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排序方式: 共有1346条查询结果,搜索用时 15 毫秒
61.
Jiwon Lee Bryan S. Der Christos S. Karamitros Wenzong Li Nicholas M. Marshall Oana I. Lungu Aleksandr E. Miklos Jianqing Xu Tae Hyun Kang Chang-Han Lee Bing Tan Randall A. Hughes Sang Taek Jung Gregory C. Ippolito Jeffrey J. Gray Yan Zhang Brian Kuhlman George Georgiou Andrew D. Ellington 《American Institute of Chemical Engineers》2020,66(3):e16864
We used the molecular modeling program Rosetta to identify clusters of amino acid substitutions in antibody fragments (scFvs and scAbs) that improve global protein stability and resistance to thermal deactivation. Using this methodology, we increased the melting temperature (Tm) and resistance to heat treatment of an antibody fragment that binds to the Clostridium botulinum hemagglutinin protein (anti-HA33). Two designed antibody fragment variants with two amino acid replacement clusters, designed to stabilize local regions, were shown to have both higher Tm compared to the parental scFv and importantly to retain full antigen binding activity after 2 hr of incubation at 70°C. The crystal structure of one thermostabilized scFv variants was solved at 1.6 Å and shown to be in close agreement with the RosettaAntibody model prediction. 相似文献
62.
Scott J. Robertson Marina B. Ruggles-Wrenn Randall S. Hay Theodore Shillig Ronald Mitchell Brian Kroeger Logan Gumucio 《Journal of the American Ceramic Society》2020,103(2):1358-1371
A facility for testing SiC fiber tows in static fatigue and creep at elevated temperatures in air and steam was developed. Static fatigue of Hi-Nicalon™-S fibers was investigated at 800°C-1100°C at applied stresses between 115 and 1250 MPa in air, in Si(OH)4(g)-saturated steam, and in unsaturated steam. Fibers tested in Si(OH)4(g)-saturated steam and in air had silica scales throughout the test sections, but those tested in unsaturated steam did not develop scales near the steam injection point. Fiber lifetimes in static fatigue were shortest in unsaturated steam, intermediate in Si(OH)4(g)-saturated steam, and longest in air. Failure strains did not exceed 0.3%. Steady-state strain rates and static fatigue lifetimes are modelled empirically by the Monkman-Grant relationship. Failure mechanisms are discussed. 相似文献
63.
Grain growth of ZnO in the presence of a liquid phase of the ZnO–BaO system has been studied for temperatures from 1300° to 1400°C. The specimens were treated in boiling water and the grains were separated by dissolving the matrix phase in an ultrasonic bath. As a consequence three-dimensional grain size measurements were possible. Microstructural examination shows some grain coalescence with a wide range of neck size ratios and corresponding dihedral angles, however, most grains are isolated. Lognormal grain size distributions show similar shapes, indicating that the growth mechanism is invariant over this time and temperature. All regressions between G n and time for n = 2 and 3 proved statistically significant. The rate constants calculated with the growth exponent set to n = 3 are on the same order of magnitude as in metallic systems. The apparent activation energy for growth is estimated between 355 and 458 kJ/mol. 相似文献
64.
Degradation of Nextel™ 610‐based oxide‐oxide ceramic composites by aluminum oxychloride decomposition products 下载免费PDF全文
Randall S. Hay Kristin A. Keller Larry P. Zawada Nathan S. Jacobson Geoff E. Fair 《Journal of the American Ceramic Society》2018,101(9):4203-4223
Nextel? 610 alumina fibers and alumina‐YAG (yttrium‐aluminum garnet) matrices were used to make oxide‐oxide ceramic matrix composites (CMCs) with and without monazite (LaPO4) fiber‐matrix interfaces. Twelve sequential aluminum oxychloride (AlOCl) infiltrations with 1 hour heat treatments at 1100°C and a final 1 hour heat treatment at 1200°C were used for matrix densification. This matrix processing sequence severely degraded CMC mechanical properties. CMC tensile strengths and interlaminar tensile (ILT) strengths were less than 10 MPa and 1 MPa, respectively. Axial fracture of Nextel? 610 fibers was observed after ILT testing, highlighting the extreme degradation of fiber strength. Extensive characterization was done to attempt to determine the responsible degradation mechanisms. Changes in Nextel? 610 fiber microstructure after CMC processing were characterized by optical microscopy, SEM, and extensively by TEM. In AlOCl degraded fibers, grain boundaries near the fiber surface were wetted with a glass that contained Y2O3/SiO2 or Y2O3/La2O3/P2O5/SiO2, and near‐surface pores were partially filled with Al2O3. This glass must also contain some Al2O3 and initially some chlorine. AlOCl decomposition products were predicted using the FactSage® Thermochemical code, and were characterized by mass spectrometry. Effects of AlOCl precursors on monazite coated and uncoated Nextel? 610 fibers tow and filament strength were evaluated. A mechanism for the severe degradation of the oxide‐oxide CMCs and Nextel? 610 fibers that involves subcritical crack growth promoted by release of chlorine containing species during breakdown of intergranular glasses in an anhydrous environment is proposed. 相似文献
65.
