Fully-coupled simulations of thermally-induced cracking in pegmatite due to microwave irradiation

Fully-coupled thermo-mechanical simulations are implemented in COMSOL Multiphysics to investigate micro-scale stress-strain variability in pegmatite specimens subjected to thermal loading using microwaves. Thermally-induced compressive and tensile stresses increase as the microwave irradiation duration increases. The dielectric constant, coefficient of expansion, and type and size of mineralogical boundary have significant impacts on the responses of the rock to microwave irradiation. The maximum principal stress of the chlorite is the smallest, indicating that the chlorite experiences the most damage under microwave irradiation, followed by the quartz. The maximum principal stress values of plagioclase and orthoclase are larger, indicating that they are likely to incur the least damage. Where quartz or chlorite is dominant, the resulting von Mises stresses are consistently higher after 120 s of microwave irradiation. The rate of generation of von Mises stresses increases most rapidly along the interface between quartz and plagioclase, and the interface between quartz and orthoclase, followed by the interface between quartz and chlorite, and finally the interface between plagioclase and orthoclase. The presented modeling approach provides a practical method to investigate stress-strain relationships within mineralogical boundaries inside a rock thin section.     

Nanocomposites based on transition metal oxides in polyvinyl alcohol for EMI shielding application

In the present work, the nanocomposites based on different transition metal oxides like iron oxide (Fe₂O₃), zinc oxide (ZnO), silicon dioxide (SiO₂), zirconium dioxide (ZrO₂), and titanium dioxide (TiO₂) in PVA matrix have been studied for their suitability as electromagnetic interference (EMI) shielding materials in the frequency range of 4–8 GHz (C-band) and 8–12 GHz (X-band). The nanocomposites containing 0.1, 0.5, 1.0, 5.0, and 10.0 wt% of oxides in the matrix were synthesised by solvent casting method. The EMI attenuation studies in 4–12 GHz frequency range were carried out using the Vector Network Analyzer R & S: ZVA40 method by measuring the loss due to reflection. The minimum reflectivity values for the composites containing Fe₂O₃, ZnO, SiO_2, ZrO₂, and TiO₂ in PVA matrix at 10 wt% concentration level in the matrix were found to be ?38.85 dB (10.4 GHz), ?33.65 dB (10.4 GHz), ?41.90 dB (10.4 GHz), ?24.90 dB (11.0 GHz), and ?32.90 dB (9.76 GHz), respectively. Based on these results, the SiO₂- and Fe₂O₃-based composites, which also exhibit high thermal stability and mechanical strength, are found to be low-cost and efficient EMI shielding materials.     

Direct quantification of topological protection in symmetry-protected photonic edge states at telecom wavelengths

Topological on-chip photonics based on tailored photonic crystals(PhCs)that emulate quantum valley-Hall effeas has recently gained widespread interest owing to its promise of robust unidirectional transport of classical and quantum information.We present a direct quantitative evaluation of topological photonic edge eigenstates and their transport properties in the telecom wavelength range using phase-resolved near-field optical microscopy.Experimentally visualizing the detailed sub-wavelength structure of these modes propagating along the interface between two topologically non-trivial mirror-symmetric lattices allows us to map their dispersion relation and differentiate between the contributions of several higher-order Bloch harmonics.Selective probing of forward-and backward-propagating modes as defined by their phase velocities enables direct quantification of topological robustness.Studying near-field propagation in controlled defects allows us to extract upper limits of topological protection in on-chip photonic systems in comparison with conventional PhC waveguides.We find that protected edge states are two orders of magnitude more robust than modes of conventional PhC waveguides.This direct experimental quantification of topological robustness comprises a crucial step toward the application of topologically protected guiding in integrated photonics,allowing for unprecedented error-free photonic quantum networks。     

PHOTOCHEMICAL AND CHEMICAL TRANSFORMATION OF Calotropis procera LATEX TOWARDS OBTAINING VALUE ADDED CHEMICALS AND FUELS

ABSTRACT

Photothermal degradation of the latex obtained from Calotropis procera showed enhanced extraction in heptane up to 50%. Treatment of the latex with different concentrations of NaOH resulted in the reduction in heptane extraction of the latex. Treatment of latex with aqueous HC1 coagulated it and thus resulted in an increase in extraction yield. The ¹HNMR, ^l3CNMR and FTTR spectral analyses of treated latex showed an increase in the olefinic and carbonyl groups in the latex. Thus, this showed that photothermal treatments rendered the latex more amenable to hydrocracking for obtaining value added chemicals and fuels from the latex.     

