Micro Solid Oxide Fuel Cells on Glass Ceramic Substrates

Miniaturized solid oxide fuel cells are fabricated on a photostructurable glass ceramic substrate (Foturan) by thin film and micromachining techniques. The anode is a sputtered platinum film and the cathode is made of a spray pyrolysis (SP)‐deposited lanthanum strontium cobalt iron oxide (LSCF), a sputtered platinum film and platinum paste. A single‐layer of yttria‐stabilized zirconia (YSZ) made by pulsed laser deposition (PLD) and a bilayer of PLD–YSZ and SP–YSZ are used as electrolytes. The total thickness of all layers is less than 1 µm and the cell is a free‐standing membrane with a diameter up to 200 µm. The electrolyte resistance and the sum of polarization resistances of the anode and cathode are measured between 400 and 600 °C by impedance spectroscopy and direct current (DC) techniques. The contribution of the electrolyte resistance to the total cell resistance is negligible for all cells. The area‐specific polarization resistance of the electrodes decreases for different cathode materials in the order of Pt paste > sputtered Pt > LSCF. The open circuit voltages (OCVs) of the single‐layer electrolyte cells ranges from 0.91 to 0.56 V at 550 °C. No electronic leakage in the PLD–YSZ electrolyte is found by in‐plane and cross‐plane electrical conductivity measurements and the low OCV is attributed to gas leakage through pinholes in the columnar microstructure of the electrolyte. By using a bilayer electrolyte of PLD–YSZ and SP–YSZ, an OCV of 1.06 V is obtained and the maximum power density reaches 152 mW cm⁻² at 550 °C.     

Cavitation Rates in Water with Dissolved Gas and Other Impurities

Our objective is a better understanding of the role of physical properties of real fluids in the thermodynamics of cavitation in impure water. An extension to the classical homogenous nucleation theory suitable for mixtures is presented in attempt to address the discrepancy between the theoretical predictions and practical observations of cavitation rates in water at normal temperatures. The extension takes into account the non-equilibrium (dissipative) effects involved in nuclei formation through a substance dependent correction coefficient to be determined experimentally. The theory of thermodynamic fluctuations is applied to derive the work of formation of a bubble nucleus. The value of the correction coefficient is estimated using preliminary experimental data from a convergent-divergent nozzle. An application of the results to the numerical prediction of the cavitation zones in a radial-flow water pump is shown.     

Generation of low‐contrast sinusoidal test patterns on a high‐brightness display

Abstract— By using a technique of addressing individual subpixels, low‐contrast sinusoidal test patterns were generated on a high‐brightness color LCD. Detection tasks were performed using 2AFC experiments, and the value obtained for the contrast threshold was found to agree well with previously published data. As long as the shape of the pattern was close to sinusoidal, a good correlation was found between pattern contrast and detection rate. The influence of the eye‐adaptation luminance level was studied and compared to the f‐factor published by Barten. Luminance non‐uniformities in the background did not cause any significant change in the detection threshold.     

Households' switching behavior between electricity suppliers in Sweden

The overall purpose of this paper is to analyze the factors affecting households' decisions to: (a) switch to a new electricity supplier; and (b) actively renegotiate the electricity contract with the prevailing supplier. The study is based on 536 survey responses from Swedish households and they are analyzed econometrically using probit regression techniques. The analysis is based on a theoretical framework, which embraces both economic and psychological motives behind household decision-making. The results show that households that anticipate significant economic benefits from choosing a more active behavior are also more likely to purse this, while those with smaller potential gains (e.g., households without electric heating) are less likely to change supplier and/or renegotiate their contracts. The impact of overall electricity costs and knowledge about these is particularly important for the latter decision, while respondents that perceive relatively high search and information costs are less likely to switch to an alternative electricity supplier. Moreover, constraints on time, attention, and the ability to process information, may lead to optimizing analyses being replaced by imprecise routines and rules of thumb, and the benefits of the status quo appear to represent one of those simplifying rules. This also opens up for other influences on households' activity such as social interaction and media discourses that raise the attention level. Our results show that these influences are more likely to affect households' choice to switch to new service providers, i.e., the one area of the two investigated here that put the most demand on people's ability to search for and process information.     

Optical and MRI multifunctional nanoprobe for targeting gliomas

A multifunctional nanoprobe capable of targeting glioma cells, detectable by both magnetic resonance imaging and fluorescence microscopy, was developed. The nanoprobe was synthesized by coating iron oxide nanoparticles with covalently bound bifunctional poly(ethylene glycol) (PEG) polymer, which were subsequently functionalized with chlorotoxin and the near-infrared fluorescing molecule Cy5.5. Both MR imaging and fluorescence microscopy showed significant preferential uptake of the nanoparticle conjugates by glioma cells. Such a nanoprobe could potentially be used to image resections of glioma brain tumors in real time and to correlate preoperative diagnostic images with intraoperative pathology at cellular-level resolution.     

Microsecond protein dynamics measured by 13Calpha rotating-frame spin relaxation

NMR spin relaxation in the rotating frame (R1rho) is a unique method for atomic-resolution characterization of conformational (chemical) exchange processes occurring on the microsecond timescale. We present a rotating-frame 13C(alpha) relaxation dispersion experiment for measuring conformational dynamics in uniformly 13C-labeled proteins. The experiment was validated by using the E140Q mutant of the C-terminal fragment of calmodulin, which exhibits significant conformational exchange between two major conformations, as gauged from previous 15N and 1H relaxation studies. Consistent with previous work, the present 13C(alpha) R1rho experiment detects conformational-exchange dynamics throughout the protein. The average correlation time of =25+/-8 micros is in excellent agreement with those determined previously from 1H and 15N R1rho relaxation data: =19+/-7 and 21+/-3 micros, respectively. The extracted chemical-shift differences between the exchanging states reveal significant fluctuations in dihedral angles within single regions of Ramachandran phi-psi space, that were not identified from the 1H and 15N relaxation data. The present results underscore the advantage of using several types of nuclei to probe exchange dynamics in biomolecules.     

Nanotribological characterization of perfluoroalkylphosphonate self-assembled monolayers deposited on aluminum-coated silicon substrates

Aluminum-coated silicon substrates are commonly used for various micro/nanooptoelectromechanical systems (MOEMS/NOEMS) including Digital Micromirror Devices (DMD^®). For efficient and failure proof operation of these devices, ultra-thin lubricant films of self-assembled monolayers (SAMs) are increasingly being employed. Fluorinated molecules are known to exhibit low surface energy, adhesion, and friction, desirable for tribological applications. In this study, we investigate contact angle, surface energy, friction, adhesion, and wear properties of a perfluoroalkylphosphonate SAM and compare them with those of alkylphosphonate SAMs. The influence of relative humidity, temperature, and sliding velocity on the friction and adhesion behavior is studied. Failure mechanisms of SAMs are investigated by wear tests. These studies are expected to aid in the design and selection of proper lubricants for MOEMS/NOEMS.