Utilising grape juice processing by-products as bulking and colouring agent in white chocolate

In this study, grape pomace (mixture of grape seeds and skins) powder (GPP), obtained from grape processing, was used at different concentrations [10.0 (GPP10), 20.0 (GPP10) and 30.0 (GPP10) g/100 g] in white chocolate formulation for the partial replacement of sucrose. The results indicated that GPP addition at a higher concentration (>10.0 g/100 g) significantly affected the particle size, moisture content, texture and flow behaviour of white chocolate samples (P < 0.05). However, using GPP at a concentration of 10.0 g/100 g had advantages for physicochemical and flow properties. As expected, under simulated in vitro digestion conditions, the bioaccessibility of total phenolic compounds in saliva, gastric juice and intestinal juice for GPP10 samples was significantly higher than the control (P < 0.05). In conclusion, results of the study showed that it was possible to partially replace the sucrose with GPP at a concentration of 10.0 g/100 g in white chocolate formulations.     

Systematic multiscale models to predict the compressive strength of self-compacting concretes modified with nanosilica at different curing ages

The evolution of nanotechnology brings materials with novel performance and during last year’s much attempt has been established to include nanoparticles especially nano-silica (NS) into the concrete to improve performance and develop concrete with enhanced characteristics. Generally, NS is incorporated into the self-compacting concrete (SCC) aiming to positively influence the fresh, mechanical, microstructure, and durability properties of the composite. The most important mechanical property for all types of concrete composites is compressive strength. Therefore, developing reliable models for predicting the compressive strength of SCC is crucial regarding saving time, energy, and cost-effectiveness. Moreover, it gives valuable information for scheduling the construction work and provides information about the correct time for removing the formwork. In this study, three different models including the linear relationship model (LR), nonlinear model (NLR), and multi-logistic model (MLR) were proposed to predict the compressive strength of SCC mixtures made with or without NS. In this regard, a comprehensive data set that consists of 450 samples were collected and analyzed to develop the models. In the modeling process, the most important variables affecting the compressive strength such as NS content, cement content, water to binder ratio, curing time from 1 to 180 days, superplasticizer content, fine aggregate content, and coarse aggregate content were considered as input variables. Various statistical assessments such as Root Mean Squared Error (RMSE), Mean Absolute Error (MAE), Scatter Index (SI), OBJ value, and the coefficient of determination (R²) were used to evaluate the performance of the proposed models. The results indicated that the MLR model performed better for forecasting the compression strength of SCC mixtures modified with NS compared to other models. The SI and OBJ values of the MLR model were 18.8% and 16.7% lower than the NLR model, indicating the superior performance of the MLR model. Moreover, the sensitivity analysis demonstrated that the curing time is the most affecting variable for forecasting the compressive strength of SCC modified with NS.

     

Adaptive State-space Control of Under-actuated Systems Using Error-magnitude Dependent Self-tuning of Cost Weighting-factors

International Journal of Control, Automation and Systems - This article methodically constructs a novel adaptive self-tuning state-space controller that enhances the robustness of under-actuated...     

Highly active and stable CeO2 supported nickel-complex catalyst in hydrogen generation

Cerium oxide supported 5-Amino-2,4-dichlorophenol-3,5-ditertbutylsalisylaldimine-Nickel complex for the first time was used to produce H₂ from hydrolysis of sodium borohydride. Cerium oxide supported Nickel complex catalyzed hydrolysis system was studied depend on temperature, concentration of sodium hydroxide, amount of Cerium oxide supported Ni complex catalyst, concentration of Ni complex and concentration of sodium borohydride. Cerium oxide supported Ni(II) complex display highly effective catalytic activity in sodium borohydride hydrolysis reaction. The obtained Cerium oxide supported Ni(II) complex catalyst was characterized by using Fourier Transform Infrared Spectroscopy, Scanning Electron Microscope, Transmission Electron Microscope, Brunauer-Emmett-Teller Surface Area Analysis, X-Ray Diffraction Analysis techniques. The catalyst stability was tested, even the fifth recycle the catalytic activity was maintained at 100%. Additionally the proposed Cerium oxide supported-Ni (II) complex catalyzed sodium borohydride hydrolysis mechanism was determined carefully. The experimental results showed that Cerium oxide supported Ni (II) complex catalyst accelerate sodium borohydride hydrolysis with 43,392 and 19,630 mL H₂ g_cat^?1 min^?1 hydrogen production rates at 50 °C and 30 °C respectively and 20,587 kJ mol^?1 activation energy.     

Polymeric Nanoparticles as a Self-Adjuvanting Peptide Vaccine Delivery System: The Role of Shape

Antigens incorporated in subunit vaccines are typically poorly immunogenic, so a strong immunostimulant (adjuvant) and/or delivery system is required to boost immunogenicity. In this work, the various functional polymer nanostructures, that is, rods, worms, spheres, and tadpoles are used to develop potent peptide antigen delivery systems. The antigen PADRE-J8 (PJ8), derived from Group A Streptococcus (GAS) M-protein, is either physically mixed or chemically conjugated to polymeric nanoparticles of different shapes. The physical mixture of polymeric nanoparticles and antigen is more effective in inducing antibody production than their chemical conjugates. Moreover, rod-shaped polymeric nanoparticles in physical mixture with PJ8 elicited higher and more opsonic antibody titers than powerful complete Freund's adjuvant (CFA)-adjuvanted antigen. Herein, for the first time it is demonstrated that a) the block copolymer, in nanoparticle form, can act as an immune adjuvant, b) nanoparticle shape plays a crucial role in their immunogenicity, and c) antigen conjugation is not required, nor is antigen encapsulation or absorption.     

TENET: a new hybrid network architecture for adversarial defense

International Journal of Information Security - Deep neural network (DNN) models are widely renowned for their resistance to random perturbations. However, researchers have found out that these...     

Investigating the effect of production process of ball mill refiner on some physical quality parameters of compound chocolate: response surface methodology approach

Chocolate compound was produced using ball mill refiner, and the effect of agitator shaft speed and refining time on the physical quality parameters (particle size, colour and steady‐state rheology) of compound chocolate was determined using response surface methodology. The shaft speed and refining time range were selected between 40–60 r.p.m. and 10–30 min, respectively. Determination coefficient of the models established for particle size, Newtonian viscosity and colour parameters (brightness, chroma and hue angle) were found to be very close to unity. Increasing shaft speed and time induced a reduction in particle size and an increase in viscosity of the samples. Temperature sweep test was also performed, and the obtained data were successfully fitted to Arrhenius equation to calculate the corresponding parameters representing temperature dependency of the compounds. The results highlighted that the establishment of such models can provide essential information in terms of optimisation of production processes regarding usage purpose of the compound chocolate.     

Heat pipes thermoelectric solar collectors for energy applications

This study investigates the load characteristics of heat pipe thermoelectric solar collector (HPTSC) in practice. Heat pipe thermoelectric solar collector converts the heat generated by the Sun directly into electrical energy and produces hot water as well. The maximum power in HPTSC is obtained when the internal resistance of the thermoelectric module is equal to the load resistance. It has been observed to be possible to produce both hot water and electricity by improving available solar collectors or producing new generation HPTSC. While it is possible to generate an electrical power of 160 W from a HPTSC of one square meter using the thermoelectric method, the power produced with an average photovoltaic panel with the same area is only 132 W. Accordingly, HPTSC is a superior alternative not only to available solar collectors, but also to available PV panels. HPTSC, involving three different technologies, is environmentally friendly and certainly a product that allows for more efficient use of solar energy.