Structural changes in marinated fillets of gilthead sea bream (Sparus aurata L.) during vacuum storage at refrigerated temperature

Fillets of Sparus aurata were marinated in a mixture of salt (5.5%) and citric acid (48.9 g/kg) for 1 h, then vacuum packed and refrigerated for 1, 5, 16, and 21 d. Structural and ultrastructural parameters were evaluated in 6 specimens per time period. At day 1, the preservative solution appeared among the muscle fibers, thus increasing the interfibrillar spaces; cytoplasmic organelles were swollen and the sarcolemma-endomysium appeared very altered and electron-dense. At 5 to 10 d, the marinade solution had penetrated into the muscle fibers. The subsarcolemmal and intermyofibrillar spaces were dilated and granular lines of electron-dense material appeared among the fibers. From 16 d, broad interfibrillar spaces were occupied by granular material derived from denatured sarcolemma-endomysium and denatured myofibrils. Sarcomeres were already altered from initial stages, mainly at the I-band level. The Z-line also appeared disrupted. Such alterations were more severe from 10 d on, such that most of the sarcomeres showed disintegration of myofilaments.     

Effect of the trapped mass and its composition on the heat transfer in the compression cycle of a reciprocating engine

The use of the polytropic coefficient calculation during the compression process in the thermodynamic cycle of a reciprocating internal combustion engine is an interesting tool to minimize errors in the synchronization of pressure and volume signals, and to determine heat flux transferred to the cylinder walls. The accuracy of this calculation depends on the instantaneous values for pressure, volume, trapped mass and its composition, as well as on their variations. In this work the effect of the errors in blow-by, trapped mass and its composition have been studied in detail, specially the effect of errors in the composition estimation, owing to the use of exhaust gas recirculation in typical diesel engines.     

Chemical and physicochemical properties of dried wet masa and dry masa flour

Commercial ‘masas’ and dry ‘masa’ flours (DMFs) were evaluated for chemical composition, water retention capacity (WRC), gelatinization, retrogradation and X‐ray diffraction. Both masas and DMF had similar chemical compositions. The masas had higher soluble carbohydrate contents and lower WRCs than DMF. In the same way, DMFs had lower gelatinization temperatures and enthalpies of gelatinization than masas. These results were confirmed by X‐ray diffraction analysis showing a lower degree of crystallinity in DMFs than in masas. The melting temperature in retrogradated samples of both masas and DMFs had a tendency to increase as storage time increased. This increment was more apparent with the enthalpy of melting. These results were probably associated with crystal perfection during starch retrogradation, ie recrystallization of gelatinized starch occurred as a time‐dependent process. Copyright © 2003 Society of Chemical Industry     

Functional Disambiguation Based on Syntactic Structures

This article presents a disambiguation method which diminishesthe functional combinations of the words of a sentence takinginto account the context in which they appear. This processis built in two phases: the first phase is based on the localsyntactic structures of the Spanish language and reaches anaverage yield of 87%. The second one is supported by syntactictree representation and pushes the results up to an approximatehigh end of 96%. This process constitutes the starting pointtowards an automated syntactic analysis.     

Transesterification of Jatropha curcas oil glycerides: Theoretical and experimental studies of biodiesel reaction

Vegetal oil, also known as triglycerides, is a mixture of fatty acid triesters of glycerol. In the triglycerides alkyl chains of Jatropha curcas oil, predominate the palmitic, oleic and linoleic fatty acids. The process usually used to convert these triglycerides to biodiesel is called transesterification. The overall process is a sequence of three equivalent, consecutive and reversible reactions, in which di- and monoglycerides are formed as intermediates. Semi-empirical AM1 molecular orbital calculations were used to investigate the reaction pathways of base-catalyzed transesterification of glycerides of palmitic, oleic and linoleic acid. The most probable pathway and the rate determining-step of the reactions were estimated from the molecular orbital calculations. Our results suggest the formation of only one tetrahedral intermediate, which in a subsequent step rearranges to form the products. The rate determining-step is the break of this tetrahedral intermediate.     

Effect of different compatibilizers on environmentally friendly composites from poly(lactic acid) and diatomaceous earth

Environmentally friendly composites from poly(lactic acid) (PLA) and diatomaceous earth (DE) were successfully manufactured by extrusion, followed by injection moulding. DE was used as a filler; several compatibilizer/coupling agents, namely (3‐glycidyloxypropyl)trimethoxysilane, epoxy styrene acrylic oligomer and maleinized linseed oil, were used to improve polymer–filler interactions. Mechanical characterization was carried out by standard tensile, impact and hardness tests while morphological characterization of the fractured surfaces was conducted by field emission scanning electron microscopy. The effect of DE was evaluated by differential scanning calorimetry and dynamic mechanical thermal behaviour. The results show that the addition of DE provides an improved tensile modulus and induces more brittle composites due to stress concentration phenomena. The addition of compatibilizers in PLA‐DE positively contributes to improve ductile properties, thus leading to high environmental efficiency materials with balanced mechanical properties. Specifically, the compatibility improvement between the PLA and DE was good with maleinized linseed oil and contributed to improving the impact strength, which is a key factor in PLA‐based composites due to the intrinsic brittleness of neat PLA. © 2019 Society of Chemical Industry     

Acid-Catalyzed Homogeneous Esterification Reaction for Biodiesel Production from Palm Fatty Acids

This work deals with esterification of palm fatty acids to produce biodiesel in a batch reactor, using homogeneous acid catalysts, evaluating the effect of the alcohol used, presence of water, type and concentration of catalysts. Methanesulfonic and sulfuric acid were the best catalysts. Reaction with methanol showed greater yields. It was showed very clearly that the presence of water in the reaction medium showed a negative effect in the reaction velocity. Kinetic parameters were estimated and molecular modeling was performed. Protonation of the carboxylic moiety of the fatty acid were defined as rate determinant step for the reaction.     