Alkyl and alk-1-enyl glyceryl ethers have been identified in the phospholipids of three insect species, the American cockroach
(Periplaneta americana), the tobacco budworm (Heliothis virescens), and the boll weevil (Anthonomus grandis). Glyceryl ethers were not detected in the neutral lipids. The ethers were found in the phospholipid fraction of whole insects
and in isolated fat body tissue. The ether content varied among the three insect species, and fluctuated during various developmental
stages. Gas liquid chromatographic analysis of the alkyl glyceryl ethers and aldehydes derived from the alk-1-enyl glyceryl
ethers of the cockroach and budworm whowed striking differences in chain length. However, the hydrocarbon side-chain of the
two ether fractions were similar in length for each species. Preliminary evidence indicates that 1-14C-acetate can be incorporated into alkyl ethers but not into alk-1-enyl ethers ofHeliothis pupae.
Presented at the AOCS-AACC joint meeting, Washington, D.C., 1968.
Under contract with the U.S. Atomic Energy Commission. 相似文献
66.
Keisuke Kobayashi Minoru Ryu Yutaka Doshida Youichi Mizuno Clive A. Randall 《Journal of the American Ceramic Society》2013,96(2):531-537
The (1?x)NaNbO3–(x)NaTaO3 solid solution was investigated for x ≤ 0.4 in terms of new high‐temperature and high‐permittivity dielectric system that is suitable for base metal inner electrode capacitor applications. The addition of Ta significantly enhanced the resistivity of the dielectric, resulting in superior resistivity than the dielectrics‐formulated BaTiO3 systems that dominate the multilayer ceramic capacitor dielectric devices. The voltage dependence of the permittivity was also superior to BaTiO3‐based materials, providing higher capacitance at higher temperatures. A transmission electron microscopy study illustrated that the grains had so‐called core‐shell structure. According to the electron diffraction analysis, the core region had an inhomogeneous structure between antiferroelectric and ferroelectric phases, and shell region had an incommensurate ferroelectric‐like structure. The core and shell region had Nb‐ and Ta‐rich composition, respectively, and their interface was compositionally sharp, implying that shell region was formed via a liquid phase during the sintering process with an incongruent Ta dissolution reprecipitation. We anticipate that these or similar materials based on the alkali‐niobate perovskites can be further enhanced to provide capacitor solutions from 150°C to 250°C, which is an important range for a number of new AC–DC invertor and engine control units. 相似文献
67.
Do-Kyun Kwon Clive A. Randall Thomas R. Shrout Michael T. Lanagan 《Journal of the American Ceramic Society》2004,87(6):1088-1092
The dielectric properties and frequency dispersion associated with a dielectric relaxation were evaluated within the perovskite (1− x )BiScO3 – x Ba(Mg1/3 Nb2/3 )O3 solid solution systems (0.7 ≤ x ≤ 1). With increasing BiScO3 , the room-temperature dielectric permittivity at low frequency (100 Hz) increased up to 115 at x = 0.7, and a dielectric relaxation phenomenon was evident. Relaxation parameters were analyzed using several Arrhenius-type equations, and the microwave dielectric property measurement using rectangular wave-guide method enabled confirmation of the extrapolated value of the Arrhenius plot. The result of the microwave dielectric property measurement was also checked with J -function fitting based on the frequency-dependent Gaussian distribution of the associated dielectric loss data at low frequency. 相似文献
68.
