Formation of chromium nitride layers on AISI 1010 steel by nitro-chromizing treatment

In this study, chromium nitride coating was realized on AISI 1010 steels by nitro-chromizing treatment. Steel samples were tufftrided at 575 °C for 2 h in the first step of the coating process, and then chromized by pack method in the powder mixture consisting of ferro-chromium, ammonium chloride and alumina at 1000 °C for 1-4 h. Samples were characterized by scanning electron microscopy (SEM), Energy dispersive X-ray spectroscopy, X-ray diffraction (XRD) analysis and Vickers micro-hardness tests. Coating layer formed on the steel samples is smooth and compact and well bonded to the steel matrix. The thickness of chromium nitride layer formed on the steel samples ranged from 5.16±1.48 to 13.45±1.73 μm, depending on the treatment time. The average micro-hardness value of the layer was 1789±59 HV_0.05. The layer consisted of Cr₂N and (Cr,Fe)₂N_(1−x) phases, according to XRD. EDS results showed that coating layer includes chromium and nitrogen.     

Cross-Layer Optimized Rate Adaptation and Scheduling for Multiple-User Wireless Video Streaming

We present a cross-layer optimized video rate adaptation and user scheduling scheme for multi-user wireless video streaming aiming for maximum quality of service (QoS) for each user,, maximum system video throughput, and QoS fairness among users. These objectives are jointly optimized using a multi-objective optimization (MOO) framework that aims to serve the user with the least remaining playback time, highest delivered video seconds per transmission slot and maximum video quality. Experiments with the IS-856 (1timesEV-DO) standard numerology and ITU pedestrian A and vehicular B environments show significant improvements over the state-of- the-art wireless schedulers in terms of user QoS, QoS fairness, and the system throughput.     

Determination of neotectonic features of the Karasu Basin (SE Turkey) and their relationship with Quaternary volcanic activity using Landsat ETM+ imagery

The junction between the East Anatolian and the Dead Sea fault zones lies close to an unstable F: Transform fault (FFF) triple junction where the African, Eurasian and Arabian plates meet in south-eastern Turkey. The Karasu Basin is an ephemeral rifted structure located close to the junction of these plate boundaries and is expressed by a range of tectono-morphological features. This study uses remote sensing to define tectonic structures and discriminate volcanic rocks linked to rifting within the basin using Landsat Enhanced Thematic Mapper Plus (ETM+) imagery. Prior to advanced image processing stages, images were corrected to eliminate atmospheric scattering effects and determine the best band combination for multi-spectral processing techniques based on statistical methods. Following pre-processing stages, edge detection filters were applied to derive tectonic structures defining the basin. The Brovey transformation, a statistical data merging method, was used to combine reflective multi-spectral bands with the Landsat ETM+?panchromatic band. This method fuses higher spatial data with data of lower spatial value. The western margin of the Karasu Basin is defined by the left-lateral Amanos Fault Zone with a contemporary motion (c. –0.4 mm a^?1) probably accommodating most of the left-lateral strike-slip motion between Arabian and African plates on the northern continuation of the Dead Sea Fault Zone. The rift zone has been the site of extensive recent volcanism concentrated within the Brunhes Chron (<0.78 Ma) and linked to fault block rotations between the intracontinental master faults. The boundaries of this activity are defined here using a regolith mapping technique.     

Reduced myofibroblast differentiation on femtosecond laser treated 316LS stainless steel

In-stent restenosis is a common complication after stent surgery which leads to a dangerous wall narrowing of a blood vessel. Laser assisted patterning is one of the effective methods to modify the stent surface to control cell–surface interactions which play a major role in the restenosis. In this current study, 316LS stainless steel substrates are structured by focusing a femtosecond laser beam down to a spot size of 50 μm. By altering the laser induced spot density three distinct surfaces (low density (LD), medium density (MD) and high density (HD)) were prepared. While such surfaces are composed of primary microstructures, due to fast melting and re-solidification by ultra-short laser pulses, nanofeatures are also observed as secondary structures. Following a detailed surface characterization (chemical and physical properties of the surface), we used a well-established co-culture assay of human microvascular endothelial cells and human fibroblasts to check the cell compatibility of the prepared surfaces. The surfaces were analyzed in terms of cell adherence, proliferation, cell morphology and the differentiation of the fibroblast into the myofibroblast, which is a process indicating a general fibrotic shift within a certain tissue. It is observed that myofibroblast proliferation decreases significantly on laser treated samples in comparison to non-treated ones. On the other hand endothelial cell proliferation is not affected by the surface topography which is composed of micro- and nanostructures. Such surfaces may be used to modify stent surfaces for prevention or at least reduction of restenosis.     

Convergence of an implicit algorithm for two families of nonexpansive mappings

In this paper, we study an implicit iterative algorithm for two nonexpansive mappings and two finite families of nonexpansive mappings in Banach spaces. We prove some weak and strong convergence theorems for these iterative algorithms. Our results extend some existing results.     

