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51.
Daniel Duda Patrik Švančara Marco La Mantia Miloš Rotter David Schmoranzer Oleg Kolosov Ladislav Skrbek 《Journal of Low Temperature Physics》2017,187(5-6):376-382
We report direct optical observation of cavitation bubbles in liquid helium, both in classical viscous He I and in superfluid He II, close to the \(\lambda \)-transition. Heterogenous cavitation due to the fast-flowing liquid over the rough surface of prongs of a quartz tuning fork oscillating at its fundamental resonant frequency of \(4\,\mathrm {kHz}\) occurs in the form of a cluster of small bubbles rapidly changing its size and position. In accord with previous investigators, we find the cavitation threshold lower in He I than in He II. In He I, the detached bubbles last longer than one camera frame (10 ms), while in He II the cavitation bubbles do not tear off from the surface of the fork up to the highest attainable drive. 相似文献
52.
Flight controllers for micro-air UAVs are generally designed using proportional-integral-derivative (PID) methods, where the tuning of gains is difficult and time-consuming, and performance is not guaranteed. In this paper, we develop a rigorous method based on the sliding mode analysis and nonlinear backstepping to design a PID controller with guaranteed performance. This technique provides the structure and gains for the PID controller, such that a robust and fast response of the UAV (unmanned aerial vehicle) for trajectory tracking is achieved. First, the second-order sliding variable errors are used in a rigorous nonlinear backstepping design to obtain guaranteed performance for the nonlinear UAV dynamics. Then, using a small angle approximation and rigorous geometric manipulations, this nonlinear design is converted into a PID controller whose structure is naturally determined through the backstepping procedure. PID gains that guarantee robust UAV performance are finally computed from the sliding mode gains and from stabilizing gains for tracking error dynamics. We prove that the desired Euler angles of the inner attitude controller loop are related to the dynamics of the outer backstepping tracker loop by inverse kinematics, which provides a seamless connection with existing built-in UAV attitude controllers. We implement the proposed method on actual UAV, and experimental flight tests prove the validity of these algorithms. It is seen that our PID design procedure yields tighter UAV performance than an existing popular PID control technique. 相似文献
53.
Craig A. Peeples Delf Kober Franz-Josef Schmitt Patrik Tholen Konrad Siemensmeyer Quinn Halldorson Bünyemin Çoşut Aleksander Gurlo Ahmet Ozgur Yazaydin Gabriel Hanna Gündoğ Yücesan 《Advanced functional materials》2021,31(3):2007294
A conductive phosphonate metal–organic framework (MOF), [{Cu(H2O)}(2,6-NDPA)0.5] (NDPA = naphthalenediphosphonic acid), which contains a 2D inorganic building unit (IBU) comprised of a continuous edge-sharing sheet of copper phosphonate polyhedra is reported. The 2D IBUs are connected to each other via polyaromatic 2,6-NDPA's, forming a 3D pillared-layered MOF structure. This MOF, known as TUB40, has a narrow band gap of 1.42 eV, a record high average electrical conductance of 2 × 102 S m−1 at room temperature based on single-crystal conductivity measurements, and an electrical conductance of 142 S m−1 based on a pellet measurement. Density functional theory (DFT) calculations reveal that the conductivity is due to an excitation from the highest occupied molecular orbital on the naphthalene-building unit to the lowest unoccupied molecular orbital on the copper atoms. Temperature-dependent magnetization measurements show that the copper atoms are antiferromagnetically coupled at very low temperatures, which is also confirmed by the DFT calculations. Due to its high conductance and thermal/chemical stability, TUB40 may prove useful as an electrode material in supercapacitors. 相似文献
54.
The development of selected ion flow tube mass spectrometry, SIFT‐MS, is described from its inception as the modified very large SIFT instruments used to demonstrate the feasibility of SIFT‐MS as an analytical technique, towards the smaller but bulky transportable instruments and finally to the current smallest Profile 3 instruments that have been located in various places, including hospitals and schools to obtain on‐line breath analyses. The essential physics and engineering principles are discussed, which must be appreciated to design and construct a SIFT‐MS instrument. The versatility and sensitivity of the Profile 3 instrument is illustrated by typical mass spectra obtained using the three precursor ions H3O+, NO+ and ${\rm O}_{{\rm 2}}^{{\rm + } \cdot }$ , and the need to account for differential ionic diffusion and mass discrimination in the analytical algorithms is emphasized to obtain accurate trace gas analyses. The performance of the Profile 3 instrument is illustrated by the results of several pilot studies, including (i) on‐line real time quantification of several breath metabolites for cohorts of healthy adults and children, which have provided representative concentration/population distributions, and the comparative analyses of breath exhaled via the mouth and nose that identify systemic and orally‐generated compounds, (ii) the enhancement of breath metabolites by drug ingestion, (iii) the identification of HCN as a marker of Pseudomonas colonization of the airways and (iv) emission of volatile compounds from urine, especially ketone bodies, and from skin. Some very recent developments are discussed, including the quantification of carbon dioxide in breath and the combination of SIFT‐MS with GC and ATD, and their significance. Finally, prospects for future SIFT‐MS developments are alluded to. © 2010 Wiley Periodicals, Inc., Mass Spec Rev 30:236–267, 2011 相似文献
55.