Intensification of Freeze-Drying Rate of Bacillus subtilis MTCC 2396 Using Tungsten Halogen Radiation: Optimization of Moisture Content and α-Amylase Activity

A novel freeze-drying protocol has been explored to render fast and cost-effective freeze drying of hyperamylase producing Bacillus subtilis MTCC2396 employing a tungsten halogen lamp radiator (THLR) as a heat source. Response surface methodology assessed the maximum reduction in moisture content (96.07%) and minimum reduction in α-amylase (EC 3.2.1.1) activity (1.02%) in 4 h drying time at 42.5°C radiation temperature. α-amylase activity (0.046 U) and final moisture content (3.93%) of the optimally freeze-dried bacterial strain appeared satisfactory. The freeze-drying time using THLR (4 h) is remarkably lower compared to that under a conventional conductive plate heater (CPH) (10 h) at otherwise identical conditions. The higher effective moisture diffusivity of 0.0052 to 0.0078 m ²/s under THLR compared to 0.00084 to 0.0015 m ²/s under CPH (corresponding to 20–50°C) advocated the superiority of the THLR heating protocol. The higher efficacy of THLR was also evidenced through lower activation energy (8.42 kJ/mol) of moisture diffusion compared to that (12.051 kJ/mol) of CPH. The optimally freeze-dried bacteria demonstrated the same growth rate in addition to exhibiting excellent retention of bioremedial (Hg²⁺ removal) activity to that of the control.     

Link Estimation and Routing in Sensor Network Backbones: Beacon-Based or Data-Driven?

In the context of IEEE 802.11b network testbeds, we examine the differences between unicast and broadcast link properties, and we show the inherent difficulties in precisely estimating unicast link properties via those of broadcast beacons even if we make the length and transmission rate of beacons be the same as those of data packets. To circumvent the difficulties in link estimation, we propose to estimate unicast link properties directly via data traffic itself without using periodic beacons. To this end, we design a data-driven routing protocol Learn-on-the-Fly (LOF). LOF chooses routes based on ETX/ETT-type metrics, but the metrics are estimated via MAC feedback for unicast data transmission instead of broadcast beacons. Using a realistic sensor network traffic trace and an 802.11b testbed of ~195 Stargates, we experimentally compare the performance of LOF with that of beacon-based protocols, represented by the geography-unaware ETX and the geography-based PRD. We find that LOF reduces end-to-end MAC latency by a factor of 3, enhances energy efficiency by a factor up to 2.37, and improves network throughput by a factor up to 7.78, which demonstrate the feasibility and the potential benefits of data-driven link estimation and routing.     

Effects of Post-Weld Heat Treatment on the Microstructure and Toughness of Flash Butt Welded High-Strength Low-Alloy Steel

Metallurgical and Materials Transactions A - Effect of post-weld heat treatment on the weld microstructure, texture, and its correlation to the toughness of flash butt welded joints were...     

Synthesis, properties and biomedical applications of poly(glycerol sebacate) (PGS): A review

Poly(glycerol sebacate) (PGS) is a biodegradable polymer increasingly used in a variety of biomedical applications. This polyester is prepared by polycondensation of glycerol and sebacic acid. PGS exhibits biocompatibility and biodegradability, both highly relevant properties in biomedical applications. PGS also involves cost effective production with the possibility of up scaling to industrial production. In addition, the mechanical properties and degradation kinetics of PGS can be tailored to match the requirements of intended applications by controlling curing time, curing temperature, reactants concentration and the degree of acrylation in acrylated PGS. Because of the flexible and elastomeric nature of PGS, its biomedical applications have mainly targeted soft tissue replacement and the engineering of soft tissues, such as cardiac muscle, blood, nerve, cartilage and retina. However, applications of PGS are being expanded to include drug delivery, tissue adhesive and hard tissue (i.e., bone) regeneration. The design and fabrication of PGS based devices for applications that mimic native physiological conditions are also being pursued. Novel designs range from accordion-like honeycomb structures for cardiac patches, gecko-like surfaces for tissue adhesives to PGS (nano) fibers for extra cellular matrix (ECM) like constructs; new design avenues are being investigated to meet the ever growing demand for replacement tissues and organs. In less than a decade PGS has become a material of great scrutiny and interest by the biomedical research community. In this review we consolidate the valuable existing knowledge in the fields of synthesis, properties and biomedical applications of PGS and PGS-related biomaterials and devices.     

Towards Strong Nonapproximability Results in the Lov��sz-Schrijver Hierarchy

Lovász and Schrijver described a generic method of tightening the LP and SDP relaxation for any 0–1 optimization problem. These tightened relaxations were the basis of several celebrated approximation algorithms (such as for max-cut, max-3sat, and sparsest cut).