Structural analysis of charged polymeric networks

Summary A new model was developed to accurately describe the swelling behavior of charged polymeric networks. The model incorporates elastic, mixing and ionic contributions to the chemical potential. Changes in the equilibrium degree of swelling as a function of pH can be predicted.     

An architecture for managing virtual circuit and virtual path services in ATM networks

ATM networks rely on the Virtual Circuit (VC) and Virtual Path (VP) concepts to provide unicast connection-oriented services with Quality of Service (QoS) guarantees. This paper presents a model for managing the configuration and performance of the VC and VP services in these networks. The model consists of a connection management architecture that provides the services and is instrumented for network management purposes, and a network management architecture that uses the OSI management model to provide access to the appropriate service monitoring and control functions. The network management architecture proposes complete managed object definitions that achieve a variety of monitoring and control objectives: service configuration, service performance at the call and cell level, and service control. The latter includes the capability to establish VPs and control their allocated networking capacity and also control parameters of the signaling system that affect the performance of the VC service. The architecture was implemented in its entirety on the Xunet ATM testbed, and several experiments were conducted to illustrate the trade-off between the throughput of the VC service and the allocation of capacity to VPs. The experiments further demonstrated that the signaling system can create throughput bottlenecks in the absence of VPs in the network, and therefore, the network operator can increase performance by controlling the VP distribution.     

The study and performance of a modified conventional refrigerator to serve as a PV powered one

This paper describes the design and development stages to convert a conventional refrigerator to a solar powered one. The development of such a system was effected and the results of this work to provide a cost effective version are given.A conventional refrigerator was chosen and some changes were introduced to reduce the cooling load and consequently the power required. Tests were carried out to study the performance of the refrigerator components and especially the compressor's, as well as the refrigerator as a whole. The latter tests are the well-known pull down tests.The cost effective final product was searched via a PV sizing package developed for the purpose of this project incorporating the LCC analysis.     

Prediction of Metallic Materials Relaxation at Elevated Temperature

A simple stress relaxation function is presented for metallic materials at elevated temperature. The function is derived from a more general physical‐phenomenological model describing the mechanical behaviour of metallic materials under creep conditions. The physical‐phenomenological model is represented by a simple Theological diagram with the minimum possible number of rheological elements. The creep function has only three fitting parameters whose dependencies on stress are presented by simple functions. The resulting stress relaxation curves agree with the experiments, not only the ones carried out in the laboratory but also the ones taken from literature.     

Anodic stripping voltametric cell for determination of copper and lead in atmospheric dust

Studies of air pollution by metals contained in dust particules usually require mineralization of a dust-collecting filter. This treatment introduces impurities into the sample. To avoid such contamination, an anodic stripping cell was constructed requiring no preliminary treatment of the sample filter. The cell uses a three-electrode amperometric system in differential pulse anodic stripping mode (DPAS). Solubilization of the metals from dust by a complexing agent, instead of the strong acid normally encountered in other methods, allows selective determination of metals according to their chemical form. With this cell, minimal handling of the collection filter and a large area mercury-coated vitreous carbon electrode located close to the sample filter (2 mm) lead to limits of detection as low as 0.15 μg of lead and 10 ng of copper. Precision is 2% for lead determination and 4% for copper determination (RSD).     

A strange convergence property of the lobatto-chebyshev method for the numerical determination of stress intensity factors

The Lobatto-Chebyshev method for the numerical solution of the Cauchy type singular integral equation of crack problems in two-dimensional elasticity, plates and shells and the determination of the values of the stress intensity factors at the crack tips is shown to converge for non-differentiable Hölder-continuous or even discontinuous loading distributions as far as the values of the stress intensity factors are concerned. Moreover, in all cases of differentiable loading distributions it is shown to converge more rapidly than believed up to now. The problems of a simple straight crack and a periodic array of cracks loaded by three non-differentiable loading distributions are used for the application of the present results. The displayed numerical results for these problems verify and further corroborate the theoretical results. The extension of the present results to the Gauss-Chebyshev method is also quite possible.     

