全文获取类型
收费全文 | 1533篇 |
免费 | 31篇 |
国内免费 | 4篇 |
专业分类
电工技术 | 86篇 |
综合类 | 4篇 |
化学工业 | 382篇 |
金属工艺 | 30篇 |
机械仪表 | 41篇 |
建筑科学 | 17篇 |
能源动力 | 42篇 |
轻工业 | 107篇 |
水利工程 | 3篇 |
无线电 | 95篇 |
一般工业技术 | 275篇 |
冶金工业 | 314篇 |
原子能技术 | 32篇 |
自动化技术 | 140篇 |
出版年
2023年 | 7篇 |
2022年 | 8篇 |
2021年 | 5篇 |
2020年 | 13篇 |
2019年 | 13篇 |
2018年 | 32篇 |
2017年 | 18篇 |
2016年 | 27篇 |
2015年 | 10篇 |
2014年 | 22篇 |
2013年 | 55篇 |
2012年 | 55篇 |
2011年 | 71篇 |
2010年 | 48篇 |
2009年 | 44篇 |
2008年 | 55篇 |
2007年 | 75篇 |
2006年 | 50篇 |
2005年 | 64篇 |
2004年 | 39篇 |
2003年 | 43篇 |
2002年 | 39篇 |
2001年 | 28篇 |
2000年 | 33篇 |
1999年 | 42篇 |
1998年 | 131篇 |
1997年 | 81篇 |
1996年 | 56篇 |
1995年 | 38篇 |
1994年 | 28篇 |
1993年 | 40篇 |
1992年 | 23篇 |
1991年 | 33篇 |
1990年 | 11篇 |
1989年 | 23篇 |
1988年 | 15篇 |
1987年 | 15篇 |
1986年 | 8篇 |
1985年 | 14篇 |
1984年 | 20篇 |
1983年 | 15篇 |
1982年 | 20篇 |
1981年 | 16篇 |
1980年 | 11篇 |
1979年 | 14篇 |
1978年 | 7篇 |
1977年 | 13篇 |
1976年 | 12篇 |
1972年 | 6篇 |
1971年 | 4篇 |
排序方式: 共有1568条查询结果,搜索用时 0 毫秒
51.
Yasutaka Nagai Kazuhiko Dohmae Kentaro Teramura Tsunehiro Tanaka Gemma Guilera Kazuo Kato Masaharu Nomura Hirofumi Shinjoh Shinichi Matsumoto 《Catalysis Today》2009,145(3-4):279
Two main pivotal subjects of research in automotive catalysts were studied by modern X-ray absorption analysis techniques. One is oxygen storage/release behaviour, and the other is sintering inhibition of Pt particles. First, three types of CeO2–ZrO2 (Ce:Zr = 1:1 molar ratio) compounds with different oxygen storage/release capacities and different structural properties were prepared, and the valence change of Ce as a function of temperature during oxygen release/storage processes was investigated. The reduction of surface Ce mainly occurred in the range 100–170 °C, and the reduction of bulk Ce progressed at high temperatures of 170 °C and above. The Ce reduction behaviour depended not only on the homogeneity of the Ce and Zr for bulk reduction at high temperatures but also on the particle size of the CeO2–ZrO2 samples for surface reduction at low temperatures. Secondly, sintering inhibition of Pt in Pt/Al2O3, Pt/MgO and Pt/ceria-based catalysts after 800 °C ageing in air was studied. We found that the Pt–O–M (M = Mg, Ce) bond acted as an anchor and inhibited the sintering of Pt particles on MgO or ceria-based oxide. Especially, it was noteworthy that the Pt–O–Ce4+ bond on the ceria-based support breaks easily through the reduction of Ce (Ce4+ → Ce3+) during the usual stoichiometric and reducing conditions. 相似文献
52.
