Low temperature synthesis of calcium cobaltites in a solid state reaction

This paper presents synthesis of calcium cobaltites of the nominal composition of Ca₃Co₄O₉ prepared by the solid state reaction. The reaction between CaCO₃ and Co₃O₄ was investigated at 700–900 °C during 20 h and at 800 °C during 2–30 h. Mass changes, phase composition and Co⁺³, Co⁺⁴ content were examined. Stability of the calcined specimens was tested by DTA/TG. It was found that two phases: Ca₃Co₄O₉ and Ca₃Co₂O₆ were present as a result of calcinations above 800 °C. On the other hand, the temperature of 750 °C was too low for calcium cobaltites to be synthesized. Mono-phase material with Ca₃Co₄O₉ phase was obtained after calcinations at 800 °C but non-stoichiometry of the compound and its relation to the calcinations time were found. Once synthesized, the compound was stable up to 900 °C.     

Comparison of Two Analytical Methods for Assessing Antioxidant Capacity of Rapeseed and Olive Oils

The oxygen radical absorbance capacity (ORAC) and the ferric reducing antioxidant power (FRAP) methods were used for the determination of antioxidant capacities (AC) of rapeseed oils at different steps of technological process and olive oils. The mean ORAC and FRAP results obtained for rapeseed oils (1,106–160 and 552–95.6 μmol TE/100 g) were higher than for olive oils (949–123 and 167–32.1 μmol TE/100 g). Although, FRAP values were lower than ORAC values for all studied oils, there is a linear and significant correlation between these two analytical methods (r = 0.9665 and 0.9298, P < 0.0005) for rapeseed and olive oils, respectively). Also, total phenolic compounds in rapeseed oils and olives correlated with antioxidant capacities (correlation coefficient ranged between 0.9470 and 0.8049). The refining process of rapeseed oils decreased the total phenolics content and antioxidant capacities by about 80%.     

Application testing of Sr doping effect of PZT ceramics on the piezoelectric transformer gain and efficiency proposed for MEMS actuators driving

Effect of Sr content in lead zirconate titanate PZT ceramic system on performance of piezoelectric transformer application were studied. Our experiments provide consistent evaluation of doping strontium amount on piezoelctric coefficients values and final voltage gain and efficiency of piezoelectric transformer. Extreme values of these parameters are preferred for MEMS device effective driving. Modification of ferroelectric materials with isovalent ions, however with the bigger radii than the original atoms, significantly affects their properties. Particularly the electromechanical coefficients of (Pb_1-xSr_x)(Zr_0,70Ti_0,30)O₃, for mole %??s as x?=?0.05, 0.10 and 0.15 ceramics exhibit marked increase, if the PSZT material stoichiometry is near the ferroelectric/relaxor phase boundary. To determine the piezoelectric coefficients, the resonance-antiresonance method was implemented. The results indicated that addition of Sr²⁺ ions in the amount of 5?mol% in the ceramic structure maximally increased the values of piezoelectric parameter to d₃₁?=?8.2?pC/N and mechanical quality factor Q_m?=?2902. Finally we demonstrated that in spite of the high piezoelectric coefficients for certain material only the practical examination must be applied in order to draw decisive application conclusions due to the complexity of the double energy conversion in such a specific device as the piezoelectric transformer.     

Isolation and amino acid sequence of a serine proteinase inhibitor from common flax (Linum usitatissimum) seeds

LUTI (Linum usitatissimum trypsin inhibitor), a member of the potato inhibitor I family, has been isolated from seeds of flax by ethanol fractionation, ion exchange chromatography on CM-Sephadex C-25, affinity purification on immobilized methylchymotrypsin (alpha-chymotrypsin in which His57 has been converted to 3-methylhistidine) in the presence of 5M NaCl, and finally by reversed-phase HPLC. The 7655 Da inhibitor consists of a single polypeptide chain of 69 residues with one disulfide bridge. The molecule is acetylated at the N terminus. Its primary structure has been determined after limited proteolysis of the native molecule with trypsin at the reactive site, cleavage with cyanogen bromide or arginyl endopeptidase (Arg-gingipain), and alcoholytic deacetylation of the N-terminally blocked serine. The association constants (K(a)) of LUTI with bovine beta-trypsin and alpha-chymotrypsin are 3.58x10(10) M(-1) and 5.02x10(5) M(-1), respectively. High NaCl concentration (3M) increased the association constant of LUTI with alpha-chymotrypsin to 6.64x10(7) M(-1). To our knowledge, LUTI is the first serine-proteinase-type inhibitor isolated from a plant of the Linaceae family.     

A heuristic approach to the reinforcement-learning control of the one-dimensional model of an HTR core

Results of calculations are presented, which are concerned with applications of the heuristic linear reinforcement systems to the control of pebble-bed HTRs with the OTTO-loading scheme. Control results of three types of systems applications are presented and discussed. The systems were found to be satisfactory for control of the complex physical plants.