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151.
Jesús?MarínEmail author 《Soft Computing - A Fusion of Foundations, Methodologies and Applications》2012,16(4):683-698
Ruggedness has a strong influence on the performance of algorithms, but it has been barely studied in real-coded optimization,
mainly because of the difficulty of isolating it from a number of involved topological properties. In this paper, we propose
a framework consisting of increasing ruggedness function sets built by a mechanism which generates multiple funnels. This
mechanism introduces different levels of sinusoidal distortion which can be controlled to isolate the singular influence of
some related features. Some commonly used measures of ruggedness have been applied to analyze these sets of functions, and
a numerical study to compare the performance of some representative algorithms has been carried out. The results confirm that
ruggedness has an influence on the performance of the algorithm, proving that it depends on the multi-funnel structure and
peak features, such as height and relative size of the global peak, and not on the number of peaks. 相似文献
152.
Alejandro F. Villaverde Cesáreo Raimúndez Antonio Barreiro 《International Journal of Control, Automation and Systems》2012,10(1):78-87
Crane operation is a challenging task, due to the combined problem of obstacle avoidance and load swing suppression in underactuated
conditions. This paper presents a human-machine interface that increases the operator’s perception of a gantry crane’s workspace.
With this aim, a virtual environment resembling the workspace is connected with a haptic device. This allows the user to receive
not only visual but also tactile feedback, thus increasing maneuvering safety. Additionally, this capability is integrated
in a teleoperation setup, adopting a passivity-based control approach that guarantees overall stability. This includes also
the design of controllers by means of the IDA-PBC method. Experimental results carried out with a laboratory crane show its
feasibility for internet-based teleoperation and demonstrate the improvements on the system performance. 相似文献
153.
The perovskite-type oxide PrCoO3 has been studied by means of X-ray photoelectron spectroscopy (XPS), reduction in H2 and X-ray diffraction. Two types of oxygen were detected: lattice oxygen (binding energy = 528.4 eV) and adsorbed oxygen (binding energy = 530.9 eV). The increase in relative intensity of the peak corresponding to the latter species after reduction of PrCo03 to 3e– per molecule is assigned to the formation of hydroxyl groups. Temperature-programmed reduction (TPR) results showed two reduction steps: to 1 e– per molecule (Co3.1 Co2+) at 475 to 635 K, and to 3e– per molecule (Co21 Co0) at 725 to 815 K. Reduction in the first and second steps occurs according to the contracting sphere model and the nucleation mechanism, respectively. Reduction of Co3+ to Co2+ causes minimal structural changes in the perovskite. Reduction to 3e– per molecule yielded Pr2O3 and metallic cobalt. After this reduction and reoxidation at 973 K, the perovskite structure was regained. By XPS and TPR it was shown that PrCo03 is more easily reducible than LaCo03. It is concluded that the cation in the A position of the structure plays a significant role in the bulk and surface properties of LnCo03 (Ln, lanthanide elements) oxides. 相似文献
154.
Z. Z. Öztürk E. Musluoğlu V. Ahsen A. Gül Ö. Bekaroğlu 《Journal of Materials Science》1992,27(22):6183-6186
D.c. conductivities of polycrystalline monoazacrown ether-substituted phthalocyanines (M=2H, Ni, Zn, Pb, Cu) and diphthalocyanine (M=Lu) are measured as Au-MPc-Au sandwiches to be of the order 10–10–10–12 S m–1. Chemical doping with oxidants (e.g. NOBF4) and enhancing the stacking of planar phthalocyanine moieties through the formation of alkali metal adducts with sodium and potassium ions leads to increase in conductivity of the order 101–102. The low conductivity and the diamagneticity of the bis(phthalocyaninato)-lutetium can be ascribed to the lack of radical nature in LuH(Pc)2. For the a.c. conductivities, lead and lutetium complexes form a group with higher conductivities and the rest show lower conductivity. The conduction activation energies calculated from Arrhenius plots exhibit the lowest value (0.40 eV) for the lutetium compound.Part of this work was presented at NATO-ASI on Semiconductor Materials and Processing Technologies, Erice, Sicily, 1–13 July 1991. 相似文献
155.
