Copolymerizations of ethylene with 1-decene were carried out with a series of
stereospecific metallocene compounds, rac–(EBI)Zr(NMe2)2 [ 1, EBI = ethylene–1,2–bis( 1–indenyl)], rac–(EBI)Hf(NMe2 (2), rac–Me2Si( 1–C5H2–2–Me–4–tBu)2Zr(NMe2)2
(3), ethylidene(cyclopentadienyl)(9-fluorenyl)ZrMe2 [4, Et(Flu)(Cp)ZrMe2] and isopropylidene(cyclopentadienyl)(9–fluorenyl)ZrMe2 [5, iPr(Flu)(Cp)ZrMe2], combined
with Al(i–Bu)3/[CPh3] [B(C6F5)4] cocatalyst. All catalyst systems showed very high
copolymerization rates and the 1–decene reactivity decreased in the order of 2 > 5 > 14 > 3. The reactivity product of ethylene and 1–decene (rE x rD) was below 1 except
3 catalyst, corresponding to random copolymer structures with an alternating
character. The melting point (Tm), crystallinity (XC), intrinsic viscosity ([] and
density of the 1–decene/ethylene copolymers decreased markedly with an increase in
the 1–decene content, regardless of the type of catalytic system. 相似文献
A power management unit (PMU) chip supplying dual panel supply voltage, which has a low electro-magnetic interference (EMI)
characteristic and is favorable for miniaturization, is designed. A two-phase charge pump circuit using external pumping capacitor
increases its pumping current and works out the charge-loss problem by using bulk-potential biasing circuit. A low-power start-up
circuit is also proposed to reduce the power consumption of the band-gap reference voltage generator. And the ring oscillator
used in the ELVSS power circuit is designed with logic devices by supplying the logic power supply to reduce the layout area.
The PMU chip is designed with MagnaChip’s 0.25 μm high-voltage process. The driving currents of ELVDD and ELVSS are more than
50 mA when a SPICE simulation is done. 相似文献
The peel and tack properties of mixtures of polystyrene-block-polybutadiene-block-polystyrene (SBS) and a tackifier were investigated after these were crosslinked by ultraviolet (UV) irradiation at various amounts of benzophenone (BP) as a photoinitiator and trimethylolpropane mercaptopropionate (TRIS) as a crosslinking agent.The degree of crosslinking of polybutadiene (PB) block in the SBS mixture was qualitatively estimated from the amount of gel fraction as well as the change in the glass transition temperature of the PB block. The crosslinking of the PB block was done within 3 min after UV irradiation and the peel strength of crosslinked specimens was as low as 45[percnt] of specimens without crosslinking. Nano-tack and bulk tack properties as well as the surface tension of mixtures were measured depending upon amounts of BP and TRIS. 相似文献
Parents of six children are facing a trial on charges of aggravated manslaughter in the care a 5 1/2 month old infant who
died suddenly and neglect of their four older children for causing them to be malnourished by feeding them all an exclusively
raw foods vegan diet. Both parents declined plea bargains and plan to defend themselves in court. 相似文献
International Journal of Control, Automation and Systems - In this paper, we consider the fuzzy moving sliding surface anti-sway control problem for container cranes. We first introduce the dynamic... 相似文献
The satellite-based regression model provides the data model that identifies water quality for inland and coastal waters. However, the satellite regression usually depends on the selection of observation, satellite data, and model type. A resampling simulation technique, such as sequential simulation using geographically weighted regression (GWR simulation), can be applied in generating multiple realizations for water quality estimation to reduce the sampling effect and consider spatial heterogeneity. Traditional models often result in considerable underestimation in extreme observations. The GWR simulation provides the best goodness of fit and spatial varying relationship between observed water quality and remote sensing considering parameter outlier and noise removal for parameter stability. This simulation model can increase the sampling diversity from various observations and reduce the neighboring effects of observations using outlier and noise removal. The model that handles spatial uncertainty and heterogeneity is a novel tool for inferring the characteristics of water quality from a series of sample subsets.
Light-sensitive drug delivery systems are considered ideal for applications in the biomedical fields for their ability to release the payload in an on-demand spatiotemporal controlled manner through the manipulation of the light source. Among the broad radiation spectrum, near infrared (NIR) light is considered advantageous compared to UV and visible light, due to its inherently lower photodamage to normal tissues and deeper penetration to lesion areas. In this study, we report a successful synthesis of a polymer capable of undergoing partial degradation upon irradiation with NIR light by conjugating 10-N-carbamoyl linkage methylene blue (MB) moiety, a NIR photocleavable ligand, with polyethylene glycol (PEG). Through effective coupling of MB, a hydrophobic moiety, to the hydrophilic PEG molecule, an amphiphilic polymer was synthesized, as demonstrated by a lowered surface tension (55 mN/m at 0.1% wt/vol). Subsequently, photo-induced reversal of surface activity associated with self-assembled structure disruption, was displayed by surface tension measurements, size distribution analysis, and burst release profile of paclitaxel (PTX) from polymeric micelles upon the exposure to NIR irradiation. 相似文献