Hard‐to‐cook phenomenon in common beans — A review

Legumes are one of the world's most important sources of food supply, especially in developing countries, in terms of food energy as well as nutrients. Common beans are a good source of proteins, vitamins (thiamine, riboflavin, niacin, vitamin B₆) and certain minerals (Ca, Fe, Cu, Zn, P, K, and Mg). They are an excellent source of complex carbohydrates and polyunsaturated free fatty acids (linoleic, linolenic). However, common beans have several undesirable attributes, such as long cooking times, being enzyme inhibitors, phytates, flatus factors, and phenolic compounds, having a “beany” flavor, and being lectins and allergens, which should be removed or eliminated for effective utilization.

Grain quality of common beans is determined by factors such as acceptability by the consumer, soaking characteristics, cooking quality, and nutritive value. Acceptability characteristics include a wide variety of attributes, such as grain size, shape, color, appearance, stability under storage conditions, cooking properties, quality of the product obtained, and flavor.

Storage of common beans under adverse conditions of high temperature and high humidity renders them susceptible to a hardening phenomenon, also known as the hard‐to‐cook (HTC) defect. Beans with this defect are characterized by extended cooking times for cotyledon softening, are less acceptable to the consumer, and are of lower nutritive value. Mechanisms involved in the HTC defect have not been elucidated satisfactorily. Attempts to provide a definitive explanation of this phenomenon have not been successful. The most important hypotheses that have been proposed to explain the cause of bean hardening are (1) lipid oxidation and/or polymerization, (2) formation of insoluble pectates, (3) lignification of middle lamella, and (4) multiple mechanisms. Most researchers have reported that the defect develops in the cotyledons. Recently, some authors have suggested that the seed coat plays a significant role in the process of common bean hardening. A better knowledge of cotyledon and seed coat microstructure may lead to a better understanding of the causes of seed hardness.

In order to prevent the development of the HTC defect several procedures have been proposed: (1) appropriate storage, (2) controlled atmospheres, and (3) pretreatments. Probably, the most workable solution to the hardening phenomenon may be the development of materials less prone to HTC phenomenon.

Decreasing cooking time, increasing nutritive value, and improving sensory properties of seeds with HTC defect would have great nutritional and economical impact. Furthermore, an understanding of the mechanisms leading to reversibility of this phenomenon would provide insight into the development of the defect itself and would aid in the search for appropriate methods to prevent it.

Efforts to develop technological processes are needed in order to transform the HTC beans into edible and useful products. Several economic alternatives to utilize HTC common beans have been proposed: (1) dehulling, (2) extrusion, (3) solid state fermentation, (4) quick‐cooking beans, and (5) production of protein concentrates and isolates and starch fractions.     

Characteristics of Velocity and Excess Density Profiles of Saline Underflows and Turbidity Currents Flowing over a Mobile Bed

Turbidity currents in the ocean and lakes are driven by suspended sediment. The vertical profiles of velocity and excess density are shaped by the interaction between the current and the bed as well as between the current and the ambient water above. We present results of a set of 74 experiments that focus on the characteristics of velocity and fractional excess density profiles of saline density and turbidity currents flowing over a mobile bed. The gravity flows include saline density flows, hybrid saline/turbidity currents and a pure turbidity current. The use of dissolved salt is a surrogate for suspended mud that is so fine that it does not settle out readily. Thus, all the currents can be considered to be model turbidity currents. The data cover both Froude-subcritical and Froude-supercritical regimes. Depending on flow conditions, the bed remains flat or bed forms develop over time, which in turn affect vertical profiles. For plane bed experiments, subcritical flow profiles have velocity peaks located higher up in the flow, and display a sharper interface at the top of the current, than their supercritical counterparts. The latter have excess density profiles that decline exponentially upward from the bed, whereas subcritical flows show profiles with a region near the bed where excess density varies little. Wherever bed forms are present, they have a significant effect on the profiles. Especially for Froude-supercritical flow, bed forms push the location of peak velocity upward, and render the near-bed fractional excess density more uniform. In the case of subcritical flow, bed forms do not significantly affect fractional excess density profiles; velocity profiles are pushed farther upward from the bed than in the case of a plane bed, but to a lesser extent than for supercritical bed forms. Overall, the relative position of the velocity peak above the bed shows a dependence upon flow regime, being lowered for increasing Froude number Fd. Gradient Richardson numbers Rig in the near-bed region increase with increasing Fd, but are lower than the critical value of 0.25, indicating that near-bed turbulent structures are not notably suppressed. At the top interface, values of Rig are above the critical value for subcritical and mildly supercritical Fd, effectively damping turbulence. However as Fd increases, Rig goes below the critical value. Shape factors calculated from the profiles for use in the depth-averaged equation of motion are evaluated for different flow and bed conditions. Normalized experimental profiles for supercritical currents scale up well with observations of field-scale turbidity currents in the Monterey Canyon, and the range of average bed slopes and Froude numbers also compare favorably with estimated field-scale flow conditions for the Amazon canyon and fan. This suggests that the experimental results can be used to interpret the kinds of flows that are responsible for the shaping of major submarine canyon-fan systems.