Masao Shimizu Naoto Kudo Yoshinobu Nakajima Noboru Matsuo Yoshihisa Katsuragi Ichiro Tokimitsu Francisca Barceló 《Journal of the American Oil Chemists' Society》2008,85(7):629-633
Olive oils have a higher relative diacylglycerol (DAG) content than other plant oils. The lipase in olive fruits is involved
in DAG production and is directly related to the acidity of the olive oil. However, the lipase activity and positional selectivity
have not been clarified. To investigate the properties of olive fruit lipase, olive fruits of the Mission variety harvested
during mid-December of 2005 on Shodoshima Island (Japan) were stored at 20, 30 or 40 °C for 4 weeks. Changes in the acidity
and acylglycerol content of the oils extracted from the stored fruits were analyzed. The acidity and DAG content of the olive
oils increased due to triacylglycerol (TAG) hydrolysis during storage. sn-1,2-DAGs preferentially increased during the early stages of storage, indicating that the olive fruit lipase is enantioselective
for the sn-3 position, while non-enzymatic isomerization of sn-1,2-DAGs was observed throughout the entire duration of storage. Kinetic analysis revealed that the enantioselectivity of
olive fruit lipase for the sn-3 position was approximately four times greater than for the sn-1 position. The lipase was gradually inactivated at temperatures of 30 °C or higher, and the ratios of the rate constant
for inactivation to TAG hydrolysis at the sn-3 position was 0.2, 13, and 23 at 20, 30, and 40 °C, respectively. 相似文献
53.
Toshiya Sugimoto Toshihiro Koremoto Takeshi Inoue Ryoji Nomura Toshio Masuda 《Polymer Bulletin》1999,42(1):55-60
Summary
Poly(phenylacetylene)s bearing dialkylamino groups were prepared by the polymerization of p-(N,N-dialkylamino)phenylacetylenes with [Rh(nbd)Cl]2, and their electrochemical behavior was examined. Rh-catalyzed polymerization of p-(N,N-diethylamino)phenylacetylene (DEAPA) and p-(N,N-di-n-butylamino)phenylacetylene (DBAPA) in toluene in the presence of triethylamine gave good yields of the polymers (86 and 90%,
respectively). Poly(DEAPA) was soluble in chloroform and dichloromethane, and poly(DBAPA) dissolved in various solvents such
as toluene, THF, dichloromethane and chloroform. Poly(DEAPA) and poly(DBAPA) showed onset temperatures at 248 and 190°C, respectively,
and absorptions around 300–400 nm. Electrochemical doping of the polymer films resulted in the shift of the absorptions to
a region around 680 nm, which accompanied a color change of the polymer films from green ocher to deep blue.
Received: 26 October 1998/Revised version: 6 November 1998/Accepted: 12 November 1998 相似文献
54.
局部加压铝合金的凝固变化及其数值模拟 总被引:1,自引:0,他引:1
局部加压方法是压铸中用于消除铸件厚壁处缩孔缺陷的一种新工艺.该研究通过试验模型测量局部加压过程中金属型、铸件和加压杆的温度变化曲线,分析了传热与凝固现象.结果表明,局部加压使铸件的凝固时间大为缩短,加压杆前端的温度大幅上升,而金属型的温度则无明显变化.利用变网格技术,根据加压深度通过适时修改网格文件、初始条件和边界条件的方法,模拟了铝合金在局部加压过程中的凝固变化,并与试验结果进行了对比和讨论. 相似文献
55.
56.
Noboru Nishioka Miyuki Funakoshi Kohji Inamoto Masakuni Uno Akira Ueda 《应用聚合物科学杂志》2010,118(4):2482-2487
Homogeneous grafting of styrene onto cellulose was carried out in a dimethylacetamide/lithium chloride solvent system. The grafted products were added to cellulose/polystyrene (PS) blends as compatibilizers. The thermal decomposition behavior of the blends was investigated by thermogravimetry. The thermal stability of the blends decreased with an increase in grafted product content. The crystallinity of the blends decreased with grafted product content. The microphase‐separated structures of the blends became finer with grafted product content. The glass transition temperatures for cellulose and PS in the blends were lowered with grafted product content. Differences in thermal decomposition behavior of the blends were correlated with compatibility. Thermogravimetry was effective for compatibility estimation in cellulose/PS blends containing grafted products. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
57.
