Ionic conductivity ageing behaviour of 10 mol.% Sc<Subscript>2</Subscript>O<Subscript>3</Subscript>–1 mol.% CeO<Subscript>2</Subscript>–ZrO<Subscript>2</Subscript> ceramics

The long-term ionic conductivity behaviour of samples of zirconia co-doped with 10 mol.% of Sc₂O₃ and 1 mol.% CeO₂ is evaluated in oxidizing and reducing atmospheres at 600 °C. After 3,000 h, the sample kept in reducing atmospheres exhibits 20% loss in the ionic conductivity, while the sample kept in air shows 6% degradation. No phase transitions were observed in the samples after both the ageing studies. The main contribution towards the loss in the ionic conductivity of the sample kept in air comes from grain boundaries; however, for the sample aged in reducing conditions, both grain and grain boundary contribute similarly towards the increase in the total resistivity. This is tentatively explained by the reduction of Ce⁴⁺ cations, dissolved in the fluorite lattice of ZrO₂.     

Reversible hydrogenation and bandgap opening of graphene and graphite surfaces probed by scanning tunneling spectroscopy

The effects of hydrogenation on the topography and electronic properties of graphene and graphite surfaces are studied by scanning tunneling microscopy and spectroscopy. The surfaces are chemically modified using an Ar/H(2) plasma. By analyzing thousands of scanning tunneling spectroscopy measurements it is determined that the hydrogen chemisorption on the surface of graphite/graphene opens on average an energy bandgap of 0.4 eV around the Fermi level. Although the plasma treatment modifies the surface topography in an irreversible way, the change in the electronic properties can be reversed by moderate thermal annealing and the samples can be hydrogenated again to yield a similar, but slightly reduced, semiconducting behavior after the second hydrogenation.     

Selective mercury determination after membrane complexation and total reflection X-ray fluorescence analysis

A new method for low mercury concentration analysis in drinking waters is presented. Membranes containing a few micrograms of various complexing reagents were produced on the surface of quartz glasses (reflectors). The reflectors were immersed in water solutions containing various concentrations of inorganic mercury salts at low concentrations (1-40 ng/mL). The membranes were left to equilibrate in 5-500 mL of solution for many hours; when the equilibration stage was finished they were cleaned with ultrapure water and left to dry. Analyses were performed by total reflection X-ray fluorescence (TXRF). The effects of various experimental parameters (complexing agent, equilibrium time, sample volume, etc.) as well as the selectivity of the membranes were studied. The complexing reagent dithizone with a PVC-based membrane gave the best results. The limit of quantitation was 0.8 ng/mL.     

Color-Selective Printed Organic Photodiodes for Filterless Multichannel Visible Light Communication

Future lightweight, flexible, and wearable electronics will employ visible-light-communication schemes to interact within indoor environments. Organic photodiodes are particularly well suited for such technologies as they enable chemically tailored optoelectronic performance and fabrication by printing techniques on thin and flexible substrates. However, previous methods have failed to address versatile functionality regarding wavelength selectivity without increasing fabrication complexity. This work introduces a general solution for printing wavelength-selective bulk-heterojunction photodetectors through engineering of the ink formulation. Nonfullerene acceptors are incorporated in a transparent polymer donor matrix to narrow and tune the response in the visible range without optical filters or light-management techniques. This approach effectively decouples the optical response from the viscoelastic ink properties, simplifying process development. A thorough morphological and spectroscopic investigation finds excellent charge-carrier dynamics enabling state-of-the-art responsivities >10² mA W⁻¹ and cutoff frequencies >1.5 MHz. Finally, the color selectivity and high performance are demonstrated in a filterless visible-light-communication system capable of demultiplexing intermixed optical signals.     

Scheduling parallel iterative methods on multiprocessor systems

The paper describes the implementation of the Successive Overrelaxation (SOR) method on an asynchronous multiprocessor computer for solving large, linear systems. The parallel algorithm is derived by dividing the serial SOR method into noninterfering tasks which are then combined with an optimal schedule of a feasible number of processors. The important features of the algorithm are: (i) achieves a speedup S_p O(N/3) and an efficiency E_p 2/3 using P = [N/2] processors, where N is the number of the equations, (ii) contains a high level of inherent parallelism, whereas on the other hand, the convergence theory of the parallel SOR method is the same as its sequential counterpart and (iii) may be modified to use block methods in order to minimise the overhead due to communication and synchronisation of the processors.     

Identification of Move Method Refactoring Opportunities

Placement of attributes/methods within classes in an object-oriented system is usually guided by conceptual criteria and aided by appropriate metrics. Moving state and behavior between classes can help reduce coupling and increase cohesion, but it is nontrivial to identify where such refactorings should be applied. In this paper, we propose a methodology for the identification of Move Method refactoring opportunities that constitute a way for solving many common Feature Envy bad smells. An algorithm that employs the notion of distance between system entities (attributes/methods) and classes extracts a list of behavior-preserving refactorings based on the examination of a set of preconditions. In practice, a software system may exhibit such problems in many different places. Therefore, our approach measures the effect of all refactoring suggestions based on a novel Entity Placement metric that quantifies how well entities have been placed in system classes. The proposed methodology can be regarded as a semi-automatic approach since the designer will eventually decide whether a suggested refactoring should be applied or not based on conceptual or other design quality criteria. The evaluation of the proposed approach has been performed considering qualitative, metric, conceptual, and efficiency aspects of the suggested refactorings in a number of open-source projects.     

Effective education for energy efficiency

A lot of today's world vices can be eliminated if certain targeted modules and adapted curricula are introduced in the schooling system. One of these vices is energy squandering with all its negative consequences for the planet (e.g. depletion of finite energy sources and the subsequent climate change). This paper describes the results of an energy-thrift information and education project taking place in different levels of education in Crete—Greece, which records 321 students’ and their parents’ routine energy-related behavior and proves that this behavior changes to a more energy efficient one, after the dissemination of relevant information and the participation into the energy education projects. Namely, response percentages indicating the energy-efficient behavior increased after project participation while the ones indicating an energy-squandering behavior decreased. The Wilcoxon signed rank test was statistically significant in all energy behavior questions related to students and to most questions related to parents.     

French Fries oleuropein content during the successive deep frying in oils enriched with an olive leaf extract

Olive oil, sunflower oil and soybean oil were enriched with an olive (Olea Europaea) leaf extract rich in oleuropein at a supplementation level of 100 mg total phenolics per kg oil. Supplemented oils were used for deep frying of potatoes for eight successive frying sessions without replenishment under domestic frying conditions. Supplemented oils contained oleuropein while deep frying resulted in a gradual decrease in oils oleuropein content. After the eighth successive frying, oleuropein was still detected in oils, its retention being 3.2–12.4%. Deep frying of potatoes in supplemented oils succeeded in preparing French fries containing oleuropein even after eight successive fryings. Contrary to the oil type, the number of frying sessions affected potatoes oleuropein content. Oleuropein intake by consuming French fries deep‐fried in enriched oils was approximately ten times higher in potatoes prepared in the first frying session as compared to the respective intake after the eighth frying.