Kinetics of pyrolysis of pure and doped cobalt oxalate

The object of the present work was to illustrate the effect of impurities on the kinetics and energetics of the thermal decomposition of pure cobalt oxalate. Cationic impurities like Mg²⁺, Mn²⁺, Fe²⁺, Ni²⁺, Cu²⁺, Zn²⁺, Cd²⁺, Pb²⁺, Zr⁴⁺ have been introduced into pure cobalt oxalate dihydrate and differential thermal analysis has been used to determine the enthalpy and energy of activation for the decomposition reaction of pure and doped samples.     

Need for recovery from work: evaluating short-term effects of working hours,patterns and schedules

In this paper working hours, patterns and work schedules of employees were evaluated in terms of need for recovery from work. Self-administered questionnaire data from employees of the Maastricht Cohort Study on Fatigue at Work (n = 12,095) were used. Poisson regression analyses and multivariate logistic regression analyses revealed that higher working hours a day and working hours a week generally went together with more need for recovery from work. Overtime work was particularly associated with higher need for recovery from work in both genders. Both male and female three-shift or irregular shift workers had higher odds of elevated need for recovery compared to day workers. When additionally controlling for work-related factors, need for recovery levels among shift workers substantially lowered. This study clearly showed that working hours and schedules are associated with need for recovery from work, with different associations for men and women. Especially the associations between work schedules and need for recovery from work were very interrelated with other work-related factors. Future studies could further investigate the possibility that shift work might function as a proxy of other work-related factors that explain the different levels in need for recovery from work, or that job demands are perceived higher among shift workers and may therefore lead to more need for recovery from work.     

Microstructural and magnetic studies on P/M processed (Nd14.9Dy1.9)(Fe65.0Co8.0Cu1.0Ga1.0Nb0.7) B7.5 alloy

Sintered samples of (Nd_14.9 Dy_1.9) (Fe₆₅ Co₈ Cu_1.0 Ga_1.0 Nb_0.7)B_7.5 were prepared and subjected to stepwise annealing in the temperature range 875 K–675 K. The XRD and metallographic (optical and electron microscopy) studies reveal a multi-phase microstructure with each phase showing different solubility of the alloying additions. This alloy has T _C of 705 K with an intrinsic coercivity of 1000 kA/m and energy product of 250 kJ/m³ at RT. Solubility of Co into the matrix phase and that of Ga and Cu into the Nd-rich grain boundary phase are considered to be the main contributing factors for the significant enhancement in T _C and H _ci respectively of the multi-component alloy when compared to those of ternary NdFeB, wherein H _ci = 720 kA/m and T _C = 585 K.     

Ground-based method for measuring thermal infrared effective emissivities: Implications and perspectives on the measurement of land surface temperature from satellite data

Thermal infrared emissivity is an important parameter for surface characterization and for determining surface temperature. The field-based measurements for ground and vegetation emissivities in 8-14 w m waveband were performed with an emissivity box. A theoretical analysis was carried out using the box and a correcting factor has been determined. The average value for thermal band emissivity of the exposed bare soil was found to be around 0.909; the average value measured for most of the varieties of vegetation present were in the range of 0.980-0.985. A theoretical model is used for obtaining effective emissivity in the 8-14 w m region from Advanced Very High Resolution Radiometer (AVHRR) data considering the proportion of vegetation cover in a pixel and the field-measured emissivity values. The error of the methodology is found to be within 1.5%. Narrow band emissivities for AVHRR channels 4 and 5 have been derived from the emissivity values in the 8-14 w m waveband. The surface temperature has been derived from AVHRR data using a split-window algorithm as a function of emissivities derived in narrow bands. The split-window algorithm accounted for absorption effects of the atmosphere by incorporating the water vapour concentration measured in the campaign. A good agreement was obtained between the satellite-derived surface temperature and the in situ observations. The result suggest that the methodology allows us to derive land surface temperature with an accuracy better than 1.5° C provided the surface emissivity is known. The paper describes the field-based emissivity measurement and approach for deriving surface temperature over land surface.     