Jing Guo Amanda L. Baker Hanzheng Guo Michael Lanagan Clive A. Randall 《Journal of the American Ceramic Society》2017,100(2):669-677
Cold sintering process (CSP) is an extremely low‐temperature sintering process (room temperature to ~200°C) that uses aqueous‐based solutions as transient solvents to aid densification by a nonequilibrium dissolution‐precipitation process. In this work, CSP is introduced to fabricate microwave and packaging dielectric substrates, including ceramics (bulk monolithic substrates and multilayers) and ceramic‐polymer composites. Some dielectric materials, namely Li2MoO4, Na2Mo2O7, K2Mo2O7, and (LiBi)0.5MoO4 ceramics, and also (1?x)Li2MoO4?xPTFE and (1?x)(LiBi)0.5MoO4?xPTFE composites, are selected to demonstrate the feasibility of CSP in microwave and packaging substrate applications. Selected dielectric ceramics and composites with high densities (88%‐95%) and good microwave dielectric properties (permittivity, 5.6‐37.1; Q × f, 1700‐30 500 GHz) were obtained by CSP at 120°C. CSP can be also used to potentially develop a new co‐fired ceramic technology, namely CSCC. Li2MoO4?Ag multilayer co‐fired ceramic structures were successfully fabricated without obvious delamination, warping, or interdiffusion. Numerous materials with different dielectric properties can be densified by CSP, indicating that CSP provides a simple, effective, and energy‐saving strategy for the ceramic packaging and microwave device development. 相似文献
69.
Seth S. Berbano Jing Guo Hanzheng Guo Clive A. Randall 《Journal of the American Ceramic Society》2017,100(5):2123-2135
The recently developed technique of cold sintering process (CSP) enables densification of ceramics at low temperatures, i.e., <300°C. CSP employs a transient aqueous solvent to enable liquid phase‐assisted densification through mediating the dissolution‐precipitation process under a uniaxial applied pressure. Using CSP in this study, 80% dense Li1.5Al0.5Ge1.5(PO4)3 (LAGP) electrolytes were obtained at 120°C in 20 minutes. After a 5 minute belt furnace treatment at 650°C, 50°C above the crystallization onset, Li‐ion conductivity was 5.4 × 10?5 S/cm at 25°C. Another route to high ionic conductivities ~10?4 S/cm at 25°C is through a composite LAGP ‐ (PVDF‐HFP) co‐sintered system that was soaked in a liquid electrolyte. After soaking 95, 90, 80, 70, and 60 vol% LAGP in 1 M LiPF6 EC‐DMC (50:50 vol%) at 25°C, Li‐ion conductivities were 1.0 × 10?4 S/cm at 25°C with 5 to 10 wt% liquid electrolyte. This paper focuses on the microstructural development and impedance contributions within solid electrolytes processed by (i) Crystallization of bulk glasses, (ii) CSP of ceramics, and (iii) CSP of ceramic‐polymer composites. CSP may offer a new route to enable multilayer battery technology by avoiding the detrimental effects of high temperature heat treatments. 相似文献
70.
Douglas E. Burkes Randall S. Fielding Douglas L. Porter 《Journal of Nuclear Materials》2009,392(2):158-163
Fast reactors are once again being considered for nuclear power generation, in addition to transmutation of long-lived fission products resident in spent nuclear fuels. This re-consideration follows with intense developmental programs for both fuel and reactor design. One of the two leading candidates for next generation fast reactor fuel is metal alloys, resulting primarily from the successes achieved in the 1960s to early 1990s with both the experimental breeding reactor-II and the fast flux test facility. The goal of the current program is to develop and qualify a nuclear fuel system that performs all of the functions of a conventional, fast-spectrum nuclear fuel while destroying recycled actinides, thereby closing the nuclear fuel cycle. In order to meet this goal, the program must develop efficient and safe fuel fabrication processes designed for remote operation. This paper provides an overview of advanced casting processes investigated in the past, and the development of a gaseous diffusion calculation that demonstrates how straightforward process parameter modification can mitigate the loss of volatile minor actinides in the metal alloy melt. 相似文献