Serum and follicular fluid leptin levels are correlated with human embryo quality

This prospective study was undertaken to reassess the prognostic value of leptin during critical stages of in vitro fertilization-embryo transfer (IVF-ET) and address its role in the functional staging of assisted reproductive technologies at the level of embryo quality. Serum and follicular fluid samples of 100 selected women undergoing the long IVF-ET protocol were collected for leptin and embryo quality determination. The highest serum leptin concentration (52.11 +/- 4.27 ng/ml) was observed on ovum pick up day, while follicular fluid leptin was higher than all serum samples examined (62.59 +/- 5.73 ng/ml). Serum leptin above 59.48 +/- 7.6 ng/ml was associated with 'poor' embryo quality and above 56.87 +/- 5.52 ng/ml with pregnancy failure. Elevated leptin concentrations were associated with reduced ovarian stimulation and response, follicle maturation, embryo quality and pregnancy success. Our findings suggest that leptin modulates embryo quality and may serve as a sensitive marker of IVF outcome.     

The slow start power controlled MAC protocol for mobile ad hoc networks and its performance analysis

We propose and evaluate the performance of a new MAC-layer protocol for mobile ad hoc networks, called the Slow Start Power Controlled (abbreviated SSPC) protocol. SSPC improves on IEEE 802.11 by using power control for the RTS/CTS and DATA frame transmissions, so as to reduce energy consumption and increase network throughput and lifetime. In our scheme the transmission power used for the RTS frames is not constant, but follows a slow start principle. The CTS frames, which are sent at maximum transmission power, prevent the neighbouring nodes from transmitting their DATA frames at power levels higher than a computed threshold, while allowing them to transmit at power levels less than that threshold. Reduced energy consumption is achieved by adjusting the node transmission power to the minimum required value for reliable reception at the receiving node, while increase in network throughput is achieved by allowing more transmissions to take place simultaneously. The slow start principle used for calculating the appropriate DATA frames transmission power and the possibility of more simultaneous collision-free transmissions differentiate the SSPC protocol from the other MAC solutions proposed for IEEE 802.11. Simulation results indicate that the SSPC protocol achieves a significant reduction in power consumption, average packet delay and frequency of RTS frame collisions, and a significant increase in network throughput and received-to-sent packets ratio compared to IEEE 802.11 protocol.     

Sorption of reactive dyes from aqueous solutions by ordered hexagonal and disordered mesoporous carbons

In the present study two synthetic mesoporous carbons, a highly ordered CMK-3 sample with hexagonal structure and a disordered mesoporous carbon (denoted DMC) were investigated for the sorption of Remazol Red 3BS (C.I. 239) dye in comparison to three commercial activated carbons and a HMS mesoporous silica with a wormhole pore structure. The structural, porosity and surface characteristics of the materials were evaluated using XRD, TEM, N₂ porosimetry, FT-IR spectroscopy and zeta-potential measurements. Optimal dye sorption occurred at pH ～2. Equilibrium sorption data followed the Langmuir model and showed that the two synthetic mesoporous carbons exhibit higher sorption capacities (q_max ～ 500–580 mg/g at 25 °C) in comparison to the commercial activated carbons which possessed either microporous (Takeda 5A and Calgon carbon) or combined micro-/mesoporous (Norit SAE-2) structures and to the HMS mesoporous silica. Thermodynamic parameters as the change in free energy, enthalpy, and entropy of sorption were also estimated. Kinetic studies were carried out and showed a rapid sorption of dye in the first ca. 30 min while equilibrium was reached after ca. 3 h. The sorption kinetics of dye was best described by a second-order kinetic model. A surfactant enhanced carbon regeneration (SECR) technique was used to regenerate the dye-loaded carbon sorbents.     

Characterisation of certain major polyphenolic antioxidants in grape (<Emphasis Type="Italic">Vitis vinifera</Emphasis> cv. Roditis) stems by liquid chromatography-mass spectrometry

The stem extract, which was shown to contain high amounts of phenolics and significant antioxidant potency, was further analysed employing liquid chromatography-electrospray ionisation mass spectrometry, in an effort to obtain a deeper insight into its polyphenolic composition. The compounds identified were mainly flavanols (a trimer and a galloylated dimer), flavonols (rutin and quercetin 3-O-glucuronide), stilbenes (trans-resveratrol and a resveratrol dehydrodimer) and a dihydroflavonol glycoside (astilbin).