Variational stability of infinite-dimensional optimal control problems

In this paper we examine the variational stability of infinite-dimensional optimal control problems governed by nonlinear evolution equations. Our tools are the Kuratowski—Mosco convergence of sets and the corresponding τ-convergence of functions. We prove the τ-convergence of cost functional and the convergence of the values of the problems, and we examine the variational stability of the solution and reachable sets. These results are then applied to a sequence of nonlinear parabolic distributed-parameter optimal control problems     

An artificial neural network-based multiscale method for hybrid atomistic-continuum simulations

This paper presents an artificial neural network-based multiscale method for coupling continuum and molecular simulations. Molecular dynamics modelling is employed as a local “high resolution” refinement of computational data required by the continuum computational fluid dynamics solver. The coupling between atomistic and continuum simulations is obtained by an artificial neural network (ANN) methodology. The ANN aims to optimise the transfer of information through minimisation of (1) the computational cost by avoiding repetitive atomistic simulations of nearly identical states, and (2) the fluctuation strength of the atomistic outputs that are fed back to the continuum solver. Results are presented for prototype flows such as the isothermal Couette flow with slip boundary conditions and the slip Couette flow with heat transfer.     

Ubiquitous Agents for Ambient Ecologies

The cost of state-of-the-art devices and robots is critical for the uptake of Ambient Intelligence (AmI). One way to utilize low-cost hardware for both devices and robots is to run smart software remotely as agents deployed on computationally rich environments. In this context, the devices and the robots can be seen as the Avatars of agents, while the way devices and agents are related may be considered as an Ambient Ecology. We show how the application of a middleware platform called EVATAR realizes this vision by exemplifying the main issues with a multi-robot and a smart-home scenarios.     

The berth allocation problem with stochastic vessel handling times

In this paper, the berth allocation problem with stochastic vessel handling times is formulated as a bi-objective problem. To solve the resulting problem, an evolutionary algorithm-based heuristic and a simulation-based Pareto front pruning algorithm is proposed. Computational examples show that the proposed approach provides solutions superior to the ones where the expected value of the vessel handling times is used.     

Effects of chromium (VI) addition on the activated sludge process

The effect of hexavalent chromium, Cr(VI), addition on various operating parameters of activated sludge process was evaluated. To accomplish this, two parallel lab-scale continuous-flow activated sludge plants were operated. One was used as a control plant, while the other received Cr(VI) concentrations equal to 0.5, 1, 3 and 5 mgl(-1). Cr(VI) concentrations of 0.5 mgl(-1) caused significant inhibition of the nitrification process (up to 74% decrease in ammonia removal efficiency). On the contrary, the effect of Cr(VI) on organic substrate removal was minor for concentrations up to 5 mgl(-1), indicating that heterotrophic microorganisms are less sensitive to Cr(VI) than nitrifiers. Activated sludge floc size and structure characterization showed that Cr(VI) concentrations higher than 1 mgl(-1) reduced the filaments abundance, causing the appearance of pin-point flocs and free-dispersed bacteria. Additionally, the variability of protozoa and rotifers was reduced. As a result of disperse growth, effluent quality deteriorated, since significant amounts of suspended solids escaped with the effluent. Termination of Cr(VI) addition led to a partial recovery of the nitrification process (up to 57% recovery). Similar recovery signs were not observed for activated sludge floc size and structure. Finally, shock loading to the control plant with 5 mgl(-1) Cr(VI) for 2 days resulted in a significant inhibition of the nitrification process and a reduction in filamentous microorganisms abundance.     

Soil-washing design methodology for a lead-contaminated sandy-soil

Soils located near high traffic roadways, particularly where renovations have taken place, typically exhibit elevated levels of trace metals in the upper soil horizon. Regulators are currently seeking an efficient method of site characterization and treatment system design which will lend itself to timely and environmentally efficacious clean-up. The soil investigated in this study was a silty sand collected near a bridge abutment for a major interstate highway. The soil had a total lead content of 1392 mg/kg. In addition, the soil contained a considerable fraction of organic carbon (approximately 6.3%). A sequential chemical extraction indicated that a fraction of contaminants were in labile soil phases and thus amenable to chemical extraction (soil-washing). A soil washing design methodology is presented based on surface chemistry and equilibrium stage operation. In this work, a double layer surface complexation model was used to describe equilibrium sorption behavior and a preliminary design of an ex-situ counter-current equilibrium stage extraction process is presented. Model calibration was conducted using sorption data obtained from a 1:40 solid to liquid ratio (s/l), adsorption edge. Model validation was accomplished with batch titration data and a 1:20 s/l, adsorption edge. The model accurately predicted leachable lead concentrations over a wide pH range. The required number of ideal equilibrium stages was highly sensitive to pH.     

