroxyapatite (HA) into tricalcium phosphate (TCP) catalyzed by the thermal decomposition of silver oxide was investigated. The thermal analysis of HA powder mixed with 5 mol % Ag2O indicated the decomposition of silver oxide to be around 550°C in the presence of HA. Subsequently a functional gradient structure was formed by spreading silver oxide on one surface of the HA compact of diameter 10 mm and then firing at 700°C in air. The X-ray powder diffraction analysis confirmed the formation of -TCP induced by the Ag2O decomposition. The content of -TCP of the sintered pellet was found to decrease with the increasing depth from the surface of the pellet. In vitro solubility study in phosphate buffer of pH 7.2 showed the stability of the biphasic material as in between HA and TCP. © 2000 Kluwer Academic Publishers 相似文献
49.
J. A. Black V. Sivakumar M. R. Madhav G. A. Hamill 《Canadian Metallurgical Quarterly》2007,133(9):1154-1161
This paper investigates the performance of stone columns in a weak deposit such as peat. It evaluates the effects of reinforcing stone columns by jacketing with a tubular wire mesh and bridging reinforcement with a metal rod and a concrete plug. A series of plate loading tests was conducted on isolated stone columns installed in a soil bed consisting of a peat layer sandwiched between two layers of sand. The load–displacement characteristics of footings supported by stone columns were investigated by applying load to a circular plate supported on: (a) untreated soil; (b) soil treated with stone columns; and (c) soil treated with stone columns reinforced with the above reinforcing techniques. The work has shown that the settlement characteristics of the soil can be improved by installing stone columns and that a significant enhancement in the load–settlement response is achieved when the columns are reinforced by the various methods. 相似文献
50.
Medium access control in ad hoc networks with MIMO links: optimization considerations and algorithms 总被引:1,自引:0,他引:1
Sundaresan K. Sivakumar R. Ingram M.A. Tae-Young Chang 《Mobile Computing, IEEE Transactions on》2004,3(4):350-365
we present a medium access control (MAC) protocol for ad hoc networks with multiple input multiple output (MIMO) links. MIMO links provide extremely high spectral efficiencies in multipath channels by simultaneously transmitting multiple independent data streams in the same channel. MAC protocols have been proposed in related work for ad hoc networks with other classes of smart antennas such as switched beam antennas. However, as we substantiate in the paper, the unique characteristics of MIMO links coupled with several key optimization considerations, necessitate an entirely new MAC protocol. We identify several advantages of MIMO links, and discuss key optimization considerations that can help in realizing an effective MAC protocol for such an environment. We present a centralized algorithm called stream-controlled medium access (SCMA) that has the key optimization considerations incorporated in its design. Finally, we present a distributed SCMA protocol that approximates the centralized algorithm and compare its performance against that of baseline protocols that are CSMA/CA variants. 相似文献