Victor Sosa J. A. Azamar-Barrios J. L. Peña L. Francisco Garfias A. I. Oliva P. Quintana 《Journal of Materials Science》1992,27(22):6131-6133
Synthesis of ceramic YBa2Cu3O7– by solid-state reaction was performed under different conditions. Different values of cooling rate and oxygen flow were used, and no significant influence on superconducting characteristics of the samples was observed. A major influence on their mechanical properties was found. 相似文献
156.
157.
Jesús F. Ontiveros Bing Hong Kenji Aramaki Christel Pierlot Jean-Marie Aubry Véronique Nardello-Rataj 《Journal of surfactants and detergents》2021,24(3):401-410
A series of symmetrical dialkyl methanesulfonate amphiphiles [DiC n CHSO 3 ] m M (n = 6, 7, 8) with different counter cations (Mm+ = H+, Li+, Na+, K+, Cu2+, Zn2+, Mg2+, Ca2+, Sc3+) were synthesized in five steps. Their solubility and critical micelle concentration (CMC) in water were determined highlighting a huge effect of the chain length and the nature of the cation. The hydrophilic–lipophilic balance of the surfactants were assessed with the phase inversion temperature (PIT)-slope method based on the deviation from the PIT of the reference C10E4/n-octane/0.01 M NaCl(aq) emulsion through addition of increasing amounts of the dialkyl methanesulfonates. The hydrophilicity of the surfactants was thus ranked in terms of dPIT/dxsulfonate. A “cation” scan with the [DiC 6 CHSO 3 ] m M /benzene/water systems at fw = 0.5 was finally performed confirming the hydrophilicity ranking obtained with the PIT-slope method. It revealed that the [DiC 6 CHSO 3 ] 2 Mg behaves as a “Balanced Surfactant” able to form spontaneously a three-phase microemulsion system (Winsor III) just in the presence of water and oil, in the same way as the catalytic surfactant dimethyldioctylammonium molybdate, which has the same PIT-slope. 相似文献
158.
Julia Peas-Martínez María N. Barrachina Ernesto Jos Cuenca-Zamora Gins Luengo-Gil Susana Beln Bravo Eva Caparrs-Prez Raúl Teruel-Montoya Jos Eliseo-Blanco Vicente Vicente ngel García Irene Martínez-Martínez Francisca Ferrer-Marín 《International journal of molecular sciences》2021,22(4)
Exosomes are extracellular vesicles that contain nucleic acids, lipids and metabolites, and play a critical role in health and disease as mediators of intercellular communication. The majority of extracellular vesicles in the blood are platelet-derived. Compared to adults, neonatal platelets are hyporeactive and show impaired granule release, associated with defects in Soluble N-ethylmaleimide-sensitive fusion Attachment protein REceptor (SNARE) proteins. Since these proteins participate in biogenesis of exosomes, we investigated the potential differences between newborn and adult plasma-derived exosomes. Plasma-derived exosomes were isolated by ultracentrifugation of umbilical cord blood from full-term neonates or peripheral blood from adults. Exosome characterization included size determination by transmission electron microscopy and quantitative proteomic analysis. Plasma-derived exosomes from neonates were significantly smaller and contained 65% less protein than those from adults. Remarkably, 131 proteins were found to be differentially expressed, 83 overexpressed and 48 underexpressed in neonatal (vs. adult) exosomes. Whereas the upregulated proteins in plasma exosomes from neonates are associated with platelet activation, coagulation and granule secretion, most of the underexpressed proteins are immunoglobulins. This is the first study showing that exosome size and content change with age. Our findings may contribute to elucidating the potential “developmental hemostatic mismatch risk” associated with transfusions containing plasma exosomes from adults. 相似文献
159.