Secondary Sulphate Minerals in a Cyprus-Type Ore Deposit,Apliki, Cyprus: Mineralogy and Its Implications Regarding the Chemistry of Pit Lake Waters

The Apliki mine, a Cyprus-type massive sulphide deposit in Cyprus, was exploited for copper until the mid-1970s. Abandonment of the mine left a deep pit that now hosts a lake fed by surface runoff from the surrounding mineralized zone and hydrothermally altered basalt. Oxidation of the sulphide minerals and factors such as climate and terrain relief control the water–rock interactions that generate acid mine drainage (AMD), which ultimately affects and defines the quality of the lake waters. Pyrite and chalcopyrite constitute an almost inexhaustible sulphide source that leads to the formation of a variety of secondary iron and copper mineral phases. The secondary mineral assemblages in the ore zone are mainly iron, copper, and magnesium sulphates, whereas the lakeshore assemblage is dominated by magnesium-, calcium-, sodium-, and aluminum-bearing sulphate minerals. Near the lakeshore, the highly soluble iron sulphate salts dissolve in the lake water, increasing its iron content. Other less soluble salts are more stable and persist in the lakeshore environment. The precipitation and dissolution of efflorescent salts, and, to a lesser extent, the oxidative weathering of the remaining ore minerals, produce additional AMD. Due to the perpetual cycle of mineral dissolution and precipitation, the lake has a low pH (≈3) and contains high concentrations of some contaminants. The processes that contribute to the formation of the efflorescent mineral assemblages and their environmental impact on pit lake waters, and indeed the complete geochemical system, is a typical example of secondary mineral formation in Cyprus-type Cu-pyrite massive sulphide ore deposits.     

Evaluation of a multifunctional indicator for the electroanalytical determination of nitrite

The derivatisation of phloroglucinol by acidified nitrite has been investigated as a means through which the latter can be quantified within freshwater and saline samples. The resulting nitroso derivative is shown to provide a number of options through which an electroanalytical signal can be obtained. Three distinct species can be electrochemically addressed and their respective sensitivities and practical implementations have been evaluated. The technology has been successfully transferred from bulk electrode formats to a disposable screen-printed electrode platform that is more amenable to field analysis. The analytical viability of the resulting assay system has been critically assessed and validated through the determination of endogenous nitrite within lake water and through recovery experiments in seawater.     

Study of the solubility,antioxidant activity and structure of inclusion complex of vanillin with β-cyclodextrin

In the present study, complexes of vanillin with β-cyclodextrin (β-CD) were prepared by the freeze-drying method. The formation of the inclusion complex was confirmed by differential scanning calorimetry (DSC). DSC thermograms indicated that the endothermic peak of vanillin and the physical mixture of vanillin with β-CD, due to the melting of vanillin crystals, were absent in DSC thermograms obtained for the freeze-dried inclusion complex. Moreover, the DSC studies under oxidation conditions indicate that the complex of vanillin with β-CD is protected towards oxidation since it remains intact at temperatures where the free vanillin is oxidising. The structure of the complex in aqueous solutions was established by nuclear magnetic resonance (NMR) studies and specifically by two-dimensional rotational frame NOE spectra. NMR studies showed inclusion of the entire vanillin molecule in the β-CD in a tilted manner and with the aldehyde group in the primary side. The stoichiometry of the complex was 1:1. A phase solubility study was performed by mixing an excess amount of vanillin with aqueous solutions containing increasing amounts of β-CD. The results indicated that the complex of a vanillin/β-CD inclusion is more soluble in water than vanillin alone.     

Audio source separation: solutions and problems

The problem of separating out a number of audio sources observed from an array of microphones in a real room environment has received a great deal of attention in the past decade. While there are now a number of workable methods that can even deal with relatively high reverberation (IEEE Trans Audio Speech Process, 2003; 11 :489–497), a number of interesting problems still remain. In this paper, the authors review the methods based around independent component analysis, discussing the various choices available in algorithm design. We then explore the issue of sensitivity to speaker movement which appears to impose fundamental limitations on BSS performance. Copyright © 2004 John Wiley & Sons, Ltd.