Investigation of hydrogen storage capacity of various carbon materials

Hydrogen storage capacity of various carbon materials, including activated carbon (AC), single-walled carbon nanohorn, single-walled carbon nanotubes, and graphitic carbon nanofibers, was investigated at 303 and 77 K, respectively. The results showed that hydrogen storage capacity of carbon materials was less than 1 wt% at 303 K, and a super activated carbon, Maxsorb, had the highest capacity (0.67 wt%). By lowering adsorption temperature to 77 K, hydrogen storage capacity of carbon materials increased significantly and Maxsorb could store a large amount of hydrogen (5.7 wt%) at a relatively low pressure of 3 MPa. Hydrogen storage capacity of carbon materials was proportional to their specific surface area and the volume of micropores, and the narrow micropores was preferred to adsorption of hydrogen, indicating that all carbon materials adsorbed hydrogen gas through physical adsorption on the surface.     

微通道反应器内合成高纯度碘化钾

利用微通道反应器,研究了氢碘酸、甲酸溶液及氢氧化钾合成碘化钾的反应,考察了反应温度、原料配比、停留时间对碘化钾产率的影响。获得了较优的反应工艺条件,反应温度为85℃、停留时间为30 s、m(氢碘酸)∶m(甲酸)=54%、m(氢氧化钾)∶m(水)=31%。在该优化工艺条件下,碘化钾的产率为97%,产品纯度达到99%。实验结果表明,该方法具有反应时间短、产品收率高、绿色环保等优点。     

渗金属气压对光电高温计测温精度影响的实验研究

为准确控制双辉等离子渗金属工件的温度,借助自制的一套热电偶测温实验装置,对光电高温计测温进行了比对实验,探讨了气压对光电高温计测温精度的影响。实验结果表明:在双辉等离子渗金属过程中,对同一工件温度,随工作气压的升高,光电高温计所用的ε值也增大。工作气压每增高5～10Pa,将ε值提高0 1,这时光电高温计的温度测量误差会小于±3℃。     

Synthesis and Photocrosslinking Reaction of N-Allylcarbamoylmethyl Cellulose Leading to Hydrogel

Summary The reaction of the carboxymethyl cellulose sodium salt (Na-CMC) (degrees of substitution (DS) = 1.2) with N-hydroxysuccinimide (Su-OH) in the presence of 1-hydroxybenzotriazole and 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) was carried out in water to obtain the Su-OH ester of carboxymethyl cellulose, Su-CMC, with the DS values of 0.19 – 1.04. N-Allylcarbamoylmethyl cellulose (Allyl-CMC), which was prepared from the reaction of Su-CMC with an excess amount of allylamine, was crosslinked by UV-irradiation. In addition, the photocrosslinked Allyl-CMC film was swollen with water to form a hydrogel having a relatively high water-swelling property, e.g., the degree of swelling (ds) was ca. 360% for Allyl-CMC with the DS of 0.93.     

Synthesis of stable and soluble one-handed helical poly(substituted acetylene)s without chiral pendant groups via polymer reaction in membrane state

A soluble and stable one-handed helical conjugated polymer without the coexistence of any other chiral moieties was successfully synthesized by asymmetric-induced polymerization of a chiral monomer having two hydroxyl groups followed by desubstitution of the chiral groups in a solid membrane state. The reason for the success was the polymer reaction was carried out in the membrane state. This is an alternative method to obtain such a unique chiral polymer which was obtained only by the helix-sense-selective polymerization (HSSP) we reported before. In addition the efficiency of the chiral induction was higher than that of the HSSP. It is interesting that the “Membrane state” acted like as if a protecting group.     

三江盆地地史模拟及其地质意义研究

利用盆地数值模拟技术恢复了三江盆地地史演化过程.研究表明,三江盆地绥滨坳陷沉降开始较早,滴道组-穆棱组时期,盆地经历一次大规模的沉降-抬升过程;前进坳陷沉降开始较晚,从海浪组时期到富锦组沉积前,是盆地形成、发展的主要时期;三江盆地与松辽盆地北部的沉降趋势基本一致,其差异性主要表现在断陷作用后构造演化的不同.     

决策规则获取算法及规则表示

提出了一种基于粗糙集理论的决策规则获取算法及实用的决策规则表示方法。产品智能设计系统中,在概念设计阶段需要决定产品的类型。一般的产品设计过程,是从分析用户给定的技术参数、设计要求开始。规则获取算法就是从设计参数中挖掘设计知识,从而确定哪种类型的产品最适合用户的要求。该算法不需要任何先验知识。为了将算法应用到实际系统中,必须解决规则表示问题。本文将关系数据库成功地应用于设计规则的表示,使设计出的专家系统推理方便,运行效率高。通过继电器智能设计实例,说明了本方法的应用。     

H62/Cu同基合金磁控电弧离子镀镀层显微组织

用扫描电子显微镜和能谱仪对H62/Cu同基合金磁控电弧离子镀镀层进行了研究.结果表明,电弧离子镀电流对镀层晶粒尺寸有较大影响,弧电流较小时镀层晶粒较细,而弧电流较大时镀层的晶粒粗大.镀层主要由3部分组成:过渡层(伪扩散层 真扩散层)、细晶层和蘑菇状晶粒层.镀层中铜、锌元素分布不均匀,造成这种现象的原因与铜、锌的熔点及其离子的电离能有关.     

有线电视信号光纤传输及其优势

对有线电视网络从过去的完全同轴电缆传输,到现在的光纤与同轴电缆混合传输(HFC),再到将来的完全光纤传输,作了分析和介绍。指出光纤逐步取代同轴电缆是技术革新与发展的必然结果,重点介绍了光纤电视网络传输的十大优势。