58.
Morphology development during the crystallization of poly(vinylidene fluoride) (PVDF)/poly(methyl methacrylate) (PMMA) blends was investigated at various crystallization temperatures (TC) by means of time-resolved light scattering measurements and atomic force microscopy (AFM). A coarse spherulite obtained at a high TC of 162 °C was found to be developed with a two-step crystallization process. The ordering in the spherulites (Pr) increased with time at the early stages and then decreased at the later stages. The rate of spherulite growth started to decrease when Pr started to decrease. In contrast, in the compact spherulite obtained at a low TC of 148 °C, Pr decreased monotonously with time while the growth rate was constant. AFM observation revealed that such characteristic crystallization behavior is attributed to the exclusion of PMMA from the crystal growth during the crystallization; i.e., the amount of excluded PMMA becomes larger as the distance from the spherulite center increases and the crystallization temperature rises. 相似文献
59.
Pseudomonas aeruginosa as a model microorganism for investigation of chemotactic behaviors in ecosystem 总被引:1,自引:0,他引:1
Kato J Kim HE Takiguchi N Kuroda A Ohtake H 《Journal of Bioscience and Bioengineering》2008,106(1):1-7
Motile bacteria sense changes in the concentration of chemicals in environments and respond in a behavioral manner. This behavioral response is called chemotaxis. Bacterial chemotaxis can be viewed as an important prelude to metabolism, prey-predator relationships, symbiosis, infections, and other ecological interactions in biological communities. Genome analysis reveals that a large number of environmental motile bacteria possess a number of genes involved in chemosensing and chemotatic signal transduction. Pseudomonas aeruginosa has a very complex chemosensory system with more than 20 chemotaxis (che) genes in five distinct clusters and 26 chemoreceptor (methyl-accepting chemotaxis protein [mcp]) genes. Among the 26 MCPs of P. aeruginosa, nine have been identified as MCPs for amino acids, inorganic phosphate, oxygen, ethylene, and volatile chlorinated aliphatic hydrocarbons, whereas 3 MCPs were demonstrated to be involved in biofilm formation and biosynthesis of type IV pilus. Six che genes are essential for chemotactic responses, while genes in Pil-Chp cluster and Wsp cluster are involved in type IV pilus synthesis and twitching motility and biofilm formation, respectively. P. aeruginosa, with its complex chemotaxis system, is a better model microorganism for investigating ecological aspects of chemotaxis in environmental bacteria than Escherichia coli and Salmonella enterica serovar Typhimurium, which possess a relatively simpler chemotaxis system. 相似文献
60.
Hiroaki Ishikawa Takehide Nomura Yasuyuki Saito Haruo Kawasaki Atsushi Okamoto Ryuta Hatakenaka 《亚洲传热研究》2011,40(3):269-285
As heat generation in satellites increases, ensuring that they are provided with sufficient radiator panel area is an important problem. Deployable radiators, with radiator panels that are deployed post‐launch in space to increase the satellite's effective radiator panel area of the satellite, are becoming an important thermal control technology. A reservoir embedded loop heat pipe (RELHP) is used in deployable radiators as a heat transport device. A deployable radiator of this type was mounted on the ETS‐VIII satellite, which was launched on December 18, 2006 and injected into a geostationary orbit. The satellite is still operating without any significant issues over two years later. This paper investigates the heat transport characteristics of an RELHP system used in a deployable radiator in a geostationary orbital environment. This system can be successfully started up in a micro gravity environment. We also found that the sub‐cooling region is shorter in a micro gravity environment than in a terrestrial gravity environment, because there is less heat leakage into the reservoir in a micro gravity environment. © 2011 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.20346 相似文献