Patrik Ahlberg Malkolm Hinnemo Shi-Li Zhang Jörgen Olsson 《Journal of Electronic Materials》2018,47(3):1757-1761
By pretreating the substrate of a graphene field-effect transistor (G-FET), a stable unipolar transfer characteristic, instead of the typical V-shape ambipolar behavior, has been demonstrated. This behavior is achieved through functionalization of the SiO2/Si substrate that changes the SiO2 surface from hydrophilic to hydrophobic, in combination with postdeposition of an Al2O3 film by atomic layer deposition (ALD). Consequently, the back-gated G-FET is found to have increased apparent hole mobility and suppressed apparent electron mobility. Furthermore, with addition of a top-gate electrode, the G-FET is in a double-gate configuration with independent top- or back-gate control. The observed difference in mobility is shown to also be dependent on the top-gate bias, with more pronounced effect at higher electric field. Thus, the combination of top and bottom gates allows control of the G-FET’s electron and hole mobilities, i.e., of the transfer behavior. Based on these observations, it is proposed that polar ligands are introduced during the ALD step and, depending on their polarization, result in an apparent increase of the effective hole mobility and an apparent suppressed effective electron mobility. 相似文献
56.
A Comparison of Leisure Time Spent in a Garden with Leisure Time Spent Indoors: On Measures of Restoration in Residents in Geriatric Care 总被引:2,自引:0,他引:2
During the past 20 years, findings have indicated that nature plays an active role in helping people recover from stress and fatigue. Two of the most cited theories in this field are Rachel and Stephen Kaplan's theory of recovery from Directed Attention Fatigue in nature and Roger Ulrich's theory of aesthetic and affective responses to natural environments and stress recovery. One aim of the present study is to test whether being outdoors in a green recreational environment causes people to be more focused, compared to being in a room indoors (in line with hypotheses suggested by the Kaplans). Another aim is to test whether people experience stress reduction, i.e. as evidenced by changes in blood pressure and heart rate, if they are placed in an environment with many green elements (in line with hypotheses suggested by Ulrich). The overall study design is that of an intervention study. Fifteen elderly persons living at a home for very elderly people participated. Their powers of concentration, blood pressure and heart rate were measured before and after an hour of rest in a garden or in an indoor setting. Seven elderly people were randomly chosen to have their first series of tests in a garden, while eight elderly people had their first series of tests indoors. The results indicate that powers of concentration increase for very elderly people after a visit to a garden outside the geriatric home in which they live, compared to that after resting indoors in their favourite room. The results did not show any effects on blood pressure or heart rate. It is suggested that having a one-hour rest outdoors in a garden setting plays a role in elderly people's powers of concentration, and could thereby affect their performance of activities of daily living. One important factor in this study was that both the outdoor environment and the indoor environment at the home were highly valued by participants. 相似文献
57.
The present work presents methodology and development of a mathematical model for prediction of the influence of oxide scale on heat transfer during reheating of steel in an industrial furnace. In this developed model, temperatures inside the steel billet were measured and with thermocouples at selected places and were collected by a water cooled computer that was traveling inside the slab. CFD is used to calculate the flow field inside of a furnace. The mass‐transfer coefficient of the scale formation is obtained by solving the convection mass‐diffusion equation across a boundary layer to the surface of a flat plate. A model for inverse heat conduction is employed to calculate the local surface temperature and heat flux on top of the growing oxide scale layer on a slab moving through a walking beam reheating furnace. By using the inverse method, the transient temperature and heat flux was firstly determined on the surface of the steel. During subsequent computations, the growth of the scale was calculated and the surface temperature of the oxide scale was extracted by using the Cauchy data from the previous calculations. The sensibility of the model on steel physical parameters is studied, and suitable parameters were obtained for heating a low carbon steel plate in the reheating furnace. Results show that the oxide scale layer should not be neglected in reheating models. 相似文献
58.
The development of low-cost, accurate, and equipment-free diagnostic tests is crucial to many clinical, laboratory, and field applications, including forensics and medical diagnostics. Cellulose fiber-based paper is an inexpensive, biodegradable, and renewable resource, the use of which as a biomolecule detection matrix and support confers several advantages compared to traditional materials such as glass. In this context, a new, facile method for the preparation of surface functionalized papers bearing single-stranded probe DNA (ssDNA) for rapid target hybridization via capillary transport is presented. Optimized reaction conditions were developed that allowed the direct, one-step activation of standard laboratory filters by the inexpensive and readily available bifunctional linking reagent, 1,4-phenylenediisothiocyanate. Such papers were thus amenable to subsequent coupling of amine-labeled ssDNA under standard conditions widely used for glass-based supports. The intrinsic wicking ability of the paper matrix facilitated rapid sample elution through arrays of probe DNA, leading to significant, detectable hybridization in the time required for the sample liquid to transit the vertical length of the strip (less than 2 min). The broad applicability of these paper test strips as rapid and specific diagnostics in "real-life" situations was exemplified by the discrimination of amplicons generated from canine and human mitochondrial and genomic DNA in mock forensic samples. 相似文献
59.
Shariatgorji M Källback P Gustavsson L Schintu N Svenningsson P Goodwin RJ Andren PE 《Analytical chemistry》2012,84(10):4603-4607
The limit of detection of low-molecular weight compounds in tissue sections, analyzed by matrix assisted laser desorption ionization mass spectrometry imaging (MALDI-MSI), was significantly improved by employing sample washing using a pH-controlled buffer solution. The pH of the washing solutions were set at values whereby the target analytes would have low solubility. Washing the tissue sections in the buffered solution resulted in removal of endogenous soluble ionization-suppressing compounds and salts, while the target compound remained in situ with minor or no delocalization during the buffered washing procedure. Two pharmaceutical compounds (cimetidine and imipramine) and one new protease inhibitor compound were successfully used to evaluate the feasibility of the pH-controlled tissue washing protocol for MALDI-MSI. Enhancement in signal-to-noise ratio was achieved by a factor of up to 10. 相似文献
60.