Simulation of fine sediment transport in oscillatory boundary layer

Sediment transport and resulting morphodynamics take place at vastly different spatial and temporal scales. Bottom boundary layer dynamics is one of the most critical small-scale processes controlling sediment transport. However, it is very challenging as it involves highly nonlinear turbulent flow phenomenon that occurs at a scale as small as Kolmogorov scales. The unsteady nature of the flow forcing in the coastal environment, such as waves, is another important factor that further complicates the process. This paper aims to take a step to better understand wave-driven turbulent boundary layer and corresponding transport process. The problem of wave-driven sediment transport is simplified into fully developed oscillatory channel flow. Particles are assumed to be fine and dilute and hence they can be approximately considered as passive except gravitational settling with its settling velocity estimated from Stokes' law. Highly accurate pseudo-spectral flow solver has been employed and Direct Numerical Simulation (DNS) is carried out to resolve all scales of flow turbulence without sub-grid closure. Sediment concentration is then updated via mass conservation. Clear fluid simulation for intermittently turbulent condition (i.e., Stokes Reynolds number Re_Δ = 1000) is validated with earlier DNS results reported by Spalart and Baldwin [1989. Direct simulation of a turbulent oscillating boundary layer. Turbulent Shear Flows 6. Springer]. Fine sediment with dilute concentration is then added in the numerical simulation to study sediment suspension events under oscillatory flow. Suspension events are evaluated both qualitatively, by observing vortex structures, and quantitatively by the statistics of vertical fluxes. For fine particles and dilute concentration considered here, it is observed that particle phase is well-mixed in the boundary layer. Suspension is highly dependent on turbulent vortical structures at different wave phases.     

A new approach for measuring RMS value and phase angle of fundamental harmonic based on Wavelet Packet Transform

Traditional ways of calculating/measuring harmonics in power systems have been based on Fourier Transform and algorithms, such as Fast Fourier Transform and Goertzel that implements it. In this study, a novel approach based on Wavelet Packet Transform is presented to measure Root-Mean-Square (RMS) value and phase angle of the fundamental harmonic. To this end, analytical expressions were derived and using a Graphical User Interface (GUI) designed and experimental works the validity of analytical expressions was demonstrated.     

Fast in situ copolymerization of PET/PEN blends by ultrasonically-aided extrusion

An ultrasonically-aided extrusion process was developed for fast in situ compatibilization of immiscible polymer blends. PET, PEN, and their 50/50 blend were ultrasonically extruded at various amplitudes. PET underwent homopolymerization and degradation, respectively, at ultrasonic amplitudes of 7.5 and 10 μm, while PEN underwent degradation at amplitudes of 5, 7.5, and 10 μm. MALDI-TOF mass spectrometry revealed greater amounts of hydroxyl and carboxyl terminated oligomers in ultrasonically treated PET and PEN, indicating their greater reactivity. Ultrasonic treatment at short residence time led to the enhancement of transesterification reaction in the PEN/PET blend, as shown by ¹H NMR and MALDI-TOF, indicating greater randomization with ultrasonic treatment. The latter was also observed through a shift in T_g that closely follows Gibbs-DiMarzio relation and an increase in viscosity of blend with treatment at an amplitude of 10 μm. No crystallinity was observed in the blend due to the already high level of transesterification introduced by extrusion without treatment. Accordingly, crystallinity, mechanical properties, oxygen permeability, and optical clarity of the blend were not influenced by ultrasonic treatment.     

Multiple linear regression modeling of disinfection by-products formation in Istanbul drinking water reservoirs

Oxidation of raw water with chlorine results in formation of trihalomethanes (THM) and haloacetic acids (HAA). Factors affecting their concentrations have been found to be organic matter type and concentration, pH, temperature, chlorine dose, contact time and bromide concentration, but the mechanisms of their formation are still under investigation. Within this scope, chlorination experiments have been conducted with water reservoirs from Terkos, Buyukcekmece and Omerli lakes, Istanbul, with different water quality regarding bromide concentration and organic matter content. The factors studied were pH, contact time, chlorine dose, and specific ultraviolet absorbance (SUVA). The determination of disinfection by-products (DBP) was carried out by gas chromatography techniques. Statistical analysis of the results was focused on the development of multiple regression models for predicting the concentrations of total THM and total HAA based on the use of pH, contact time, chlorine dose, and SUVA. The developed models provided satisfactory estimations of the concentrations of the DBP and the model regression coefficients of THM and HAA are 0.88 and 0.61, respectively. Further, the Durbin-Watson values confirm the reliability of the two models. The results indicate that under these experimental conditions which indicate the variations of pH, chlorine dosages, contact time, and SUVA values, the formation of THM and HAA in water can be described by the multiple linear regression technique.