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71.
应用事故树法对深水井控进行风险评估 总被引:5,自引:0,他引:5
深水井喷事故危害极大,严重时可导致井眼报废、船毁人亡等恶性后果,预防和控制深水井喷是国内外石油界的一个技术难题。文中利用风险树分析引发深水钻井工程事故的顶事件,重点讨论各底事件的相互联系及对系统的影响程度,分析顶事件的发生概率,为最大程度地减少深水井控事故的发生提供理论依据。通过对深水钻井过程中存在的风险进行分析,构建了深水井控风险分析事故树,并对其进行了定性与定量分析。通过风险分析,认为深水井控最主要的影响因素是关井及压井时设备故障、设计方法及操作失误的影响超过安全极限。分析表明,降低基本事件的发生概率对预防井喷作用明显,基本事件发生概率提高1倍,井喷发生概率提高近10倍。针对深水井控过程中存在的风险因素,从工艺、装备及人员要求方面提出了预防深水井喷的措施。 相似文献
72.
73.
The cooling and solidification of melted drops during their movement in an immiscible cooling medium is widely employed for granulation in the chemical industry, and a study of these processes to provides a basis for the design of the granulation tower height and the temperature of the cooling medium is reported. A physical model of the cooling and solidification of the drop is established and the numerical calculation is performed. The influences of the key factors in the solidification, i.e., Bi number, drop diameter, temperature of the cooling medium, etc. are presented. The cooling and solidification during wax granulation in a water‐cooling tower and during urea granulation in an air‐cooling tower (spraying tower) are described in detail. Characteristics of the solidification and temperature distribution within the particle at different times are shown. The model and calculations can be used for structure design of the granulation tower and optimization of the operation parameters. 相似文献
74.
Biodegradable multiblock poloxamers (BMPs) with gel duration of 8 h to several weeks were prepared by varying their molecular weights from 4000 to 40 000 g mol?1. The molecular weight of the BMP was controlled by changing the poloxamer to coupling agent ratio. Assuming a micelle packing model of the BMP gel, as in the case of a poloxamer gel, the micelle properties and critical gel concentration of BMPs were investigated on the basis of the scaling concept. The findings suggest that the control of molecular weight by hydrolyzable groups can be a facile approach to optimize the gel properties for biomedical applications. Copyright © 2005 Society of Chemical Industry 相似文献
75.
Colour Centres and Energy Transfer in BaF2-xClx:Eu2+ Phosphors 总被引:1,自引:1,他引:0
The optical absorption spectra of BaF2-xClx:Eu2 after ultraviolet (UV) light excitation were investigated.The differences between the absorption spectra after and before excitation (DAS) were observed.The DAS increase at both the high and the low energy side of F band in BaF2-xClx:Eu2 after 245 nm UV light excitation.The bleach effect of UV light and the absorption of electrons in the valence band may account for the former and the formation of Fa centres (association of F(Cl-) centres), whose absorption band matches the HeNe laser better, may explain the latter.In the write-in process, the transfer of electrons is via tunneling.In the readout process, the transfer of electrons captured in F(F-) and Fa centres is more likely via tunneling, and that of F(Cl-) centres is more likely via conduction band. 相似文献
76.
利用引进的制造技术和设备,制作出了 APT(STLRI)—1.78型系列化光纤连接器。 相似文献
77.
78.
研究了某种环氧树脂阻尼灌封胶在热氧老化的作用下分子结构、硬度、断面形貌以及动态力学性能随时间的变化.傅立叶红外光谱图表明,所制备的样品环氧基团反应比较完全,热氧老化后试样表面由仲胺和环氧基团形成的酯键发生了部分断裂和氧化;邵氏硬度的增加、瓦向高温区移动则表明在老化过程中复杂的固化反应仍然继续进行;最大损耗因子(tanδmax)波动较小表明试样老化后分子结构几乎保持不变;SEM图片显示试样的冲击断裂由老化前的韧性转变为老化后的脆性断裂. 相似文献
79.
Grazing incidence reflection absorption Fourier transform infrared (GIRA-FTIR) spectroscopy was used to characterize the ferroelectric behavior of a thin poly(vinylidene fluoride–trifluoroethylene) P(VDF–TrFE) copolymer. The lab-built GIRA-FTIR apparatus allowed the heating and corona poling process to be carried out whilst collecting the GIRA spectra of the thin polymer film. The Curie transition from the ferroelectric to paraelectric phase was confirmed from the abrupt change in intensity of the 849 cm−1 band in the RA-FTIR spectrum. It was found that the Curie temperature dropped dramatically when the film thickness was lowered to below a certain critical value of approximately 100 nm. The switching of the CF2 dipoles in the ferroelectric crystals after applying the external electric field could be determined by monitoring the change in the 849 cm−1 band intensity. For the 600 nm thick P(VDF–TrFE) film, the switching of the dipoles appears to occur almost instantaneously, while the kinetics of dipole switching of the 75 nm thick film were significantly retarded. The repeated switchability of the CF2 dipoles upon the application of a bipolar cyclic electric field was also confirmed. The bistability of the film due to remnant polarization was also confirmed from the absorbance of the 849 cm−1 band after removing the applied voltage during corona poling. 相似文献
80.
Du Young Choi Long Mei Jin Dexian Wang Kyung Ho Row 《Korean Journal of Chemical Engineering》2005,22(3):465-469
High-performance frontal analysis (HPFA) was used for a protein binding study of isoflavones (daidzein, genistin, and genistein),
enantiomers of perillyl alcohol and S-ibuprofen to human serum albumin (HSA). The analyses were performed on a Develosil and
Inertsil 100-Diol-5 column (10 cm×4.6mm). Sodium phosphate solution (pH 7.4, ionic strength 0.17) was used as the mobile phase
at a flow rate of 1 ml/min. To ensure the drug to be eluted as a trapezoidal peak with a plateau, injection volumes were each
fixed up the zonal profile with an evident plateau appears. The unbound drug concentration was determined from a plateau height
of the plateau region after that experimental data were fitted by Scatchard equation. The binding constants (K) and total
binding affinities (nK) of drugs to HSA were calculated, respectively. 相似文献