Biomass burning and related trace gas emissions from tropical dry deciduous forests of India: A study using DMSP-OLS data and ground-based measurements

Biomass burning is one of the major sources of trace gas emissions in the atmosphere. In India the major sources of biomass burning include deforestation, shifting cultivation, accidental fires, controlled burning, fire wood burning, burning from agricultural residues and burning due to fire lines. Studies on biomass burning practices gain importance due to increasing anthropogenic activities and increasing rates of deforestation. Satellite data have been widely used over the globe to monitor the rates of deforestation and also with respect to biomass burning studies. But, much of the polar orbiting satellites, due to their repetitive cycle, have limitations in observing such events and in the tropics, due to cloud cover, getting a cloud-free image during the daytime is difficult. In this study we used Defence Meteorological Satellite Program Operational Line Scanner (DMSP-OLS) night-time data to study the biomass burning events over a period of 10 years from 1987 to 1998 for the Eastern Ghats region, covering the northern part of Andhra Pradesh, India. Two ground-based experiments were carried out to quantify the emissions from biomass burning practices. The results of the study with respect to trace gases suggested emission ratios for CO, CH4, NOx and N20 during the burning to be about 12.3%, 1.29%, 0.29% and 0.07% at the first site and 12.5%, 1.59%, 0.29% and 0.05% at the second site, suggesting low inter-fire variability between the sites. The variation has been attributed to the fuel load, vegetation characteristics, site conditions and local meteorological parameters affecting the relative amounts of combustion. Using the DMSP OLS derived areal estimates of active fires, the trace gas emissions released from the biomass burning were quantified. The results suggested the emissions of 8.2 2 10 10 g CO 2, 1.8 2 10 8 g CO, 6.0 2 10 6 g N 2 O, 3.0 2 10 6 g NO x and 1.2 2 10 8 8 g CH 4 during March 1987. The emissions increased to 1.0 2 10 11 g CO 2, 2.3 2 10 g CO, 7.8 2 10 6 g N 2 O, 3.9 2 10 7 g NO x and 1.6 2 10 8 g CH 4, over a period of 10 years. The results of the analysis suggest the possible use of monitoring biomass burning events from DMSP-OLS night-time data.     

High‐Performance Nanocomposites of Sodium Carboxymethylcellulose and Graphene Oxide

High‐performance nanocomposites of NaCMC with GO are produced by solution casting. FESEM images reveal a good homogeneous dispersion of GO in the NaCMC matrix. The composite formation is facilitated by H‐bonding interaction between GO and NaCMC. T_g of the composites increases with increasing GO concentration. The storage modulus (G′) exhibits a maximum 174% increase over NaCMC at 1 wt% GO. The mechanical properties of the composites exhibit highest increase of tensile stress and Young's modulus of 188 ± 4% and 154 ± 11%, respectively, for 1 wt% GO. Analysis of Young's modulus (E_y) data using the Halpin‐Tsai equation suggests that the E_y data are close to the unidirectional orientation at >0.5 wt% GO, indicating more efficient load transfer at these compositions.

     

Design and fabrication of the passive solar still using blue metal stone

In this paper, an attempt has been made to find out the effect of blue metal stone on heat transfer coefficient for a passive single-slope distillation system in summer climatic conditions. The experiments have been conducted on a south facing, single slope, solar still of 10° inclination of condensing cover, in summer climatic conditions for 24?h on 5 different days for three different sizes of blue metal stone from 6 to 20?mm and this is finally compared by using the basin without any absorbing material. The thermal efficiency is calculated by using the energy balance equation.     

Densification of Alumina and Silica in the Presence of a Liquid Phase

Alumina and silica powders were sintered at 1250° to 1460°C in the presence of liquid phases containing CaO, A1₂O₃, and SiO₂. The data were analyzed using the equation D = K log t +C and the Arrhenius equation. The activation energy for sintering decreases with increasing amounts of liquid phase.     

An integrated approach to the optimum utilization of national tungsten resources: Technology gaps

A critical review of the current status of tungsten resources, of state-of-the-art processing technology and of product development in India vis-a-vis the world scenario is presented. An attempt has been made to identify technology gap areas requiring attention.