Amir Mohammadzadeh Pter P. Lakatos Mihly Balogh Ferenc Zdor Dvid rpd Kardi Zoltn S. Zdori Kornl Kirly Anna Rita Galambos Szilvia Barsi Pl Riba Sndor Benyhe Lszl Kles Tams Tbi va Szk Laszlo G. Harsing Jr. Mahmoud Al-Khrasani 《International journal of molecular sciences》2021,22(5)
The limited effect of current medications on neuropathic pain (NP) has initiated large efforts to develop effective treatments. Animal studies showed that glycine transporter (GlyT) inhibitors are promising analgesics in NP, though concerns regarding adverse effects were raised. We aimed to study NFPS and Org-25543, GlyT-1 and GlyT-2 inhibitors, respectively and their combination in rat mononeuropathic pain evoked by partial sciatic nerve ligation. Cerebrospinal fluid (CSF) glycine content was also determined by capillary electrophoresis. Subcutaneous (s.c.) 4 mg/kg NFPS or Org-25543 showed analgesia following acute administration (30–60 min). Small doses of each compound failed to produce antiallodynia up to 180 min after the acute administration. However, NFPS (1 mg/kg) produced antiallodynia after four days of treatment. Co-treatment with subanalgesic doses of NFPS (1 mg/kg) and Org-25543 (2 mg/kg) produced analgesia at 60 min and thereafter meanwhile increased significantly the CSF glycine content. This combination alleviated NP without affecting motor function. Test compounds failed to activate G-proteins in spinal cord. To the best of our knowledge for the first time we demonstrated augmented analgesia by combining GlyT-1 and 2 inhibitors. Increased CSF glycine content supports involvement of glycinergic system. Combining selective GlyT inhibitors or developing non-selective GlyT inhibitors might have therapeutic value in NP. 相似文献
160.
Bianca Stoean Dumitrita Rugina Monica Focsan Ana-Maria Craciun MÎdÎlina Nistor Tamas Lovasz Alexandru Turza Ioan-Dan Porumb Emese Gl Castelia Cristea Luminita Silaghi-Dumitrescu Simion Astilean Luiza Ioana Gaina 《International journal of molecular sciences》2021,22(6)
We report here the synthesis and structural characterization of novel cationic (phenothiazinyl)vinyl-pyridinium (PVP) dyes, together with optical (absorption/emission) properties and their potential applicability as fluorescent labels. Convective heating, ultrasound irradiation and mechanochemical synthesis were considered as alternative synthetic methodologies proficient for overcoming drawbacks such as long reaction time, nonsatisfactory yields or solvent requirements in the synthesis of novel dye (E)-1-(3-chloropropyl)-4-(2-(10-methyl-10H-phenothiazin-3-yl)vinyl)pyridin-1-ium bromide 3d and its N-alkyl-2-methylpyridinium precursor 1c. The trans geometry of the newly synthesized (E)-4-(2-(7-bromo-10-ethyl-10H-phenothiazin-3-yl)vinyl)-1-methylpyridin-1-ium iodide 3b and (E)-1-methyl-4-(2-(10-methyl-10H-phenothiazin-3-yl)vinyl)pyridin-1-ium tetrafluoroborate 3a′ was confirmed by single crystal X-ray diffraction. A negative solvatochromism of the dyes in polar solvents was highlighted by UV-Vis spectroscopy and explanatory insights were supported by molecular modeling which suggested a better stabilization of the lowest unoccupied molecular orbitals (LUMO). The photostability of the dye 3b was investigated by irradiation at 365 nm in different solvents, while the steady-state and time-resolved fluorescence properties of dye 3b and 3a′ in solid state were evaluated under one-photon excitation at 485 nm. The in vitro cytotoxicity of the new PVP dyes on B16-F10 melanoma cells was evaluated by WST-1 assay, while their intracellular localization was assessed by epi-fluorescence conventional microscopy imaging as well as one- and two-photon excited confocal fluorescence lifetime imaging microscopy (FLIM). PVP dyes displayed low cytotoxicity, good internalization inside melanoma cells and intense fluorescence emission inside the B16-F10 murine melanoma cells, making them suitable staining agents for imaging applications. 相似文献